dilithium oxide
- Formula: Li2O
- Molecular weight: 29.881
- IUPAC Standard InChIKey: XZIUWXMPQBQHMC-UHFFFAOYSA-N
- CAS Registry Number: 12057-24-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Dilithium monoxide
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to Li2O+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 1206. | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 1175.3 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.0 | EI | Ikeda, Tamaki, et al., 1982 | LBLHLM |
6.4 ± 0.2 | EI | Nakagawa, Asano, et al., 1981 | LLK |
6.19 ± 0.20 | EI | Hildenbrand, 1972 | LLK |
6.3 ± 1.0 | EI | Yamdagni, Pupp, et al., 1970 | RDSH |
7.0 ± 0.5 | EI | Zmbov, Ficalora, et al., 1968 | RDSH |
6.9 ± 0.3 | EI | White, Seshadri, et al., 1963 | RDSH |
6.8 ± 0.2 | EI | Berkowitz, Chupka, et al., 1959 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Ikeda, Tamaki, et al., 1982
Ikeda, Y.; Tamaki, M.; Matsumoto, G.; Amioka, K.; Mizuno, T.,
Mass spectrometric studies of lithium-containing oxides at high temperatures,
Spectrochim. Acta Part B, 1982, 37, 647. [all data]
Nakagawa, Asano, et al., 1981
Nakagawa, H.; Asano, M.; Kubo, K.,
Mass spectrometric study of the vaporization of lithium metasilicate,
J. Nucl. Mater., 1981, 102, 292. [all data]
Hildenbrand, 1972
Hildenbrand, D.L.,
Thermochemistry of the molecular species LiO, LiO+, and Li2O+.,
J. Chem. Phys., 1972, 57, 4556. [all data]
Yamdagni, Pupp, et al., 1970
Yamdagni, R.; Pupp, C.; Porter, R.F.,
Mass spectrometric study of the evaporation of lithium and sodium molybdates and tungstates,
J. Inorg. Nucl. Chem., 1970, 32, 3509. [all data]
Zmbov, Ficalora, et al., 1968
Zmbov, K.F.; Ficalora, P.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. XXVIII. Gaseous ternary oxides, LiMO and LiMO2,
J. Inorg. Nucl. Chem., 1968, 30, 2059. [all data]
White, Seshadri, et al., 1963
White, D.; Seshadri, K.S.; Dever, D.F.; Mann, D.E.; Linevski, M.J.,
Infrared spectra and the structures and thermodynamics of gaseous LiO, Li2O, and Li2O2,
J. Chem. Phys., 1963, 39, 2463. [all data]
Berkowitz, Chupka, et al., 1959
Berkowitz, J.; Chupka, W.A.; Blue, G.D.; Margrave, J.L.,
Mass spectrometric study of the sublimation of lithium oxide,
J. Phys. Chem., 1959, 63, 644. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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