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Carbon diselenide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - E.P. Hunter and S.G. Lias

Data compiled as indicated in comments:
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi

QuantityValueUnitsMethodReferenceComment
Proton affinity (review)725.kJ/molN/AHunter and Lias, 1998HL
QuantityValueUnitsMethodReferenceComment
Gas basicity700.9kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV)MethodReferenceComment
9.26 ± 0.01PIDrowart, Smets, et al., 1978LLK
9.4 ± 0.5EISmoes and Drowart, 1977LLK
9.258 ± 0.0002PIRadler and Berkowitz, 1977LLK
9.524PIRadler and Berkowitz, 1977LLK
9.25SGreening and King, 1976LLK
9.26PECradock and Duncan, 1974LLK
9.52PECradock and Duncan, 1974LLK
9.27 ± 0.01PEFrost, Lee, et al., 1973LLK
9.54 ± 0.01PEFrost, Lee, et al., 1973LLK

Appearance energy determinations

IonAE (eV)Other ProductsMethodReferenceComment
CSe+14.37 ± 0.02?PIDrowart, Smets, et al., 1978LLK
CSe+14.586SePIRadler and Berkowitz, 1977LLK
Se+13.38 ± 0.02?PIDrowart, Smets, et al., 1978LLK
Se+13.4543CSePIRadler and Berkowitz, 1977LLK
Se2+15.21 ± 0.02?PIDrowart, Smets, et al., 1978LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656. [doi:10.1063/1.556018] [all data]

Drowart, Smets, et al., 1978
Drowart, J.; Smets, J.; Reynaert, J.C.; Coppens, P., Mass spectrometric study of the photoionization of inorganic gases vapours, Adv. Mass Spectrom., 1978, 7, 647. [all data]

Smoes and Drowart, 1977
Smoes, S.; Drowart, J., Determination of the atomization energies of the molecules CSe(g) and CSe2(g) by the mass spectrometric Knudsen cell method, J. Chem. Soc. Faraday Trans. 2, 1977, 73, 1746. [all data]

Radler and Berkowitz, 1977
Radler, K.; Berkowitz, J., Photoionization mass spectrometric study of CSe2, J. Chem. Phys., 1977, 66, 2176. [all data]

Greening and King, 1976
Greening, F.R.; King, G.W., Rydberg states of carbon diselenide, J. Mol. Spectrosc., 1976, 61, 459. [all data]

Cradock and Duncan, 1974
Cradock, S.; Duncan, W., The photoelectron spectrum of CSe2, Mol. Phys., 1974, 27, 837. [all data]

Frost, Lee, et al., 1973
Frost, D.C.; Lee, S.T.; McDowell, C.A., Photoelectron spectra of OCSe, SCSe, and CSe2, J. Chem. Phys., 1973, 59, 5484. [all data]


Notes

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