2-Methyl-1-butene

• Formula: C₅H₁₀
• Molecular weight: 70.1329
• IUPAC Standard InChI: InChI=1S/C5H10/c1-4-5(2)3/h2,4H2,1,3H3 Copy

  
• IUPAC Standard InChIKey: MHNNAWXXUZQSNM-UHFFFAOYSA-N Copy
• CAS Registry Number: 563-46-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: 1-Butene, 2-methyl-; γ-Isoamylene; 1-Isoamylene; C2H5C(CH3)=CH2; 2-Methylbutene-1; Isopentene; UN 2371; UN 2459; 2-methylbut-1-ene
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

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Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Gorin, Galkina, et al., 1966
Gorin, Yu.A.; Galkina, G.I.; Makashina, A.N.; Andreeva, N.P., Catalytic Dehydrogenation of Normal Pentenes and Isopentenes and of Their Mixtures, Diluted with Steam, Zh. Prikl. Khim., 1966, 39, 1577-83. [all data]

Kaal. T.A., Ordyan, et al., 1965
Kaal. T.A.; Ordyan, M.B.; Eidus, Y.T., Synthesis of Carboxylic Acid Derivatives Uner Conditions of Acid Catalysis From Carbon Monoxide, Olefines, and Acylating Agents, Zh. Org. Khim., 1965, 1, 1187-9. [all data]

Samartsev and Ogloblin, 1965
Samartsev, M.A.; Ogloblin, K.A., Interaction of nitrosyl Chloride with unsaturate compounds. XVII. cis-trans -isomerism of aliphatic chloronitroso compounds, J. Org. Chem. USSR (Engl. Transl.), 1965, 1, 29-34. [all data]

Eidus, Puzitskii, et al., 1960
Eidus, Y.T.; Puzitskii, K.V.; Sterligov, O.D., Synthesis of Esters and Other Derivatives of Carboxylic Acis by Acid Catalysis from Carbon Monoxide, Olefins, and Acylating Compounds, Zh. Obshch. Khim., 1960, 30, 3799-3802. [all data]

Desty and Whyman, 1957
Desty, D.H.; Whyman, B.H.F., Anal. Chem., 1957, 29, 320. [all data]

Pines and Arrigo, 1957
Pines, H.; Arrigo, J.T., J. Am. Chem. Soc., 1957, 79, 4958. [all data]

Robertson, Heyes, et al., 1952
Robertson, P.W.; Heyes, J.K.; Swedlund, B.E., The Kinetics of Halogen Addition to Unsaturated Compounds XXII. Alkyl- and Halogenoalkylethylenes, J. Chem. Soc., 1952, 1952, 1014. [all data]

Desty and Fidler, 1951
Desty, D.H.; Fidler, F.A., Ind. Eng. Chem., 1951, 43, 905. [all data]

Parker and Goldblatt, 1950
Parker, E.D.; Goldblatt, L.A., The Thermal Isomerization of alo-Ocimene, J. Am. Chem. Soc., 1950, 72, 2151-9. [all data]

Derfer, Greenlee, et al., 1949
Derfer, J.M.; Greenlee, K.W.; Boord, C.E., A New Synthesis of Monoalkylcyclobutanes: Reduction of Neopentyl Type Tribromides, J. Am. Chem. Soc., 1949, 71, 175. [all data]

Foehr and Fenske, 1949
Foehr, E.G.; Fenske, M.R., Magneto-optic Rotation of Hydrocarbons, Ind. Eng. Chem., 1949, 41, 1956. [all data]

Larin and Frost, 1948
Larin, A.Ya.; Frost, A.V., Transformation of Ketones over Active Aluminosilicates, Dokl. Akad. Nauk SSSR, 1948, 59, 1297. [all data]

Thornton and Herald, 1948
Thornton, V.; Herald, A.E., Anal. Chem., 1948, 20, 9. [all data]

Anonymous, 1947
Anonymous, R., , Am. Pet. Inst. Res. Proj. 45, Ohio State Univ., 1947. [all data]

