Iodide

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Iodide + Water = (Iodide • Water)

By formula: I- + H2O = (I- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°43. ± 3.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°64.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°80.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
ΔrS°68.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°23. ± 1.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • Water) + Water = (Iodide • 2Water)

By formula: (I- • H2O) + H2O = (I- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°41.4 ± 0.84kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
ΔrH°39.7kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
ΔrH°39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°41. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
ΔrH°41. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°73.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°84.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
ΔrS°79.5J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°17. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Iodide + Carbon dioxide = (Iodide • Carbon dioxide)

By formula: I- + CO2 = (I- • CO2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 7.5kJ/molN/APiani, Becucci, et al., 2008gas phase; Stated electron affinity is the Vertical Detachment Energy; B
ΔrH°17. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°20. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
ΔrH°13.4kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°23.4 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°56.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
ΔrS°76.1J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
ΔrG°3.3 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B,M
ΔrG°1.7 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Iodide • 2Water) + Water = (Iodide • 3Water)

By formula: (I- • 2H2O) + H2O = (I- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°38.9 ± 1.3kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
ΔrH°36. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
ΔrH°38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°39. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
ΔrH°39. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°85.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°87.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
ΔrS°89.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°12.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
ΔrG°13.0 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Iodide + Acetonitrile = (Iodide • Acetonitrile)

By formula: I- + C2H3N = (I- • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°49.8 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
ΔrH°46.4 ± 1.7kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°46.4 ± 4.6kJ/molLPESDessent, Bailey, et al., 1995gas phase; B
ΔrH°46.02 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°50.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°57.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°76.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°27. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B
ΔrG°28. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B
ΔrG°28.9 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Methyl Alcohol = (Iodide • Methyl Alcohol)

By formula: I- + CH4O = (I- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°49.79 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°47.3 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
ΔrH°46.9kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrH°46.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°71.5J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrS°74.5J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°24.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°25. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B
ΔrG°24. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

Iodide + Methane, iodo- = (Iodide • Methane, iodo-)

By formula: I- + CH3I = (I- • CH3I)

Quantity Value Units Method Reference Comment
ΔrH°35.7 ± 0.84kJ/molN/AVan Duzor, Wei, et al., 2010gas phase; B
ΔrH°32.6 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
ΔrH°35.1 ± 2.1kJ/molN/AArnold, Neumark, et al., 1995gas phase; ZEKE data, shift relative to bare I-; B
ΔrH°34.7 ± 2.1kJ/molPDisCyr, Bishea, et al., 1992gas phase; B
ΔrH°38. ± 8.4kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°68.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°11.4 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
ΔrG°17.2 ± 1.3kJ/molTDAsDougherty and Roberts, 1974gas phase; B

(Iodide • Acetonitrile) + Acetonitrile = (Iodide • 2Acetonitrile)

By formula: (I- • C2H3N) + C2H3N = (I- • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°43.51 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°46.4 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°46.4 ± 1.7kJ/molN/ADessent, Bailey, et al., 1995gas phase; Vertical Detachment Energy: 2.25±0.08 eV.; B
ΔrH°43.93kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°77.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°87.0J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°20.5 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°18.0kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Iodide + Sulfur dioxide = (Iodide • Sulfur dioxide)

By formula: I- + O2S = (I- • O2S)

Quantity Value Units Method Reference Comment
ΔrH°59.8 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
ΔrH°53.97 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°73.6J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
ΔrS°84.5J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°38. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B
ΔrG°7.11 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
ΔrG°28.5 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • 2Carbon dioxide) + Carbon dioxide = (Iodide • 3Carbon dioxide)

By formula: (I- • 2CO2) + CO2 = (I- • 3CO2)

Quantity Value Units Method Reference Comment
ΔrH°9.20kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°19. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°77.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide • 4Carbon dioxide) + Carbon dioxide = (Iodide • 5Carbon dioxide)

By formula: (I- • 4CO2) + CO2 = (I- • 5CO2)

