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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - S.G. Lias

Data compiled as indicated in comments:
LL - S.G. Lias and J.F. Liebman
LBLHLM - S.G. Lias, J.E. Bartmess, J.F. Liebman, J.L. Holmes, R.D. Levin, and W.G. Mallard
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi
RDSH - H.M. Rosenstock, K. Draxl, B.W. Steiner, and J.T. Herron
B - J.E. Bartmess

View reactions leading to Sb+ (ion structure unspecified)

IE (evaluated)8.64eVN/AN/AL

Electron affinity determinations

EA (eV)MethodReferenceComment
1.047418 ± 0.000044N/AScheer, Haugen, et al., 1997B
1.0460 ± 0.0050LPESPolak, Gerber, et al., 1992B
1.070 ± 0.050PDFeldmann, Rackwitx, et al., 1977B

Ionization energy determinations

IE (eV)MethodReferenceComment
8.64EVALLide, 1992LL
8.6EIBusse and Weil, 1982LBLHLM
8.3 ± 0.4EIPiacente and Balducci, 1974LLK
8.68 ± 0.06EICabaud, Hoareau, et al., 1973LLK
8.641SMoore, 1970RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Scheer, Haugen, et al., 1997
Scheer, M.; Haugen, H.K.; Beck, D.R., Single- and Multiphoton Infrared Laser Spectroscopy of Sb-: A Case Study, Phys. Rev. Lett., 1997, 79, 21, 4104-4107. [doi:10.1103/PhysRevLett.79.4104] [all data]

Polak, Gerber, et al., 1992
Polak, M.L.; Gerber, G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Small Antimony Cluster Anions - Sb(-) Sb2(-), Sb3(-), and Sb4(-), J. Chem. Phys., 1992, 97, 12, 8990. [doi:10.1063/1.463326] [all data]

Feldmann, Rackwitx, et al., 1977
Feldmann, D.; Rackwitx, R.; Heinicke, E.; Kaiser, H.J., Photodetachment of Some Atomic Negative Ions: P-, As-, Sb-, Te-, Cr-, Ni-, Z. Physik A., 1977, 282, 2, 143-148. [doi:10.1007/BF01408156] [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Busse and Weil, 1982
Busse, B.; Weil, K.G., Mass spectrometric studies on the vapour phase composition over solid and fused Cs3Sb, Ber. Bunsen-Ges. Phys. Chem., 1982, 86, 93. [all data]

Piacente and Balducci, 1974
Piacente, V.; Balducci, G., The dissociation energy of the molecule GaSb, High Temp. Sci., 1974, 6, 254. [all data]

Cabaud, Hoareau, et al., 1973
Cabaud, B.; Hoareau, A.; Nounou, P.; Uzan, R., High temperature mass spectrometric study of polyatomic antimony species by electron impact. Direct evidence for the existence of Sb3 molecules, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 157. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


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