BaNC

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 18016 T gas C-X 513 556 Pasternack and Dagdigian, 1976
Mikhailov, Wheeler, et al., 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 245 T gas LF Mikhailov, Wheeler, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 NC stretch 2048.9 Ar IR Lanzisera and Andrews, 1997
Π 2 Bend 70 gas LF Mikhailov, Wheeler, et al., 2003

Additional references: Jacox, 2003, page 60

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pasternack and Dagdigian, 1976
Pasternack, L.; Dagdigian, P.J., Laser-fluorescence study of the reactions of alkaline earth atoms with BrCN: Spectroscopic observation of the alkaline earth monocyanides, J. Chem. Phys., 1976, 65, 4, 1320, https://doi.org/10.1063/1.433228 . [all data]

Mikhailov, Wheeler, et al., 2003
Mikhailov, V.; Wheeler, M.D.; Ellis, A.M., Laser-Induced Fluorescence Spectroscopy of the BaNC Free Radical in a Supersonic Jet, J. Phys. Chem. A, 2003, 107, 22, 4367, https://doi.org/10.1021/jp027617i . [all data]

Lanzisera and Andrews, 1997
Lanzisera, D.V.; Andrews, L., Reactions of Laser-Ablated Mg, Ca, Sr, and Ba Atoms with Hydrogen Cyanide in Excess Argon. Matrix Infrared Spectra and Density Functional Calculations on Novel Isocyanide Products, J. Phys. Chem. A, 1997, 101, 50, 9666, https://doi.org/10.1021/jp972098i . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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