Cyclohexane, 1,4-dimethyl-, cis-
- Formula: C8H16
- Molecular weight: 112.2126
- IUPAC Standard InChIKey: QRMPKOFEUHIBNM-OCAPTIKFSA-N
- CAS Registry Number: 624-29-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: cis-1,4-Dimethylcyclohexane; 1,cis-4-Dimethylcyclohexane; 1,4-Dimethylcyclohexane, cis-; Cyclohexane, cis-1,4-dimethyl-; 1,4(cis)-dimethylcyclohexane
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Packed | Capillary | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | C78, Branched paraffin | OV-101 | OV-101 | C78, Branched paraffin | OV-101 |
Column length (m) | 3.3 | 20. | 20. | 3.3 | 2.4 |
Carrier gas | He | He | |||
Substrate | Chromosorb G HP | Chromaton W AW | |||
Column diameter (mm) | 0.5 | 0.5 | |||
Phase thickness (μm) | |||||
Temperature (C) | 130. | 150. | 180. | 130. | 120. |
I | 838.2 | 823.4 | 828.3 | 837.4 | 813. |
Reference | Dallos, Sisak, et al., 2000 | Cha and Lee, 1994 | Cha and Lee, 1994 | Reddy, Dutoit, et al., 1992 | Litvinenko, Isakova, et al., 1988 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Squalane | DB-1 |
Column length (m) | 50. | 50. | 180. | 60. | |
Carrier gas | He | He | |||
Substrate | |||||
Column diameter (mm) | 0.22 | 0.22 | 0.25 | 0.264 | |
Phase thickness (μm) | |||||
Temperature (C) | 50. | 50. | 70. | 50. | 60. |
I | 804.6 | 804.6 | 809.8 | 805.0 | 804.1 |
Reference | Litvinenko, Isakova, et al., 1988 | Lunskii and Paizanskaya, 1988 | Lunskii and Paizanskaya, 1988 | Krupcik, Cellar, et al., 1986 | Lubeck and Sutton, 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | SE-30 | SE-30 | Squalane | Squalane |
Column length (m) | 60. | 100. | 64. | 100. | 50. |
Carrier gas | He | He | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.259 | 0.5 | 0.25 | 0.25 | |
Phase thickness (μm) | 1. | ||||
Temperature (C) | 60. | 80. | 80. | 80. | 86. |
I | 804.5 | 810. | 809.6 | 811.9 | 815.1 |
Reference | Lubeck and Sutton, 1983 | Bredael, 1982 | Albaigés and Guardino, 1980 | Albaigés and Guardino, 1980 | Nabivach and Kirilenko, 1979 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Squalane | Squalane |
Column length (m) | 50. | 50. | 50. | 120. | 120. |
Carrier gas | N2 | N2 | N2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | |||
Phase thickness (μm) | |||||
Temperature (C) | 86. | 70. | 70. | 100. | 100. |
I | 815.3 | 810.7 | 810.8 | 813.1 | 813.1 |
Reference | Nabivach and Kirilenko, 1979 | Nabivach and Kirilenko, 1979 | Nabivach and Kirilenko, 1979 | Lulova, Leont'eva, et al., 1976 | Lulova, Leont'eva, et al., 1976 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | SE-30 | Squalane |
Column length (m) | 6.1 | 6.1 | 6.1 | 6.1 | 100. |
Carrier gas | H2 | H2 | H2 | H2 | N2 |
Substrate | |||||
Column diameter (mm) | 3.18 | 3.18 | 3.18 | 3.18 | 0.25 |
Phase thickness (μm) | |||||
Temperature (C) | 130. | 150. | 160. | 170. | 50. |
I | 822. | 829. | 833. | 836. | 805. |
Reference | Mitra, Mohan, et al., 1974 | Mitra, Mohan, et al., 1974 | Mitra, Mohan, et al., 1974 | Mitra, Mohan, et al., 1974 | Rijks and Cramers, 1974 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Vacuum Grease Oil (VM-4) | SE-30 | SE-30 |
Column length (m) | 100. | 100. | |||
Carrier gas | N2 | N2 | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | |||
Phase thickness (μm) | |||||
Temperature (C) | 70. | 70. | 35. | 130. | 80. |
I | 810. | 805.5 | 801. | 820. | 804. |
Reference | Rijks and Cramers, 1974 | Dimov and Schopov, 1971 | Sidorov, Ivanova, et al., 1971 | Mitra and Saha, 1970 | Mitra and Saha, 1970 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed |
---|---|---|
Active phase | Squalane | Methyl Silicone |
Column length (m) | ||
Carrier gas | ||
Substrate | ||
Column diameter (mm) | ||
Phase thickness (μm) | ||
Temperature (C) | 70. | 130. |
I | 810. | 820. |
Reference | Schomburg, 1966 | Antheaume and Guiochon, 1965 |
Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E.,
Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups,
