p,p,p-Trimethylphosphine-borane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
10.15PECowley, Kemp, et al., 1982Vertical value; LBLHLM

De-protonation reactions

C3H11BP- + Hydrogen cation = p,p,p-Trimethylphosphine-borane

By formula: C3H11BP- + H+ = C3H12BP

Quantity Value Units Method Reference Comment
Deltar1567. ± 8.8kJ/molG+TSRen, Workman, et al., 1998gas phase; B
Quantity Value Units Method Reference Comment
Deltar1529. ± 8.4kJ/molIMRBRen, Workman, et al., 1998gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cowley, Kemp, et al., 1982
Cowley, A.H.; Kemp, R.A.; Lattman, M.; McKee, M.L., Lewis base behavior of methylated and fluorinated phosphines. A photoelectron spectroscopic investigation, Inorg. Chem., 1982, 21, 85. [all data]

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]


Notes

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