Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

CuOH


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 18406.779 gas B-X 500 560 Trkula and Harris, 1983
Jarman, Fernando, et al., 1990
Wang and Steimle, 2011

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 15911.546 gas A-X Jarman, Fernando, et al., 1991

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 Bend 743 ± 1 gas LF Trkula and Harris, 1983
Tao, Mukarakate, et al., 2007
2 Bend 727.7 Ar IR Kauffman, Hauge, et al., 1985
3 CuO stretch 625 gas LF Tao, Mukarakate, et al., 2007
3 CuO stretch 632.7 Ar IR Kauffman, Hauge, et al., 1985

Additional references: Jacox, 1994, page 31; Jacox, 2003, page 27; Whitham, Ozeki, et al., 1999; Whitham, Ozeki, et al., 2000

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Trkula and Harris, 1983
Trkula, M.; Harris, D.O., Laser spectroscopy of the 1A´´--X 1A´ system of CuOH and CuOD, J. Chem. Phys., 1983, 79, 3, 1138, https://doi.org/10.1063/1.445916 . [all data]

Jarman, Fernando, et al., 1990
Jarman, C.N.; Fernando, W.T.M.L.; Bernath, P.F., Further analysis of the system of CuOH and CuOD, J. Mol. Spectrosc., 1990, 144, 2, 286, https://doi.org/10.1016/0022-2852(90)90215-C . [all data]

Wang and Steimle, 2011
Wang, F.; Steimle, T.C., Optical Stark spectroscopy of the B[sup 1]A[sup ´´](000)<--X[sup 1]A[sup ´](000) system of copper hydroxide, J. Chem. Phys., 2011, 134, 1, 014303, https://doi.org/10.1063/1.3517057 . [all data]

Jarman, Fernando, et al., 1991
Jarman, C.N.; Fernando, W.T.M.L.; Bernath, P.F., Laser spectroscopy of the system of CuOH and CuOD, J. Mol. Spectrosc., 1991, 145, 1, 151, https://doi.org/10.1016/0022-2852(91)90359-I . [all data]

Tao, Mukarakate, et al., 2007
Tao, C.; Mukarakate, C.; Reid, S.A., Single vibronic level emission spectroscopy and fluorescence lifetime of the system of CuOH and CuOD, Chem. Phys. Lett., 2007, 449, 4-6, 282, https://doi.org/10.1016/j.cplett.2007.10.084 . [all data]

Kauffman, Hauge, et al., 1985
Kauffman, J.W.; Hauge, R.H.; Margrave, J.L., Studies of reactions of atomic and diatomic chromium, manganese, iron, cobalt, nickel, copper, and zinc with molecular water at 15 K, J. Phys. Chem., 1985, 89, 16, 3541, https://doi.org/10.1021/j100262a023 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Whitham, Ozeki, et al., 1999
Whitham, C.J.; Ozeki, H.; Saito, S., Microwave spectroscopic detection of transition metal hydroxides: CuOH and AgOH, J. Chem. Phys., 1999, 110, 23, 11109, https://doi.org/10.1063/1.479051 . [all data]

Whitham, Ozeki, et al., 2000
Whitham, C.J.; Ozeki, H.; Saito, S., Microwave spectra of CuOD and AgOD: Molecular structure and harmonic force field of CuOH and AgOH, J. Chem. Phys., 2000, 112, 2, 641, https://doi.org/10.1063/1.480725 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References