J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0
. [all data]
Cha and Lee, 1994
Cha, K.-W.; Lee, D.-J.,
Prediction of retention indices of various compounds in gas-liquid chromatography,
J. Korean Chem. Soc., 1994, 38, 2, 108-120, retrieved from http://journal.kcsnet.or.kr/publi/dh/dh94n2/108.pdf. [all data]
Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz.,
Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups,
J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S
. [all data]
Litvinenko, Isakova, et al., 1988
Litvinenko, G.S.; Isakova, L.A.; Rubanyk, N.N.,
Quantitative correlation between structure of stereoisomeric saturated cyclic compounds and gas-chromatographic retention indices. I. Methysubstituted,
Izv. AN Kaz. SSR, Ser. Khim., 1988, 5, 54-66. [all data]
Lunskii and Paizanskaya, 1988
Lunskii, M.Kh.; Paizanskaya, I.L.,
Identification of hydrocarbons C1-C9 of petrol fractions of oils and condensates in the use of capillary columns with dinonylphthalate,
Zh. Anal. Khim., 1988, 43, 127-135. [all data]
Krupcik, Cellar, et al., 1986
Krupcik, J.; Cellar, P.; Repka, D.; Garaj, J.; Guiochon, G.,
Use of Kováts retention indices for characterization of solutes in linear temperature-programmed capillary gas-liquid chromatography,
J. Chromatogr., 1986, 351, 111-121, https://doi.org/10.1016/S0021-9673(01)83477-4
. [all data]
Lubeck and Sutton, 1983
Lubeck, A.J.; Sutton, DL.,
Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 6, 328-332, https://doi.org/10.1002/jhrc.1240060612
. [all data]
Bredael, 1982
Bredael, P.,
Retention indices of hydrocarbons on SE-30,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610
. [all data]
Albaigés and Guardino, 1980
Albaigés, J.; Guardino, X.,
Gas chromatographic-mass spectrometric identification of alkylcyclohexanes and cyclohexenes,
Chromatographia, 1980, 13, 12, 755-762, https://doi.org/10.1007/BF02265555
. [all data]
Nabivach and Kirilenko, 1979
Nabivach, V.M.; Kirilenko, A.V.,
The use of retention indices for identifying the components of crude benzene,
Solid Fuel Chem. (Engl. Transl.), 1979, 13, 3, 82-87. [all data]
Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N.,
Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines
in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]
Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A.,
Gas chromatographic analysis of complex hydrocarbon mixtures,
J. Chromatogr. A, 1974, 91, 633-648, https://doi.org/10.1016/S0021-9673(01)97944-0
. [all data]
Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A.,
High precision capillary gas chromatography of hydrocarbons,
Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819
. [all data]
Dimov and Schopov, 1971
Dimov, N.; Schopov, D.,
Empirische korrektion der physikalisch-chemischen retentionsindexe von kohlenwasserstoffen auf squalan,
J. Chromatogr., 1971, 63, 223-228, https://doi.org/10.1016/S0021-9673(01)85634-X
. [all data]
Sidorov, Ivanova, et al., 1971
Sidorov, R.I.; Ivanova, M.P.; Petrova, V.I.,
Temperature dependence of cycloalkane's retention and its using in identification of structure,
Gazovaya Khromatografiya, 1971, 15, 18-26. [all data]
Mitra and Saha, 1970
Mitra, G.D.; Saha, N.C.,
Determination of Retention Indices of Saturated Hydrocarbons by Graphical Methods,
J. Chromatogr. Sci., 1970, 8, 2, 95-102, https://doi.org/10.1093/chromsci/8.2.95
. [all data]
Schomburg, 1966
Schomburg, G.,
Gaschromatographische Retentionsdaten und struktur chemischer verbindungen. III. Alkylverzweigte und ungesättigte cyclische Kohlenwasserstoffe,
J. Chromatogr., 1966, 23, 18-41, https://doi.org/10.1016/S0021-9673(01)98653-4
. [all data]
Antheaume and Guiochon, 1965
Antheaume, J.; Guiochon, G.,
Application de la chromatographie en phase gazeuse à l'étude de la composition des fractions moyennes d'un brut pétrolier,
Bull. Soc. Chim. Fr., 1965, 2, 298-307. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
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