Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

CCCN-


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 34730 ± 80 gas Yen, Garand, et al., 2010

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 2178.7 Ar IR EM Kolos, Gronowski, et al., 2008
Turowski, Gronowski, et al., 2008
1 2173.9 Kr IR EM Kolos, Gronowski, et al., 2008
Turowski, Gronowski, et al., 2008
2 1944.3 Ar IR EM Kolos, Gronowski, et al., 2008
Turowski, Gronowski, et al., 2008
2 1940.3 Kr IR EM Kolos, Gronowski, et al., 2008
Turowski, Gronowski, et al., 2008
3 877 Ar EM Turowski, Gronowski, et al., 2008
3 869 Kr EM Turowski, Gronowski, et al., 2008
Pi 4 538 ± 8 gas TPE Yen, Garand, et al., 2010
4 537 Kr EM Turowski, Gronowski, et al., 2008
5 208 ± 8 gas TPE Yen, Garand, et al., 2010

Additional references: Thaddeus, Gottlieb, et al., 2008; McCarthy and Thaddeus, 2008

Notes

dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yen, Garand, et al., 2010
Yen, T.A.; Garand, E.; Shreve, A.T.; Neumark, D.M., Anion Photoelectron Spectroscopy of C, J. Phys. Chem. A, 2010, 114, 9, 3215, https://doi.org/10.1021/jp9093996 . [all data]

Kolos, Gronowski, et al., 2008
Kolos, R.; Gronowski, M.; Botschwina, P., Matrix isolation IR spectroscopic and ab initio studies of C[sub 3]N[sup -] and related species, J. Chem. Phys., 2008, 128, 15, 154305, https://doi.org/10.1063/1.2902289 . [all data]

Turowski, Gronowski, et al., 2008
Turowski, M.; Gronowski, M.; Boye-Peronne, S.; Douin, S.; Moneron, L.; Crepin, C.; Kolos, R., The C[sub 3]N[sup -] anion: First detection of its electronic luminescence in rare gas solids, J. Chem. Phys., 2008, 128, 16, 164304, https://doi.org/10.1063/1.2904876 . [all data]

Thaddeus, Gottlieb, et al., 2008
Thaddeus, P.; Gottlieb, C.A.; Gupta, H.; Brunken, S.; McCarthy, M.C.; Agundez, M.; Guelin, M.; Cernicharo, J., Laboratory and Astronomical Detection of the Negative Molecular Ion C, Astrophys. J., 2008, 677, 2, 1132, https://doi.org/10.1086/528947 . [all data]

McCarthy and Thaddeus, 2008
McCarthy, M.C.; Thaddeus, P., High-resolution rotational spectroscopy of the carbon chain anions C[sub 3]N[sup -], C[sub 4]H[sup -], and C[sub 4]D[sup -], J. Chem. Phys., 2008, 129, 5, 054314, https://doi.org/10.1063/1.2960626 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References