Tungsten, (carbonothioyl)pentacarbonyl-
- Formula: C6O5SW
- Molecular weight: 367.97
- IUPAC Standard InChI: InChI=1S/5CH2O.CHS.W/c6*1-2;/h5*1H2;1H;
- IUPAC Standard InChIKey: DCCJEEMIWCMKNV-UHFFFAOYSA-N
- CAS Registry Number: 50358-92-4
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.22 ± 0.01 | EI | Michels, Flesch, et al., 1980 | |
| 8.08 | PE | Lichtenberger and Fenske, 1976 | Vertical value |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| COW+ | 19.48 ± 0.21 | 4CO+CS | EI | Michels, Flesch, et al., 1980 | |
| CSW+ | 18.07 ± 0.04 | 5CO | EI | Michels, Flesch, et al., 1980 | |
| C2OSW+ | 15.83 ± 0.04 | 4CO | EI | Michels, Flesch, et al., 1980 | |
| C2O2W+ | 17.21 ± 0.27 | 3CO+CS | EI | Michels, Flesch, et al., 1980 | |
| C3O2SW+ | 13.46 ± 0.04 | 3CO | EI | Michels, Flesch, et al., 1980 | |
| C3O3W+ | 14.86 ± 0.11 | 2CO+CS | EI | Michels, Flesch, et al., 1980 | |
| C4O3SW+ | 11.61 ± 0.04 | 2CO | EI | Michels, Flesch, et al., 1980 | |
| C4O4W+ | 13.12 ± 0.11 | CO+CS | EI | Michels, Flesch, et al., 1980 | |
| C5O4SW+ | 9.74 ± 0.04 | CO | EI | Michels, Flesch, et al., 1980 | |
| C5O5W+ | 11.46 ± 0.14 | CS | EI | Michels, Flesch, et al., 1980 | |
| W+ | 21.97 ± 0.13 | 5CO+CS | EI | Michels, Flesch, et al., 1980 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Michels, Flesch, et al., 1980
Michels, G.D.; Flesch, G.D.; Svec, H.J.,
Comparative mass spectrometry of the group 6B hexacarbonyls and pentacarbonyl thiocarbonyls,
Inorg. Chem., 1980, 19, 479. [all data]
Lichtenberger and Fenske, 1976
Lichtenberger, D.L.; Fenske, R.F.,
Electronic structure of transition metal thiocarbonyl complexes,
Inorg. Chem., 1976, 15, 2015. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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