p,p,p-Trimethylphosphine-borane

• Formula: C₃H₁₂BP
• Molecular weight: 89.912
• IUPAC Standard InChI: InChI=1S/C3H9P.BH3/c1-4(2)3;/h1-3H3;1H3 Copy

  
• IUPAC Standard InChIKey: XDZLUCBMKWYLJG-UHFFFAOYSA-N Copy
• CAS Registry Number: 1898-77-7
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

De-protonation reactions

C₃H₁₁BP^- +  =

By formula: C₃H₁₁BP^- + H⁺ = C₃H₁₂BP

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cowley, Kemp, et al., 1982
Cowley, A.H.; Kemp, R.A.; Lattman, M.; McKee, M.L., Lewis base behavior of methylated and fluorinated phosphines. A photoelectron spectroscopic investigation, Inorg. Chem., 1982, 21, 85. [all data]

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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