NH4+
- Formula: H4N+
- Molecular weight: 18.0379
- IUPAC Standard InChI:
- InChI=1S/H3N/h1H3/p+1
- Download the identifier in a file.
- IUPAC Standard InChIKey: QGZKDVFQNNGYKY-UHFFFAOYSA-O
- CAS Registry Number: 14798-03-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 93
- Options:
Reaction thermochemistry data
Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: (H4N+ 3H3N) + H3N = (H4N+
4H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51. ± 4. | kJ/mol | AVG | N/A | Average of 5 out of 10 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. ± 8. | J/mol*K | AVG | N/A | Average of 3 out of 7 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
14. | 296. | FA | Fehsenfeld and Ferguson, 1973 | gas phase |
By formula: (H4N+ 2H3N) + H3N = (H4N+
3H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50. ± 20. | kJ/mol | AVG | N/A | Average of 6 out of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. ± 5. | J/mol*K | AVG | N/A | Average of 4 out of 7 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. | 296. | FA | Fehsenfeld and Ferguson, 1973 | gas phase |
27. | 296. | SAMS | Puckett and Teague, 1971 | gas phase |
By formula: (H4N+ H3N) + H3N = (H4N+
2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70. ± 5. | kJ/mol | AVG | N/A | Average of 5 out of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | HPMS | Tang and Castleman, 1975 | gas phase |
![]() | 99.2 | J/mol*K | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 104. | J/mol*K | DT | Long and Franklin, 1973 | gas phase |
![]() | 112. | J/mol*K | PHPMS | Searles and Kebarle, 1968 | gas phase |
![]() | 95.8 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase; typographical error in «DELTA»rH |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 296. | FA | Fehsenfeld and Ferguson, 1973 | gas phase; DG> |
42.3 | 296. | SAMS | Puckett and Teague, 1971 | gas phase |
23. | 400. | HPMS | Wincel, 1972 | gas phase |
By formula: H4N+ + H3N = (H4N+ H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 107. ± 6. | kJ/mol | AVG | N/A | Average of 4 out of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 111. ± 10. | J/mol*K | AVG | N/A | Average of 4 out of 6 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 400. | HPMS | Wincel, 1972 | gas phase |
By formula: (H4N+ H2O) + H2O = (H4N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.8 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase; «DELTA»rH?, Entropy change is questionable, appear out of line |
![]() | 57.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; «DELTA»rH of 51.9 kJ/mol from plot is too small |
![]() | 61.5 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase; «DELTA»rH?, Entropy change is questionable, appear out of line |
![]() | 92.0 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; «DELTA»rH of 51.9 kJ/mol from plot is too small |
![]() | 91.6 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 37. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 414. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; «DELTA»rH of 51.9 kJ/mol from plot is too small |
By formula: (H4N+ 4H3N) + H3N = (H4N+
5H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29. | kJ/mol | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 31. | kJ/mol | PHPMS | Searles and Kebarle, 1968 | gas phase |
![]() | 30. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
![]() | 12. | kJ/mol | TPEPICO | Kamke, Herrmann, et al., 1988 | gas phase |
![]() | 40. | kJ/mol | DT | Long and Franklin, 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.0 | J/mol*K | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 100. | J/mol*K | PHPMS | Searles and Kebarle, 1968 | gas phase |
![]() | 130. | J/mol*K | DT | Long and Franklin, 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2. | kJ/mol | HPMS | Hogg, Haynes, et al., 1966 | gas phase |
By formula: (H4N+ 2H2O) + H2O = (H4N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.3 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 56.1 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
![]() | 51.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 105. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
![]() | 88.7 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: H4N+ + H2O = (H4N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 83.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 72.4 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 96.7 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 82.4 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 3CHN
H3N) + CHN = (H4N+
4CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated, T = 392 in paper is error |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated, T = 392 in paper is error |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
11. | 292. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated, T = 392 in paper is error |
By formula: (H4N+ 3H2O) + H2O = (H4N+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 51.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 114. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: H4N+ + C2N2 = (H4N+ C2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 315. | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
By formula: H4N+ + C6H12 = (H4N+ C6H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
12. | 317. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
By formula: (H4N+ H3N
2CHN) + H3N = (H4N+
2H3N
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 315. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ CHN
2H3N) + CHN = (H4N+
2CHN
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
21. | 315. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ CHN) + H3N = (H4N+
H3N
CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 78.7 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
39. | 429. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ 4C3H6O) + C3H6O = (H4N+
5C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 215. | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; Entropy change calculated or estimated |
