Bromine anion

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

Bromine anion + Benzene = (Bromine anion • Benzene)

By formula: Br- + C6H6 = (Br- • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°38. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°71.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°10. ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; B
ΔrG°16. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile = (Bromine anion • Benzonitrile)

By formula: Br- + C7H5N = (Br- • C7H5N)

Quantity Value Units Method Reference Comment
ΔrH°61.5 ± 7.5kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°26. ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-(trifluoromethyl)- = (Bromine anion • Phenol, 3-(trifluoromethyl)-)

By formula: Br- + C7H5F3O = (Br- • C7H5F3O)

Quantity Value Units Method Reference Comment
ΔrH°108. ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B
ΔrH°52.7kJ/molPHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°66.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Aniline = (Bromine anion • Aniline)

By formula: Br- + C6H7N = (Br- • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°61.1 ± 7.5kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°26. ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzoic acid = (Bromine anion • Benzoic acid)

By formula: Br- + C7H6O2 = (Br- • C7H6O2)

Quantity Value Units Method Reference Comment
ΔrH°76.6 ± 7.5kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°41. ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 423 K, ΔSaff taken as that of PhNO2..Br-; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

(Bromine anion • 2Acetonitrile) + Acetonitrile = (Bromine anion • 3Acetonitrile)

By formula: (Br- • 2C2H3N) + C2H3N = (Br- • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°43.5 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°41.84kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°69.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
ΔrS°90.8J/mol*KHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°18. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
ΔrG°15.1kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Bromine anion • Acetonitrile) + Acetonitrile = (Bromine anion • 2Acetonitrile)

By formula: (Br- • C2H3N) + C2H3N = (Br- • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°49.0 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°48.1 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°49.37kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
ΔrS°85.4J/mol*KHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°28. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
ΔrG°24.3kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Bromine anion + Methyl Alcohol = (Bromine anion • Methyl Alcohol)

By formula: Br- + CH4O = (Br- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°60.67 ± 0.42kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°58.2 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°73.6J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°33.5 ± 0.42kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°36. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B
ΔrG°35. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Bromine anion + Phenol, 2-(trifluoromethyl)- = (Bromine anion • Phenol, 2-(trifluoromethyl)-)

By formula: Br- + C7H5F3O = (Br- • C7H5F3O)

Quantity Value Units Method Reference Comment
ΔrH°101.kJ/molPHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
60.2423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

(Bromine anion • Nitric acid) + Nitric acid = (Bromine anion • 2Nitric acid)

By formula: (Br- • HNO3) + HNO3 = (Br- • 2HNO3)

Quantity Value Units Method Reference Comment
ΔrH°75.7kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°46.4kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M

(Bromine anion • 4Water) + Water = (Bromine anion • 5Water)

By formula: (Br- • 4H2O) + H2O = (Br- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°45.2 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
ΔrS°119.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°9.6 ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Bromine anion • 5Water) + Water = (Bromine anion • 6Water)

By formula: (Br- • 5H2O) + H2O = (Br- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°43.1 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°25. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
ΔrS°118.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°7.5 ± 8.8kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Bromine anion • 6Water) + Water = (Bromine anion • 7Water)

By formula: (Br- • 6H2O) + H2O = (Br- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°41.84kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy estimated; B,M
ΔrH°10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/AHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°5.44kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy estimated; B

Bromine anion + p-Cresol = (Bromine anion • p-Cresol)

By formula: Br- + C7H8O = (Br- • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°84.9 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°44.4 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
44.4423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-methyl- = (Bromine anion • Phenol, 3-methyl-)

By formula: Br- + C7H8O = (Br- • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°86.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°45.6 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
45.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + m-Guaiacol = (Bromine anion • m-Guaiacol)

By formula: Br- + C7H8O2 = (Br- • C7H8O2)

Quantity Value Units Method Reference Comment
ΔrH°92.5 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°51.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
51.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Mequinol = (Bromine anion • Mequinol)

By formula: Br- + C7H8O2 = (Br- • C7H8O2)

Quantity Value Units Method Reference Comment
ΔrH°87.9 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°47.3 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
47.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-fluoro- = (Bromine anion • Phenol, 2-fluoro-)

By formula: Br- + C6H5FO = (Br- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°87.4 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°46.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
46.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-fluoro- = (Bromine anion • Phenol, 4-fluoro-)

By formula: Br- + C6H5FO = (Br- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°97.5 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°56.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
56.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-fluoro- = (Bromine anion • Phenol, 3-fluoro-)

