C10

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to C10+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
2.3000 ± 0.0043LPESAchiba, Kohno, et al., 2005EA=Vertical Detachment Energy. Ring Structure likely.
4.499982LPESKohno, Suzuki, et al., 1998Vertical Detachment Energy, linear isomer
2.20 ± 0.10LPESArnold, Bradforth, et al., 1991Ring structure from vibrational data
2.30 ± 0.10LPESYang, Taylor, et al., 1989EA given is Vertical Detachment Energy. probably ring structure

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   2 3Su-
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 29985 ± 18 Ne 324 334 Grutter, Wyss, et al., 1999
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 5 401 ± 25 Ne AB Grutter, Wyss, et al., 1999

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 27925 ± 16 Ne 349 358 Grutter, Wyss, et al., 1999
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 5 364 ± 22 Ne AB Grutter, Wyss, et al., 1999

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σu+ 2074.41 gas DL Giesen, Berndt, et al., 2001
2074.5 Ne IR Freivogel, Grutter, et al., 1997
1915.4 Ne IR Freivogel, Grutter, et al., 1997

Additional references: Jacox, 1998, page 353; Jacox, 2003, page 377

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Achiba, Kohno, et al., 2005
Achiba, Y.; Kohno, M.; Ohara, M.; Suzuki, S.; Shiromaru, H., Electron detachment spectroscopic study on carbon and silicon cluster anions, J. Electron Spectros. Rel. Phenom., 2005, 142, 3, 231-240, https://doi.org/10.1016/j.elspec.2004.09.016 . [all data]

Kohno, Suzuki, et al., 1998
Kohno, M.; Suzuki, S.; Shiromaru, H.; Moriwaki, T.; Achiba, Y., Ultraviolet Photoelectron Spectroscopy on the Linear Conformer of Negatively Charged Carbon Clusters Cn- (1- =n=16), Chem. Phys. Lett., 1998, 282, 3-4, 330, https://doi.org/10.1016/S0009-2614(97)01273-6 . [all data]

Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M., Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211 . [all data]

Yang, Taylor, et al., 1989
Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L.; Cherhnovsky, O.; Smalley, R.E., UPS of 2-30 Atom Carbon Clusters: Chains and Rings, Chem. Phys. Lett., 1989, 144, 5-6, 431, https://doi.org/10.1016/0009-2614(88)87291-9 . [all data]

Grutter, Wyss, et al., 1999
Grutter, M.; Wyss, M.; Riaplov, E.; Maier, J.P.; Peyerimhoff, S.D.; Hanrath, M., Electronic absorption spectra of linear C[sub 6], C[sub 8] and cyclic C[sub 10], C[sub 12] in neon matrices, J. Chem. Phys., 1999, 111, 16, 7397, https://doi.org/10.1063/1.480062 . [all data]

Giesen, Berndt, et al., 2001
Giesen, T.F.; Berndt, U.; Yamada, K.M.T.; Fuchs, G.; Schieder, R.; Winnewisser, G., et al., Detection of the Linear Carbon Cluster C10: Rotationally Resolved Diode-Laser Spectroscopy, Chem. Phys. Chem., 2001, 2, 4, 242, https://doi.org/10.1002/1439-7641(20010417)2:4<242::AID-CPHC242>3.0.CO;2-# . [all data]

Freivogel, Grutter, et al., 1997
Freivogel, P.; Grutter, M.; Forney, D.; Maier, J.P., Infrared bands of mass-selected carbon chains Cn (n = 8-12) and Cn- (n = 5-10, 12) in neon matrices, Chem. Phys., 1997, 216, 3, 401, https://doi.org/10.1016/S0301-0104(97)00038-4 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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