FPO

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + FOP = (Fluorine anion • FOP)

By formula: F- + FOP = (F- • FOP)

Quantity Value Units Method Reference Comment
ΔrH°230. ± 20.kJ/molICRLarson and McMahon, 1987gas phase; bracketing

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + FOP = (Fluorine anion • FOP)

By formula: F- + FOP = (F- • FOP)

Quantity Value Units Method Reference Comment
ΔrH°230. ± 20.kJ/molICRLarson and McMahon, 1987gas phase; bracketing

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PO stretch 1297.54 gas IR Paplewski, Burger, et al., 1999
Beckers, Burger, et al., 2001
1 PO stretch 1292.2 Ar IR Ahlrichs, Becherer, et al., 1986
2 Bend 420 T gas IR Allaf and Boustani, 1998
2 Bend 416.0 Ar IR Ahlrichs, Becherer, et al., 1986
3 PF stretch 819.57 gas IR Allaf and Boustani, 1998
Paplewski, Burger, et al., 1999
Beckers, Burger, et al., 2001
3 PF stretch 811.4 Ar IR Ahlrichs, Becherer, et al., 1986

Additional references: Jacox, 1994, page 103; Jacox, 2003, page 142; Gatehouse, Brupbacher, et al., 1999

Notes

TTentative assignment or approximate value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Trends in Gas Phase Fluoride Ion Affinities of the Main Group Oxyfluorides and Fluoride Sulfides. Fluoride Adducts of FAsO, FPO, FPO2, F2SiO, F4SO, FBO, F2SiS, FPS, FAsS, F2S2, and S2O., Inorg. Chem., 1987, 26, 24, 4018, https://doi.org/10.1021/ic00271a011 . [all data]

Paplewski, Burger, et al., 1999
Paplewski, P.; Burger, H.; Beckers, H., Z. Naturforsch., 1999, 54a, 507. [all data]

Beckers, Burger, et al., 2001
Beckers, H.; Burger, H.; Paplewski, P.; Bogey, M.; Demaison, J.; Drean, P.; Walters, A.; Breidung, J.; W. Thiel. Phys. Chem. Chem. Phys., 4247, 2001. [all data]

Ahlrichs, Becherer, et al., 1986
Ahlrichs, R.; Becherer, R.; Binnewies, M.; Borrmann, H.; Schunck, S.; Schnockel, H., Formation and structure of molecular O:P-F. Mass spectrometry, infrared spectra of the matrix isolated species and ab initio calculations, J. Am. Chem. Soc., 1986, 108, 25, 7905, https://doi.org/10.1021/ja00285a004 . [all data]

Allaf and Boustani, 1998
Allaf, A.W.; Boustani, I., Gas-phase infrared spectra of phosphorus (III) oxyhalide: Experimental and theoretical study of OPF and OPCl, Vib. Spectrosc., 1998, 16, 1, 69, https://doi.org/10.1016/S0924-2031(97)00047-7 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Gatehouse, Brupbacher, et al., 1999
Gatehouse, B.; Brupbacher, Th.; Gerry, M.C.L., Fourier Transform Microwave Spectrum, Geometry, and Hyperfine Coupling Constants of Phosphenous Fluoride, OPF, J. Phys. Chem. A, 1999, 103, 5, 560, https://doi.org/10.1021/jp984202h . [all data]

Notes

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