By formula: Br- + C6H5FO = (Br- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°97.9 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°57.3 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
57.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-amino- = (Bromine anion • Phenol, 3-amino-)

By formula: Br- + C6H7NO = (Br- • C6H7NO)

Quantity Value Units Method Reference Comment
ΔrH°84.9 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°44.4 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
44.4423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-amino- = (Bromine anion • Phenol, 4-amino-)

By formula: Br- + C6H7NO = (Br- • C6H7NO)

Quantity Value Units Method Reference Comment
ΔrH°81.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°41. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-methyl- = (Bromine anion • Phenol, 2-methyl-)

By formula: Br- + C7H8O = (Br- • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°86.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°45.6 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
45.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-chloro- = (Bromine anion • Phenol, 2-chloro-)

By formula: Br- + C6H5ClO = (Br- • C6H5ClO)

Quantity Value Units Method Reference Comment
ΔrH°88.7 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°48.1 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
48.1423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, nitro- = (Bromine anion • Benzene, nitro-)

By formula: Br- + C6H5NO2 = (Br- • C6H5NO2)

Quantity Value Units Method Reference Comment
ΔrH°62.8 ± 7.5kJ/molTDAsPaul and Kebarle, 1991gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°27. ± 4.2kJ/molTDAsPaul and Kebarle, 1991gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
27.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Nitric acid = (Bromine anion • Nitric acid)

By formula: Br- + HNO3 = (Br- • HNO3)

Quantity Value Units Method Reference Comment
ΔrH°83.7kJ/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), ΔrH>; M
Quantity Value Units Method Reference Comment
ΔrS°77.4J/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), ΔrH>; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
56.1367.FADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), ΔrH>; M

Bromine anion + 1,3,5-Trinitrobenzene = (Bromine anion • 1,3,5-Trinitrobenzene)

By formula: Br- + C6H3N3O6 = (Br- • C6H3N3O6)

Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/APaul and Kebarle, 1991gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°54.8 ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff at 423 K, ΔSaff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
54.8423.PHPMSPaul and Kebarle, 1991gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M

(Bromine anion • Carbon dioxide) + Carbon dioxide = (Bromine anion • 2Carbon dioxide)

By formula: (Br- • CO2) + CO2 = (Br- • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°21. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°25. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Bromine anion + Carbon dioxide = (Bromine anion • Carbon dioxide)

By formula: Br- + CO2 = (Br- • CO2)

Quantity Value Units Method Reference Comment
ΔrH°22. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995, 2gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
ΔrH°28. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°69.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°7.5 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Bromine anion • 2Methyl Alcohol) + Methyl Alcohol = (Bromine anion • 3Methyl Alcohol)

By formula: (Br- • 2CH4O) + CH4O = (Br- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°39.7 ± 2.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°44.4 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°90.4J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°17.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°18. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion • Methyl Alcohol) + Methyl Alcohol = (Bromine anion • 2Methyl Alcohol)

By formula: (Br- • CH4O) + CH4O = (Br- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°50.21 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°52.3 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°86.6J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°23.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°26. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

Bromine anion + Methane, bromo- = (Bromine anion • Methane, bromo-)

By formula: Br- + CH3Br = (Br- • CH3Br)

Quantity Value Units Method Reference Comment
ΔrH°46.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrH°38.5 ± 2.1kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°58.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°19.2 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrG°20.9 ± 3.3kJ/molTDAsDougherty and Roberts, 1974gas phase; B

Bromine anion + Ethene, tetrafluoro- = C2BrF4-

By formula: Br- + C2F4 = C2BrF4-

Quantity Value Units Method Reference Comment
ΔrH°29.7 ± 2.1kJ/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B
Quantity Value Units Method Reference Comment
ΔrG°9.7 ± 2.1kJ/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B

Bromine anion + Propane, 2-bromo-2-methyl- = (Bromine anion • Propane, 2-bromo-2-methyl-)

By formula: Br- + C4H9Br = (Br- • C4H9Br)

Quantity Value Units Method Reference Comment
ΔrH°65.3 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrH°51.88kJ/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°80.8J/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°30.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrG°28.0kJ/molTDAsDougherty, 1974gas phase; B

Bromine anion + Ethyl bromide = (Bromine anion • Ethyl bromide)

By formula: Br- + C2H5Br = (Br- • C2H5Br)

Quantity Value Units Method Reference Comment
ΔrH°50.2 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrH°48.53kJ/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°80.3J/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°24.7 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrG°24.7kJ/molTDAsDougherty, 1974gas phase; B

