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C3S


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 26460 Ar Maier, Schrot, et al., 1991

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CCC a-stretch 2058.22 gas DL Takano, Tang, et al., 1996
1 CCC a-stretch 2047.6 vs Ar IR Maier, Schrot, et al., 1991
Szczepanski, Hodyss, et al., 1999
2 CCS a-stretch 1533.2 w m Ar IR Maier, Schrot, et al., 1991
3 Sym. stretch 721 ± 8 gas PE Garand, Yacovitch, et al., 2009
3 Sym. stretch 725.6 w Ar IR Maier, Schrot, et al., 1991
Pi 4 CCS bend 478 ± 8 gas PE Garand, Yacovitch, et al., 2009
5 C3 bend 151 ± 8 gas PE Garand, Yacovitch, et al., 2009

Additional references: Jacox, 1994, page 186; Jacox, 1998, page 249; Jacox, 2003, page 223; Yamamoto, Saito, et al., 1987; Ohshima and Endo, 1992; Lovas, Suenram, et al., 1992

Notes

wWeak
mMedium
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Schrot, et al., 1991
Maier, G.; Schrot, J.; Reisenauer, H.P.; Janoschek, R., Heterocumulene, 8 C4OS (4-Thioxo-1,2,3-butatrien-1-on), C4S2 (1,2,3-Butatrien-1,4-dithion) und C3S (3-Thioxo-1,2-propadienyliden) - Darstellung und spektroskopische Eigenschaften, Chem. Ber., 1991, 124, 11, 2617, https://doi.org/10.1002/cber.19911241136 . [all data]

Takano, Tang, et al., 1996
Takano, S.; Tang, J.; Saito, S., Infrared Diode Laser Spectroscopy of the «nu»1Fundamental and «nu»1+ «nu»5- «nu»5Bands of the C3S Molecule, J. Mol. Spectrosc., 1996, 178, 2, 194, https://doi.org/10.1006/jmsp.1996.0174 . [all data]

Szczepanski, Hodyss, et al., 1999
Szczepanski, J.; Hodyss, R.; Fuller, J.; Vala, M., Infrared Absorption Spectroscopy of Small Carbon-Sulfur Clusters Isolated in Solid Ar, J. Phys. Chem. A, 1999, 103, 16, 2975, https://doi.org/10.1021/jp984700q . [all data]

Garand, Yacovitch, et al., 2009
Garand, E.; Yacovitch, T.I.; Neumark, D.M., Slow photoelectron velocity-map imaging spectroscopy of C3O- and C3S-, J. Chem. Phys., 2009, 131, 5, 054312, https://doi.org/10.1063/1.3200927 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Yamamoto, Saito, et al., 1987
Yamamoto, S.; Saito, S.; Kawaguchi, K.; Kaifu, N.; Suzuki, H.; Ohishi, M., Laboratory detection of a new carbon-chain molecule C3S and its astronomical identification, Astrophys. J., 1987, 317, L119, https://doi.org/10.1086/184924 . [all data]

Ohshima and Endo, 1992
Ohshima, Y.; Endo, Y., Structure of C3S studied by pulsed-discharge-nozzle Fourier-transform microwave spectroscopy, J. Mol. Spectrosc., 1992, 153, 1-2, 627, https://doi.org/10.1016/0022-2852(92)90498-D . [all data]

Lovas, Suenram, et al., 1992
Lovas, F.J.; Suenram, R.D.; Ogata, T.; Yamamoto, S., Microwave spectra and electric dipole moments for low-J levels of interstellar radicals: SO, C2S, C3S, c-HC3, CH2CC, and c-C3H2, Astrophys. J., 1992, 399, 325, https://doi.org/10.1086/171928 . [all data]


Notes

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