Quantity Value Units Method Reference Comment
ΔrH°7.11kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°18. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-5.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide • Carbon dioxide) + Carbon dioxide = (Iodide • 2Carbon dioxide)

By formula: (I- • CO2) + CO2 = (I- • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°20. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
ΔrH°10.9kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Quantity Value Units Method Reference Comment
ΔrS°72.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide • 3Water) + Water = (Iodide • 4Water)

By formula: (I- • 3H2O) + H2O = (I- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°29. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.8 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°9.2 ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Iodide • 5Carbon dioxide) + Carbon dioxide = (Iodide • 6Carbon dioxide)

By formula: (I- • 5CO2) + CO2 = (I- • 6CO2)

Quantity Value Units Method Reference Comment
ΔrH°13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°7.53kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°18.kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KN/AHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M

(Iodide • 2Acetonitrile) + Acetonitrile = (Iodide • 3Acetonitrile)

By formula: (I- • 2C2H3N) + C2H3N = (I- • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°40.6 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°38.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°83.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°92.5J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°13.4 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°11.3kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Iodide • 4Water) + Water = (Iodide • 5Water)

By formula: (I- • 4H2O) + H2O = (I- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°37.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
ΔrH°17.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°6.28kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

Iodide + Ethanol = (Iodide • Ethanol)

By formula: I- + C2H6O = (I- • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.39 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°50.6 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°25.6kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B
ΔrG°25. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

(Iodide • 3Carbon dioxide) + Carbon dioxide = (Iodide • 4Carbon dioxide)

By formula: (I- • 3CO2) + CO2 = (I- • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°7.53kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°19. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°-4.2 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Iodide + Iodine = I3-

By formula: I- + I2 = I3-

Quantity Value Units Method Reference Comment
ΔrH°136. ± 10.kJ/molN/ATaylor, Asmis, et al., 1999gas phase; B
ΔrH°126. ± 5.9kJ/molCIDTDo, Klein, et al., 1997gas phase; B
ΔrH°356.1kJ/molTherFinch, Gates, et al., 1977gas phase; This value is far more bound than expected from other studies; B
ΔrH°136.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; ΔS(EA)=2.8; B
Quantity Value Units Method Reference Comment
ΔrG°94.14kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; ΔS(EA)=2.8; B

Iodide + Phenol, 4-chloro- = (Iodide • Phenol, 4-chloro-)

By formula: I- + C6H5ClO = (I- • C6H5ClO)

Quantity Value Units Method Reference Comment
ΔrH°85.8 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°48.5 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
48.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-chloro- = (Iodide • Phenol, 3-chloro-)

By formula: I- + C6H5ClO = (I- • C6H5ClO)

Quantity Value Units Method Reference Comment
ΔrH°88.3 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°51.0 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
51.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 4-fluoro- = (Iodide • Phenol, 4-fluoro-)

By formula: I- + C6H5FO = (I- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°82.0 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°44.8 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
43.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-fluoro- = (Iodide • Phenol, 3-fluoro-)

By formula: I- + C6H5FO = (I- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°81.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°43.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
44.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-nitro- = (Iodide • Phenol, 3-nitro-)

By formula: I- + C6H5NO3 = (I- • C6H5NO3)

Quantity Value Units Method Reference Comment
ΔrH°97.1 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°59.8 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 4-hydroxy- = (Iodide • Benzonitrile, 4-hydroxy-)

By formula: I- + C7H5NO = (I- • C7H5NO)

Quantity Value Units Method Reference Comment
ΔrH°99.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°62.3 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
62.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 3-hydroxy- = (Iodide • Benzonitrile, 3-hydroxy-)

By formula: I- + C7H5NO = (I- • C7H5NO)

Quantity Value Units Method Reference Comment
ΔrH°96.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°59.0 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + p-Cresol = (Iodide • p-Cresol)

By formula: I- + C7H8O = (I- • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°68.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°31. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol = (Iodide • Phenol)

By formula: I- + C6H6O = (I- • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°72.4 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°35. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Hydrogen bromide = (Iodide • Hydrogen bromide)

