OVO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21000 ± 800 gas Wu and Wang, 1998

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16421.2 gas B-X 560 655 Wu and Wang, 1998
Matsuda and Bernstein, 2005
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 1000.5 gas PI MPI Matsuda and Bernstein, 2005
2 Bend 289.6 gas PI MPI Matsuda and Bernstein, 2005

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 4840 ± 800 gas Wu and Wang, 1998

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 993.0 gas PE MPI Wu and Wang, 1998
Matsuda and Bernstein, 2005
1 Sym. stretch 946.3 w Ar IR Chertihin, Bare, et al., 1997
2 Bend 296.0 gas PI MPI Matsuda and Bernstein, 2005
b2 3 Asym. stretch 935.9 s Ar IR Chertihin, Bare, et al., 1997

Additional references: Jacox, 2003, page 104

Notes

wWeak
sStrong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu and Wang, 1998
Wu, H.; Wang, L.-S., A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4), J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966 . [all data]

Matsuda and Bernstein, 2005
Matsuda, Y.; Bernstein, E.R., Identification, Structure, and Spectroscopy of Neutral Vanadium Oxide Clusters, J. Phys. Chem. A, 2005, 109, 17, 3803, https://doi.org/10.1021/jp040718r . [all data]

Chertihin, Bare, et al., 1997
Chertihin, G.V.; Bare, W.D.; Andrews, L., Reactions of Laser-Ablated Vanadium Atoms with Dioxygen. Infrared Spectra of VO, VO, J. Phys. Chem. A, 1997, 101, 28, 5090, https://doi.org/10.1021/jp970559u . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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