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HCl3OSi


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Cl3OSi- + Hydrogen cation = HCl3OSi

By formula: Cl3OSi- + H+ = HCl3OSi

Quantity Value Units Method Reference Comment
Deltar1359. ± 18.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; Between CF3CO2H, HNO3
Quantity Value Units Method Reference Comment
Deltar1326. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; Between CF3CO2H, HNO3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Si=O stretch 1240 s Ar IR Schnockel, 1980
Junker, Wilkening, et al., 1999
2 SiCl s-stretch 501.1 m Ar IR Schnockel, 1980
Junker, Wilkening, et al., 1999
b1 4 OPLA 280 m s Ar IR Schnockel, 1980
b2 5 SiCl a-stretch 637.5 vs Ar IR Schnockel, 1980
Junker, Wilkening, et al., 1999
6 SiCl2 rock 269 m Ar IR Schnockel, 1980

Additional references: Jacox, 1994, page 211; Jacox, 2003, page 238

Notes

mMedium
sStrong
vsVery strong

References

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Schnockel, 1980
Schnockel, H., Matrixreaktionen von SiO. IR-spektroskopischer Nachweis der Molekeln SiO2 und OSiCl2, Z. Anorg. Allg. Chem., 1980, 460, 1, 37, https://doi.org/10.1002/zaac.19804600104 . [all data]

Junker, Wilkening, et al., 1999
Junker, M.; Wilkening, A.; Binnewies, M.; Schnockel, H., Eur. J. Inorg. Chem., 1999, 1531. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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