Cleaves and Sherrick, 1947
Cleaves, A.P.; Sherrick, M.E., Infrared spectra of spiropentane, methylenecyclobutane, and 2-methyl-1-butene., Natl. Advis. Comm. Aeronaut., Tech. Notes No. 1160, 1947. [all data]

Fenske, Braun, et al., 1947
Fenske, M.R.; Braun, W.G.; Wiegand, R.V.; Quiggle, D.; McCormick, R.H.; Rank, D.H., Raman Spectra of Hydrocarbons, Anal. Chem., 1947, 19, 700. [all data]

Boord, Greenlee, et al., 1946
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L., The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Weight, Am. Pet. Inst. Res. Proj. 45, Eighth Annu. Rep., Ohio State Univ., June 30, 1946. [all data]

Gerding and van der Vet, 1946
Gerding, H.; van der Vet, A.P., Raman spectra of the seven isomeric pentenes and quantitative analysis of two mixtures by means of the Raman effect, Recl. Trav. Chim. Pays-Bas, 1946, 64, 257. [all data]

Slabey, 1946
Slabey, V.A., J. Am. Chem. Soc., 1946, 68, 1335. [all data]

Moldavskii and Zharkova, 1944
Moldavskii, B.; Zharkova, V., Isomerization of hydrocarbons. VII. Analysis of mixtures of isomeric pentenes., J. Gen. Chem. USSR (Engl. Transl.), 1944, 14, 358. [all data]

Van Arkel, Meerburg, et al., 1942
Van Arkel, A.E.; Meerburg, P.; Handel, v.d., The Dipole Moment of Cylanes, Recl. Trav. Chim. Pays-Bas, 1942, 61, 767. [all data]

Ewell and Hardy, 1941
Ewell, R.H.; Hardy, P.E., Isomerization Equilibria among the Branched Chain Pentenes, J. Am. Chem. Soc., 1941, 63, 3460. [all data]

Carr and Walter, 1936
Carr, E.P.; Walter, G.F., The Ultraviolet Absorption SPectra of Simple Hydrocarbons II. In Liquid and Solution Phase, J. Chem. Phys., 1936, 4, 756. [all data]

Sherrill and Walter, 1936
Sherrill, M.L.; Walter, G.F., Preparation and Physical Constants of 2-Methylbutene-1, J. Am. Chem. Soc., 1936, 58, 742. [all data]

Church, Whitmore, et al., 1934
Church, J.M.; Whitmore, F.C.; McGrew, R.V., The ozonolysis of purely aliphatic olefins the behavior of the five simplest normal alkyl radicals in the dehydration of tertiary alcohols, J. Am. Chem. Soc., 1934, 56, 176. [all data]

Hyman and Wagner, 1930
Hyman, J.; Wagner, C.R., Autoxidation of the Amylenes, J. Am. Chem. Soc., 1930, 52, 4345. [all data]

Midgley and Henne, 1929
Midgley, T.; Henne, A.L., Natural and synthetic rubber: I products of the destructive distillation of natural rubber, J. Am. Chem. Soc., 1929, 51, 1215-26. [all data]

Norris and Joubert, 1927
Norris, J.F.; Joubert, J.M., The Polymerization of teh Amylenes, J. Am. Chem. Soc., 1927, 49, 873. [all data]

Kern, Shriner, et al., 1925
Kern, J.W.; Shriner, R.L.; Adams, R., Platinum and Palladium Oxides as Catalysts in the Reduction of Organic Compounds IX. The Reduction of Olefins, J. Am. Chem. Soc., 1925, 47, 1147. [all data]

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Faraghen; Gruse; Garner, Ind. Eng. Chem., 1921, 13, 1044. [all data]

Picon, 1919
Picon, M., C. R. Hebd. Seances Acad. Sci., 1919, 169, 32. [all data]

Brooks and Humphrey, 1918
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Walker, J.; Wood, J.M., J. Chem. Soc., 1906, 89, 598. [all data]

Fittig, 1880
Fittig, R., Justus Liebigs Ann. Chem., 1880, 200, 21. [all data]

Lebel, 1876
Lebel, J.A., Bull. Soc. Chim. Fr., 1876, 25, 545. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

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