Phosphine, ethyl-

• Formula: C₂H₇P
• Molecular weight: 62.0507
• IUPAC Standard InChI: InChI=1S/C2H7P/c1-2-3/h2-3H2,1H3 Copy

  
• IUPAC Standard InChIKey: JLHMVTORNNQCRM-UHFFFAOYSA-N Copy
• CAS Registry Number: 593-68-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Ethylphosphine
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Mass spectrum (electron ionization)
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C₂H₇P⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

De-protonation reactions

C₂H₆P^- +  =

By formula: C₂H₆P^- + H⁺ = C₂H₇P

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. VIII.Mass spectra of phosphines and diphosphines, Zh. Obshch. Khim., 1969, 39, 1808, In original 1772. [all data]

Wada and Kiser, 1964
Wada, Y.; Kiser, R.W., A mass spectrometric study of some alkyl-substituted phosphines, J. Phys. Chem., 1964, 68, 2290. [all data]

Mo, Yanez, et al., 1999
Mo, O.; Yanez, M.; Decouzon, M.; Gal, J.F.; Maria, P.C.; Guillemin, J.L., Gas-phase basicity and acidity trends in alpha,beta-unsaturated amines, phosphines, and arsines, J. Am. Chem. Soc., 1999, 121, 19, 4653-4663, https://doi.org/10.1021/ja982657e . [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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