Ethion
- Formula: C9H22O4P2S4
- Molecular weight: 384.476
- IUPAC Standard InChIKey: RIZMRRKBZQXFOY-UHFFFAOYSA-N
- CAS Registry Number: 563-12-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Phosphorodithioic acid, S,S'-methylene O,O,O',O'-tetraethyl ester; Diethion; Ethopaz; Ethyl methylene phosphorodithioate ([(EtO)2P(S)S]2CH2); ENT 24,105; Fosfatox E; Hylemax; Hylemox; Niagara 1240; Nialate; O,O,O',O'-Tetraethyl S,S'-Methylene bisphosphorodithioate; Phosphotox E; Rhodocide; Rodocid; Rodocide; RP 8167; AC 3422; Bis(S-(diethoxyphosphinothioyl)mercapto)methane; Embathion; Ethanox; Ethiol; Ethodan; Ethyl methylene phosphorodithioate; FMC-1240; Fosfono 50; Itopaz; Kwit; Methyleen-S,S'-bis(O,O-diethyl-dithiofosfaat); S,S'-Methylen-bis(O,O-diaethyl-dithiophosphat); Methylene-S,S'-bis(O,O-diaethyl-dithiophosphat); S,S'-Methylene O,O,O',O'-tetraethyl phosphorodithioate; NA 2783; NIA 1240; Phosphorodithioic acid, O,O-diethyl ester, S,S-diester with methanedithiol; O,O,O',O'-Tetraaethyl-bis(dithiophosphat); O,O,O',O'-Tetraethyl S,S'-methylenebisphosphordithioate; Tetraethyl S,S'-methylene bis(phosphorothiolothionate); O,O,O',O'-Tetraethyl-S,S'-methylene di(phosphorodithioate); RP-Thion; Vegfru-fosmite; Ethiol 100
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Gas Chromatography
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | SPB-1 | 250. | 2265. | Lora-Tamayo, Rams, et al., 1986 | He; Column length: 25. m; Column diameter: 0.20 mm |
Kovats' RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-1 | 2232. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
Capillary | DB-5 | 2220. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
Capillary | DB-5 | 2297. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | SE-30 | 2220. | Ramsey, Lee, et al., 1980 | He, Chromosorb G HP (80-100 mesh); Column length: 1.5 m; Program: not specified |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-1 | 2223. | Bicchi, D'Amato, et al., 1996 | 25. m/0.25 mm/0.3 μm, H2, 160. C @ 1. min, 5. K/min, 260. C @ 2. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-1 | 2221. | Bicchi, D'Amato, et al., 1994 | 25. m/0.25 mm/0.3 μm; Program: from 150 0C (1 min) at 5 0/min to 220 0C, then at 10 0/min to 270 0C (5 min) |
Capillary | OV-1 | 2223. | Bicchi, D'Amato, et al., 1994 | 25. m/0.25 mm/0.3 μm; Program: from 160 0C (1 min) at 1 0/min to 170 0C, then 5 0/min to 270 0C (2min) |
Normal alkane RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | OV-1 | 190. | 2220. | TSunoda, 1986 | Helium, Chromosorb W AW DMCS; Column length: 1. m |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | OV-1 | 2210. | TSunoda, 1986 | Helium, Chromosorb W AW DMCS, 4. K/min, 210. C @ 20. min; Column length: 1. m; Tstart: 140. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | 5 % Phenyl methyl siloxane | 2281. | Department of Food Safety and Welfare, 2006 | 30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C(1 min) 25 0C/min -> 125 0C 10 0C/min -> 300 0C (10 min) |
Capillary | 5 % Phenyl methyl siloxane | 2279. | Department of Food Safety and Welfare, 2006 | 30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C(1 min) 25 0C/min -> 125 0C 10 0C/min -> 300 0C (10 min) |
Capillary | Ultra-1 | 2210. | Tameo and Kiyos, 1991 | Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 2265. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Other | Methyl Silicone | 2220. | Ardrey and Moffat, 1981 | Program: not specified |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Carbowax 20M | 3181. | Tameo and Kiyos, 1991 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lora-Tamayo, Rams, et al., 1986
Lora-Tamayo, C.; Rams, M.A.; Chacon, J.M.R.,
Gas Chromatographic Data for 187 Nitrogen- or Phosphorus-Containing Drugs and Metabolites of Toxicological Interest Analysed on Methyl Silicone Capillary Columns,
J. Chromatogr., 1986, 374, 73-85, https://doi.org/10.1016/S0378-4347(00)83254-5
. [all data]
Hall, Whitehead, et al., 1986
Hall, G.L.; Whitehead, W.E.; Mourer, C.R.; Shibamoto, T.,
A new gas chromatographic retention index for pesticides and related compounds,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 5, 266-271, https://doi.org/10.1002/jhrc.1240090503
. [all data]
Ramsey, Lee, et al., 1980
Ramsey, J.D.; Lee, T.D.; Osselton, M.D.; Moffat, A.C.,
Gas-liquid chromatographic retention indices of 296 non-drug substances on SE-30 or OV-1 likely to be encountered in toxicological analyses,
J. Chromatogr., 1980, 184, 2, 185-206, https://doi.org/10.1016/S0021-9673(00)85641-1
. [all data]
Bicchi, D'Amato, et al., 1996
Bicchi, C.; D'Amato, A.; Binello, A.,
Identification of pesticide residues in real matrices by combining retention indices and specific multidetection responses,
J. Hi. Res. Chromatogr., 1996, 19, 2, 80-84, https://doi.org/10.1002/jhrc.1240190204
. [all data]
Bicchi, D'Amato, et al., 1994
Bicchi, C.; D'Amato, A.; Orlandin, M.,
Identification of the constituents of a complex mixture by combined use of retention indices and specific multidetection responses,
J. Hi. Res. Chromatogr., 1994, 17, 5, 335-338, https://doi.org/10.1002/jhrc.1240170510
. [all data]
TSunoda, 1986
TSunoda, N.,
Simultaneous determination of organophosphorous pesticides in forencis chemistry by gas-liquid chromatography with hydrogen flame ionization detector,
Eisei Kagaku, 1986, 32, 2, 91-100, https://doi.org/10.1248/jhs1956.32.91
. [all data]
Department of Food Safety and Welfare, 2006
Department of Food Safety, Ministry of Health; Welfare,
Analytical methods for residual compositional substances of agricultural chemicals, feed aadditives, and veterinary drugs in foods, 2006, retrieved from http://www.mhlw.go.jp/english/topics/foodsafety/positivelist060228/de/060526-1a.pdf. [all data]
Tameo and Kiyos, 1991
Tameo, O.; Kiyos, I.,
Simultaneous determination of pesticides by capillary gas chromatography,
Cannot be traslated (in Japan), 1991, 14, 2, 109-122. [all data]
Waggott and Davies, 1984
Waggott, A.; Davies, I.W.,
Identification of organic pollutants using linear temperature programmed retention indices (LTPRIs) - Part II, 1984, retrieved from http://dwi.defra.gov.uk/research/completed-research/reports/dwi0383.pdf. [all data]
Ardrey and Moffat, 1981
Ardrey, R.E.; Moffat, A.C.,
Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase,
J. Chromatogr., 1981, 220, 3, 195-252, https://doi.org/10.1016/S0021-9673(00)81925-1
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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