By formula: I- + HBr = (I- • HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°67.4 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
ΔrG°43. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
42.7300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen iodide = (Iodide • Hydrogen iodide)

By formula: I- + HI = (I- • HI)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°71.1 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°102.J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
ΔrG°41. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen cation = Hydrogen iodide

By formula: I- + H+ = HI

Quantity Value Units Method Reference Comment
ΔrH°1315.24 ± 0.084kJ/molD-EAPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
ΔrH°1312.1kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; ΔS(EA)=5.0; B
Quantity Value Units Method Reference Comment
ΔrG°1294.03 ± 0.25kJ/molH-TSPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
ΔrG°1290.8kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; ΔS(EA)=5.0; B

Iodide + Hydrogen chloride = (Iodide • Hydrogen chloride)

By formula: I- + HCl = (I- • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°61.9 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
ΔrH°59.4kJ/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°83.7J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
ΔrS°95.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°37. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B

(Iodide • 2Nitrous oxide) + Nitrous oxide = (Iodide • 3Nitrous oxide)

By formula: (I- • 2N2O) + N2O = (I- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°13.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°63.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Iodide • 2Methyl Alcohol) + Methyl Alcohol = (Iodide • 3Methyl Alcohol)

By formula: (I- • 2CH4O) + CH4O = (I- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°32.2 ± 2.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°93.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°14.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°13. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide • Methyl Alcohol) + Methyl Alcohol = (Iodide • 2Methyl Alcohol)

By formula: (I- • CH4O) + CH4O = (I- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°39.7 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°46.4 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°94.6J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°17.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°18. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

Iodide + Formic acid = (Iodide • Formic acid)

By formula: I- + CH2O2 = (I- • CH2O2)

Quantity Value Units Method Reference Comment
ΔrH°79.1 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
ΔrH°54.0 ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; Authors suggest real value somewhere between this and Caldwell and Kebarle, 1984; B
Quantity Value Units Method Reference Comment
ΔrS°86.6J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°53.1 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Isopropyl Alcohol = (Iodide • Isopropyl Alcohol)

By formula: I- + C3H8O = (I- • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°54.81 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°51.0 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°26.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + 2-Propanol, 2-methyl- = (Iodide • 2-Propanol, 2-methyl-)

By formula: I- + C4H10O = (I- • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°54.8 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°50.6 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°78.2J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°25.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Ammonia = (Iodide • Ammonia)

By formula: I- + H3N = (I- • H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°31.0 ± 1.3kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
ΔrH°31. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.0 ± 2.5kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B

(Iodide • 6Carbon dioxide) + Carbon dioxide = (Iodide • 7Carbon dioxide)

By formula: (I- • 6CO2) + CO2 = (I- • 7CO2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°7.95kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide • 7Carbon dioxide) + Carbon dioxide = (Iodide • 8Carbon dioxide)

By formula: (I- • 7CO2) + CO2 = (I- • 8CO2)

Quantity Value Units Method Reference Comment
ΔrH°13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°7.95kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide • Nitrous oxide) + Nitrous oxide = (Iodide • 2Nitrous oxide)

By formula: (I- • N2O) + N2O = (I- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°14. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Iodide • 7Methyl Alcohol) + Methyl Alcohol = (Iodide • 8Methyl Alcohol)

By formula: (I- • 7CH4O) + CH4O = (I- • 8CH4O)

Quantity Value Units Method Reference Comment
ΔrH°38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Iodide • 3Acetonitrile) + Acetonitrile = (Iodide • 4Acetonitrile)

By formula: (I- • 3C2H3N) + C2H3N = (I- • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°32.6 ± 0.42kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°31.0 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°80.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.4 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Iodide • 4Acetonitrile) + Acetonitrile = (Iodide • 5Acetonitrile)

By formula: (I- • 4C2H3N) + C2H3N = (I- • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°29.7 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°44.4 ± 3.8kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.9 ± 5.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Nitrous oxide = (Iodide • Nitrous oxide)

