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3-Fluorobenzyl radical


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21691 gas A-X 445 498 Bindley, Watts, et al., 1964
Charlton and Thrush, 1986
Lee and Ahn, 2000


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

734 gas LF Charlton and Thrush, 1986
466 gas LF Charlton and Thrush, 1986

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 7(19b C-CH2 stretch 1599 gas PE EM Kim, Wenthold, et al., 1999
Lee and Ahn, 2000
9(8b) 1567 gas EM Lee and Ahn, 2000
10(8a 1557 gas EM Lee and Ahn, 2000
11(19 1428 gas EM Lee and Ahn, 2000
14(14 1288 gas EM Lee and Ahn, 2000
16(9b 1142 gas EM Lee and Ahn, 2000
19(12 998 gas EM Lee and Ahn, 2000
20(7b 930 gas EM Lee and Ahn, 2000
21(1) 741 gas LF EM Charlton and Thrush, 1986
Kim, Wenthold, et al., 1999
Lee and Ahn, 2000
22(6a 530 gas EM Lee and Ahn, 2000
23(6b Ring deform. 506 gas EM PE Bindley, Watts, et al., 1964
Charlton and Thrush, 1986
Kim, Wenthold, et al., 1999
Lee and Ahn, 2000
24(15 453 gas EM Lee and Ahn, 2000

Additional references: Jacox, 1998, page 369; Jacox, 2003, page 402

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bindley, Watts, et al., 1964
Bindley, T.F.; Watts, A.T.; Walker, S., Electronic emission spectra of radicals from fluorotoluenes, Trans. Faraday Soc., 1964, 60, 1, https://doi.org/10.1039/tf9646000001 . [all data]

Charlton and Thrush, 1986
Charlton, T.R.; Thrush, B.A., The study of substituted benzyl radicals by laser-induced fluorescence, Chem. Phys. Lett., 1986, 125, 5-6, 547, https://doi.org/10.1016/0009-2614(86)87096-8 . [all data]

Lee and Ahn, 2000
Lee, S.K.; Ahn, B.U., Vibronic emission spectrum of the jet cooled m-fluorobenzyl radical in the D1-->D0 transition, Chem. Phys. Lett., 2000, 321, 1-2, 25, https://doi.org/10.1016/S0009-2614(00)00325-0 . [all data]

Kim, Wenthold, et al., 1999
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of, J. Phys. Chem. A, 1999, 103, 50, 10833, https://doi.org/10.1021/jp992817o . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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