Bromine anion + Propane, 2-bromo- = (Bromine anion • Propane, 2-bromo-)

By formula: Br- + C3H7Br = (Br- • C3H7Br)

Quantity Value Units Method Reference Comment
ΔrH°59.4 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrH°51.04kJ/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°83.3J/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°26.4 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
ΔrG°26.4kJ/molTDAsDougherty, 1974gas phase; B

Bromine anion + Benzene, nitroso- = (Bromine anion • Benzene, nitroso-)

By formula: Br- + C6H5NO = (Br- • C6H5NO)

Quantity Value Units Method Reference Comment
ΔrH°57.3 ± 7.5kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B
Quantity Value Units Method Reference Comment
ΔrG°22. ± 4.2kJ/molIMREPaul and Kebarle, 1991gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B

Bromine anion + Xenon = (Bromine anion • Xenon)

By formula: Br- + Xe = (Br- • Xe)

Quantity Value Units Method Reference Comment
ΔrH°15.1 ± 1.3kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; B
ΔrH°12.1 ± 0.42kJ/molLPESYourshaw, Lenzer, et al., 1998gas phase; Given: 0.12692(.0005) eV; B
ΔrH°14.2kJ/molMoblGatland, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrG°-4.9 ± 1.3kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; B

Bromine anion + Hydrogen cyanide = (Bromine anion • Hydrogen cyanide)

By formula: Br- + CHN = (Br- • CHN)

Quantity Value Units Method Reference Comment
ΔrH°81.2 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
ΔrH°66.9 ± 8.4kJ/molEstLarson and McMahon, 1984gas phase; Extrapolated from other halide data; B
Quantity Value Units Method Reference Comment
ΔrS°82.8J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°56.5 ± 6.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Bromine anion + Benzaldehyde = (Bromine anion • Benzaldehyde)

By formula: Br- + C7H6O = (Br- • C7H6O)

Quantity Value Units Method Reference Comment
ΔrH°55.2kJ/molPHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°84.J/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

(Bromine anion • Sulfur dioxide) + Hydrogen bromide = (Bromine anion • Hydrogen bromide • Sulfur dioxide)

By formula: (Br- • O2S) + HBr = (Br- • HBr • O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°51.0kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M
Quantity Value Units Method Reference Comment
ΔrS°80.3J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M

(Bromine anion • Sulfur dioxide) + Hydrogen chloride = (Bromine anion • Hydrogen chloride • Sulfur dioxide)

By formula: (Br- • O2S) + HCl = (Br- • HCl • O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°93.7kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M

(Bromine anion • 9Methyl Alcohol) + Methyl Alcohol = (Bromine anion • 10Methyl Alcohol)

By formula: (Br- • 9CH4O) + CH4O = (Br- • 10CH4O)

Quantity Value Units Method Reference Comment
ΔrH°33. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°4.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

Bromine anion + Hydrogen chloride = (Bromine anion • Hydrogen chloride)

By formula: Br- + HCl = (Br- • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°82.0 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°92.0J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Br-)SO2; M
Quantity Value Units Method Reference Comment
ΔrG°54. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

(Bromine anion • 8Methyl Alcohol) + Methyl Alcohol = (Bromine anion • 9Methyl Alcohol)

By formula: (Br- • 8CH4O) + CH4O = (Br- • 9CH4O)

Quantity Value Units Method Reference Comment
ΔrH°34. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°5.4 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Bromine anion • 4Acetonitrile) + Acetonitrile = (Bromine anion • 5Acetonitrile)

By formula: (Br- • 4C2H3N) + C2H3N = (Br- • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°35.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°24.3 ± 3.8kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°92.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°7.5 ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Bromine anion • 5Acetonitrile) + Acetonitrile = (Bromine anion • 6Acetonitrile)

By formula: (Br- • 5C2H3N) + C2H3N = (Br- • 6C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°33.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°23. ± 4.2kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.0 ± 3.8kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Bromine anion • 6Acetonitrile) + Acetonitrile = (Bromine anion • 7Acetonitrile)

By formula: (Br- • 6C2H3N) + C2H3N = (Br- • 7C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°32.2 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°13. ± 4.6kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°95.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

Bromine anion + Ammonia = (Bromine anion • Ammonia)

By formula: Br- + H3N = (Br- • H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°32.2 ± 0.42kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.37 ± 0.84kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B

Bromine anion + Dimethyl Sulfoxide = (Bromine anion • Dimethyl Sulfoxide)