By formula: I- + N2O = (I- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°16. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Iodide + Benzene = (Iodide • Benzene)

By formula: I- + C6H6 = (I- • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°26. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°38. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°59.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

Iodide + Dimethyl Sulfoxide = (Iodide • Dimethyl Sulfoxide)

By formula: I- + C2H6OS = (I- • C2H6OS)

Quantity Value Units Method Reference Comment
ΔrH°65.69kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
ΔrH°67.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°38.5kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

Iodide = BrI2-

By formula: I- = BrI2-

Quantity Value Units Method Reference Comment
ΔrH°141.8 ± 0.96kJ/molPDisCrider, Harrison, et al., 2011gas phase; B
ΔrH°149.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; ΔS(EA)=4.5; B
Quantity Value Units Method Reference Comment
ΔrG°107.9kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; ΔS(EA)=4.5; B

Iodide + Xenon = IXe-

By formula: I- + Xe = IXe-

Quantity Value Units Method Reference Comment
ΔrH°6.69kJ/molN/ALenzer, Furlanetto, et al., 1998gas phase; B
ΔrH°11.7kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
ΔrG°-8.24kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase, Chem. Phys. Lett., 1980, 74, 139. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Piani, Becucci, et al., 2008
Piani, G.; Becucci, M.; Bowen, M.S.; Oakman, J.; Hu, Q.; Continetti, R.E., Photodetachment and dissociation dynamics of microsolvated iodide clusters, Phys. Scripta, 2008, 78, 5, 058110, https://doi.org/10.1088/0031-8949/78/05/058110 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M., Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters, J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246 . [all data]

Keesee, Lee, et al., 1980
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Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Dessent, Bailey, et al., 1995
Dessent, C.E.H.; Bailey, C.G.; Johnson, M.A., Dipole-bound excited states of the I-center dot CH3CN and I-center dot(CH3CN)2 ion-molecule complexes: Evidence for asymmetric solvation, J. Chem. Phys., 1995, 103, 6, 2006, https://doi.org/10.1063/1.469727 . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Caldwell and Kebarle, 1984
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Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

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Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Van Duzor, Wei, et al., 2010
Van Duzor, M.; Wei, J.; Mbaiwa, F.; Mabbs, R., I-center dot CH3X (X=Cl, Br, I) photodetachment: The effect of electron-molecule interactions in cluster anion photodetachment spectra and angular distributions, J. Chem. Phys., 2010, 133, 14, 144303, https://doi.org/10.1063/1.3487739 . [all data]

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Hiraoka, K.; Fujita, K.; Ishida, M.; Ichikawa, T.; Okada, H.; Hiizumi, K.; Wada, A.; Takao, K.; Yamabe, S.; Tsuchida, N., Gas-phase Ion/Molecule Reactions in C5F8, J. Phys. Chem. A (2005), 1905, 109, 6, 1049-1056., https://doi.org/10.1021/jp040251k . [all data]

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Cyr, D.M.; Bishea, G.A.; Scarton, M.G.; Johnson, M.A., Observation of Charge-Transfer Excited States in the I-.CH3I, I-.CH3Br, and I-.CH2Br2 S(N)2 Reaction Intermediates Using Photofragmentation, J. Chem. Phys., 1992, 97, 8, 5911, https://doi.org/10.1063/1.463752 . [all data]

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Taylor, T.R.; Asmis, K.R.; Zanni, M.T.; Neumark, D.M., Characterization of the I-3 radical by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 16, 7607-7609, https://doi.org/10.1063/1.478672 . [all data]

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Do, K.; Klein, T.P.; Pommerening, C.A.; Sunderlin, L.S., A New Flowing Afterglow-Guided Ion Beam Tandem Mass Spectrometer. Applications to the Thermochemistry of Polyiodide Ions, J. Am. Soc. Mass Spectrom., 1997, 8, 7, 688, https://doi.org/10.1016/S1044-0305(97)00116-5 . [all data]

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Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

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Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

Pelaez, Blondel, et al., 2009
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Notes

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