Tricopper trichloride

Formula: Cl₃Cu₃
Molecular weight: 296.997
CAS Registry Number: 11093-65-5
Information on this page:
Options:
- Switch to calorie-based units

Gas phase ion energetics data

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to Cl₃Cu₃⁺ (ion structure unspecified)

Ionization energy determinations

IE (eV)	Method	Reference	Comment
9.5	EI	Williams, 1982	LBLHLM
9.6	EI	Bloom and Williams, 1981	LLK
10.0 ± 0.3	EI	Bernauer, Busse, et al., 1979	LLK
9.6 ± 0.5	EI	Wagner, Robert, et al., 1974	LLK
9.9 ± 0.5	EI	Guido, Balducci, et al., 1971	LLK
10.0	PE	MacNaughton, Bloor, et al., 1981	Vertical value; LLK
9.52	PE	Berkowitz, Batson, et al., 1980	Vertical value; LLK

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
ClCu⁺	20.0 ± 0.5	CuCl+Cu+Cl	EI	Wagner, Robert, et al., 1974	LLK
ClCu⁺	23.3 ± 0.5	2Cu⁺²Cl	EI	Wagner, Robert, et al., 1974	LLK
ClCu⁺	16.0 ± 0.05	2CuCl	EI	Wagner, Robert, et al., 1974	LLK
ClCu₂⁺	12.0 ± 0.5	CuCl₂	EI	Guido, Balducci, et al., 1971	LLK
Cl₂Cu₂⁺	16.7 ± 0.5	Cu+Cl	EI	Wagner, Robert, et al., 1974	LLK
Cl₂Cu₂⁺	13.5 ± 0.5	CuCl	EI	Wagner, Robert, et al., 1974	LLK
Cl₂Cu₃⁺	12.6	Cl	EI	Bloom and Williams, 1981	LLK
Cl₂Cu₃⁺	12.8 ± 0.3	Cl	EI	Bernauer, Busse, et al., 1979	LLK
Cu⁺	17.9 ± 0.5	?	EI	Wagner, Robert, et al., 1974	LLK
Cu₂⁺	18.1 ± 0.5	?	EI	Wagner, Robert, et al., 1974	LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Williams, 1982
Williams, D.J., Mass spectrometric study of the vaporization of the alkali chloride-cuprous chloride systems, Aust. J. Chem., 1982, 35, 1531. [all data]

Bloom and Williams, 1981
Bloom, H.; Williams, D.J., A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI, J. Chem. Phys., 1981, 75, 4636. [all data]

Bernauer, Busse, et al., 1979
Bernauer, O.; Busse, B.; Weil, K.G., Massenspektrometrische Untersuchungen an Kupfer- und Silber- Halogeniden IV: Die Systeme Ag_xCu_(1-x) (0=<X=<1) und AgCl_xBr_(1-x) (0=<X=<1), Ber. Bunsen-Ges. Phys. Chem., 1979, 83, 603. [all data]

Wagner, Robert, et al., 1974
Wagner, L.C.; Robert, P.; Grindstaff, Q.; Grimley, R.T., A mass spectrometric study of the fragmentation of the cuprous chloride vapor system, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 255. [all data]

Guido, Balducci, et al., 1971
Guido, M.; Balducci, G.; Gigli, G.; Spoliti, M., Mass spectrometric study of the vaporization of cuprous chloride and the dissociation energy of Cu₃Cl₃, Cu₄Cl₄, and Cu₅Cl₅, J. Chem. Phys., 1971, 55, 4566. [all data]

MacNaughton, Bloor, et al., 1981
MacNaughton, R.M.; Bloor, J.E.; Sherrod, R.E.; Schweitzer, G.K., The He(I) photoelectron psectra of some gaseous 3d-transition metal dihalides, J. Electron Spectrosc. Relat. Phenom., 1981, 22, 1. [all data]

Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L., Photoelectron spectroscopy of AgCl, AgBr, and AgI vapors, J. Chem. Phys., 1980, 72, 5829. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

Symbols used in this document:

AE Appearance energy
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
Customer support for NIST Standard Reference Data products.