By formula: Br- + C2H6OS = (Br- • C2H6OS)

Quantity Value Units Method Reference Comment
ΔrH°72.38kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
ΔrH°72.0kJ/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°89.5J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°45.61kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Determination of the Stabilities and Structures of X-(C6H6) Clusters (X = Cl, Br, and I), Chem. Phys. Lett., 1988, 147, 2-3, 174, https://doi.org/10.1016/0009-2614(88)85078-4 . [all data]

Paul and Kebarle, 1991
Paul, G.J.C.; Kebarle, P., Stabilities of Complexes of Br- with Substituted Benzenes (SB) Based on Determinations of the Gas-Phase Equilibria Br- + SB = (BrSB)-, J. Am. Chem. Soc., 1991, 113, 4, 1148, https://doi.org/10.1021/ja00004a014 . [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

Hiraoka, Mizuse, et al., 1988, 2
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Hiraoka, Mizure, et al., 1988
Hiraoka, K.; Mizure, S.; Yamabe, S.; Nakatsuji, Y., Gas Phase Clustering Reactions of CN- and CH2CN- with MeCN, Chem. Phys. Lett., 1988, 148, 6, 497, https://doi.org/10.1016/0009-2614(88)80320-8 . [all data]

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO3- and NO3- association complexes with HNO3 and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Arnold, Bradforth, et al., 1995, 2
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]

Dougherty and Roberts, 1974
Dougherty, R.C.; Roberts, J.D., SN2 reactions in the gas phase. Nucleophilicity effects, Org. Mass Spectrom., 1974, 8, 81. [all data]

Hiraoka, Mochizuki, et al., 2008
Hiraoka, K.; Mochizuki, N.; Wada, A.; Okada, H.; Ichikawa, T.; Asakawa, D.; Yazawa, I., Gas-phase ion/molecule reactions in C2F4, Int. J. Mass Spectrom., 2008, 272, 1, 22-28, https://doi.org/10.1016/j.ijms.2007.12.013 . [all data]

Curtiss, Raghavachari, et al., 7374
Curtiss, L.A.; Raghavachari, K.; Redfern, P.C.; Pople, J.A., Assesment of Gaussian-3 and density Functional Theories for a larger experimental test set, J. Chem. Phys. 112 (2000), 7374. [all data]

Dougherty, 1974
Dougherty, R.C., SN2 reactions in the gas phase. Alkyl group structural effects, Org. Mass Spectrom., 1974, 8, 85. [all data]

Wada, Kikkawa, et al., 2007
Wada, A.; Kikkawa, A.; Sugiyama, T.; Hiraoka, K., Thermochemical Stabilities of the Gas-phase Cluster Ions of Halide Ions with Rare Gas Atoms, Int. J. Mass Spectrom.., 2007, 267, 1-3, 284-287, https://doi.org/10.1016/j.ijms.2007.02.053 . [all data]

Yourshaw, Lenzer, et al., 1998
Yourshaw, I.; Lenzer, T.; Reiser, G.; Neumark, D.M., Zero electron kinetic energy spectroscopy of the KrBr-, XeBr-, and KrCl- anions, J. Chem. Phys., 1998, 109, 13, 5247-5256, https://doi.org/10.1063/1.477141 . [all data]

Gatland, 1984
Gatland, I.R., Determination of Ion-Atom Potentials from Mobility Experiments. in Swarms of Ions and Electrons In Gases, W. Lindinger, Ed., Springer-Verlag, NY,, 1984, 44. [all data]

Meot-ner, Cybulski, et al., 1988
Meot-ner, M.; Cybulski, S.M.; Scheiner, S.; Liebman, J.F., Is CN- Significantly Anisotropic? Comparison of CN- vs. Cl-: Clustering with HCN and Condensed Phase Thermochemistry, J. Phys. Chem., 1988, 92, 10, 2738, https://doi.org/10.1021/j100321a009 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Gas phase bihalide and pseudohalide ions. An ICR determination of hydrogen bond energies in XHY- species (X,Y = F, Cl, Br, CN), Inorg. Chem., 1984, 23, 2029. [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Evans, Keesee, et al., 1987
Evans, D.H.; Keesee, R.G.; Castleman Jr., The Association of Ammonia with Halide Ions in the Gas Phase, J. Chem. Phys., 1987, 86, 5, 2927, https://doi.org/10.1063/1.452043 . [all data]

Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P., Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents, J. Am. Chem. Soc., 1984, 106, 6140. [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References