Argon
- Formula: Ar
- Molecular weight: 39.948
- IUPAC Standard InChIKey: XKRFYHLGVUSROY-UHFFFAOYSA-N
- CAS Registry Number: 7440-37-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Ar; UN 1006; UN 1951; argon atom
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- NIST Atomic Spectra Database - Lines Holdings (on physics web site)
- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
- NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- Options:
Data at NIST subscription sites:
- NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
- NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 15.759 ± 0.001 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 369.2 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 346.3 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
15.763 | PIPECO | Weitzel, Mahnert, et al., 1994 | LL |
15.75962 | EVAL | Lide, 1992 | LL |
15.82 | EI | Wetzel, Baiocchi, et al., 1987 | LBLHLM |
15.760 | S | Kelly, 1987 | LBLHLM |
15.759 | PE | Kimura, Katsumata, et al., 1981 | LLK |
15.88 | EI | Clare and Sowerby, 1981 | LLK |
15.7 | EI | Freiser, 1980 | LLK |
15.75962 ± 0.00001 | S | Minnhagen, 1973 | LLK |
15.753 ± 0.002 | TE | Spohr, Guyon, et al., 1971 | LLK |
15.75962 ± 0.00001 | S | Yoshino, 1970 | RDSH |
15.759 | S | Yoshino, 1969 | RDSH |
15.713 ± 0.003 | CI | Hotop and Niehaus, 1969 | RDSH |
15.757 ± 0.005 | PE | Collin and Natalis, 1968 | RDSH |
15.74 ± 0.05 | EI | Gallegos and Klaver, 1967 | RDSH |
15.78 ± 0.03 | EI | Winters, Collins, et al., 1966 | RDSH |
15.79 | PE | Al-Joboury and Turner, 1963 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Weitzel, Mahnert, et al., 1994
Weitzel, K.-M.; Mahnert, J.; Penno, M.,
ZEKE-PEPICO investigations of dissociation energies in ionic reactions,
Chem. Phys. Lett., 1994, 224, 371. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Wetzel, Baiocchi, et al., 1987
Wetzel, R.C.; Baiocchi, F.A.; Hayes, T.R.; Freund, R.S.,
Absolute cross sections for electron-impact ionization of the rare-gas atoms by the fast-neutral-beam method,
Phys. Rev. A, 1987, 35, 559. [all data]
Kelly, 1987
Kelly, R.L.,
Atomic and ionic spectrum lines of hydrogen through kryton,
J. Phys. Chem. Ref. Data, 1987, 16. [all data]
Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.,
Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules
in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]
Clare and Sowerby, 1981
Clare, P.; Sowerby, D.B.,
Electron impact ionisation energies of some halo-cyclotriphosphazenes,
J. Inorg. Nucl. Chem., 1981, 43, 477. [all data]
Freiser, 1980
Freiser, B.S.,
Electron impact ionization of argon ions by trapped ion cyclotron resonanace spectroscopy,
Int. J. Mass Spectrom. Ion Phys., 1980, 33, 263. [all data]
Minnhagen, 1973
Minnhagen, L.,
Spectrum and the energy levels of neutral argon, Ar I,
J. Opt. Soc. Am., 1973, 63, 1185. [all data]
Spohr, Guyon, et al., 1971
Spohr, R.; Guyon, P.M.; Chupka, W.A.; Berkowitz, J.,
Threshold photoelectron detector for use in the vacuum ultraviolet,
Rev. Sci. Instrum., 1971, 42, 1872. [all data]
Yoshino, 1970
Yoshino, K.,
Absorption spectrum of the argon atom in the vacuum-ultraviolet region,
J. Opt. Soc. Am., 1970, 60, 1220. [all data]
Yoshino, 1969
Yoshino, K.,
Absorption spectrum of the argon atom in the vacuum-ultraviolet region,
J. Opt. Soc. Am., 1969, 59, 1525. [all data]
Hotop and Niehaus, 1969
Hotop, H.; Niehaus, A.,
Reactions of excited atoms molecules with atoms and molecules. II. Energy analysis of penning electrons,
Z. Phys., 1969, 228, 68. [all data]
Collin and Natalis, 1968
Collin, J.E.; Natalis, P.,
Vibrational and electronic ionic states of nitric oxide. An accurate method for measuring ionization potentials by photoelectron spectroscopy,
Intern. J. Mass Spectrom. Ion Phys., 1968, 1, 483. [all data]
Gallegos and Klaver, 1967
Gallegos, E.J.; Klaver, R.F.,
Automatic voltage scanner for a peak switching mass spectrometer,
J.Sci. Instr., 1967, 44, 427. [all data]
Winters, Collins, et al., 1966
Winters, R.E.; Collins, J.H.; Courchene, W.L.,
Resolution of fine structure in ionization-efficiency curves,
J. Chem. Phys., 1966, 45, 1931. [all data]
Al-Joboury and Turner, 1963
Al-Joboury, M.I.; Turner, D.W.,
Molecular photo-electron spectroscopy. Part I. The hydrogen and nitrogen molecules,
J. Chem. Soc., 1963, 5141. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.