H2CCl+
- Formula: CH2Cl+
- Molecular weight: 49.479
- CAS Registry Number: 59000-00-9
- Information on this page:
- Other data available:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 1 | CH2 s-stretch | 2987.3 | w m | Ar | IR | Ma, Chen, et al., 2009 |
| 3 | CCl stretch | 1040 ± 30 | gas | PE | Andrews, Dyke, et al., 1983 Andrews, Dyke, et al., 1984 | ||
| 3 | CCl stretch | 1037.6 | vs | Ar | IR | Ma, Chen, et al., 2009 | |
| b1 | 4 | CH2 wag | 1110.2 | w m | Ar | IR | Ma, Chen, et al., 2009 |
| b2 | 5 | CH2 a-stretch | 3109.3 | m s | Ar | IR | Ma, Chen, et al., 2009 |
Additional references: Jacox, 1994, page 147
Notes
| w | Weak |
| m | Medium |
| s | Strong |
| vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ma, Chen, et al., 2009
Ma, R.; Chen, M.; Zhou, M.,
Infrared Spectra of the Chloromethyl and Bromomethyl Cations in Solid Argon,
J. Phys. Chem. A, 2009, 113, 46, 12926, https://doi.org/10.1021/jp9084266
. [all data]
Andrews, Dyke, et al., 1983
Andrews, L.; Dyke, J.M.; Jonathan, N.; Keddar, N.; Morris, A.; Ridha, A.,
The first band in the He(I) photoelectron spectrum of the CH2Cl free radical,
Chem. Phys. Lett., 1983, 97, 1, 89, https://doi.org/10.1016/0009-2614(83)87190-5
. [all data]
Andrews, Dyke, et al., 1984
Andrews, L.; Dyke, J.M.; Jonathan, N.; Keddar, N.; Morris, A.,
Photoelectron spectroscopic study of the ground states of CH2Cl+, CHCl2+, and CHFCl+,
J. Am. Chem. Soc., 1984, 106, 299. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.