By formula: H4N+ + C4H8 = (H4N+ C4H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 146. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1991 | gas phase; condensation |
![]() | 146. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1990 | gas phase; forms t-C4H9NH3+ |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 155. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1991 | gas phase; condensation |
![]() | 164. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1990 | gas phase; forms t-C4H9NH3+ |
By formula: H4N+ + C6H4F2 = (H4N+ C6H4F2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
21. | 395. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
By formula: H4N+ + C2H4 = (H4N+ C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 294. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ 4H2O) + H2O = (H4N+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 41. | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 93.7 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 5H3N) + H3N = (H4N+
6H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27. | kJ/mol | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 30. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.6 | J/mol*K | PHPMS | Arshadi and Futrell, 1974 | gas phase |
By formula: (H4N+ 5H2O) + H2O = (H4N+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 266. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: (H4N+ 6H2O) + H2O = (H4N+
7H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
12. | 254. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: H4N+ + CHN = (H4N+ CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 91.6 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
![]() | 85.8 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.9 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
![]() | 84.5 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: (H4N+ 2H3N) + CHN = (H4N+
CHN
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 76.6 | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ H3N
2H2O) + H3N = (H4N+
2H3N
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.7 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 142. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H2O
2H3N) + H2O = (H4N+
2H2O
2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 116. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H3N
H2O) + H3N = (H4N+
3H3N
H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 144. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H2O
H3N) + H2O = (H4N+
3H2O
H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H3N
H2O) + H3N = (H4N+
2H3N
H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.5 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 133. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H2O
H3N) + H2O = (H4N+
2H2O
H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H3N) + H2O = (H4N+
H2O
2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H2O) + H3N = (H4N+
H3N
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 76.1 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 127. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 3H3N) + H2O = (H4N+
H2O
3H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 3H2O) + H3N = (H4N+
H3N
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.4 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 147. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H2O
O2S) + H2O = (H4N+
3H2O
O2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; From thermochemical cycle,switching reaction, electric fields |
By formula: (H4N+ H3N) + H2O = (H4N+
H2O
H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.9 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H2O
O2S) + H2O = (H4N+
2H2O
O2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; From thermochemical cycle,switching reaction, electric fields |
By formula: (H4N+ H2O) + H3N = (H4N+
H3N
H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ C4H10O2) + H3N = (H4N+
H3N
C4H10O2)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: H4N+ + C4H10O2 = (H4N+ C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 160. ± 10. | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; possible ether decomposition |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 150. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; possible ether decomposition |
By formula: H4N+ + CH4 = (H4N+ CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. | kJ/mol | HPMS | Bennet and Field, 1972 | gas phase; Entropy change is questionable |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.9 | J/mol*K | HPMS | Bennet and Field, 1972 | gas phase; Entropy change is questionable |
By formula: H4N+ + H2S = (H4N+ H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.9 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
By formula: (H4N+ 2CHN
H3N) + CHN = (H4N+
3CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ CHN
H3N) + CHN = (H4N+
2CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.2 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 2H3N
C2H3N) + H3N = (H4N+
3H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 3H3N
C2H3N) + H3N = (H4N+
4H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 4H3N
C2H3N) + H3N = (H4N+
5H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 5H3N
C2H3N) + H3N = (H4N+
6H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 6H3N
C2H3N) + H3N = (H4N+
7H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
Ion clustering data
Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: H4N+ + CHN = (H4N+ CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 91.6 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
![]() | 85.8 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.9 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
![]() | 84.5 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: (H4N+ CHN) + CHN = (H4N+
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.8 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.9 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 2CHN) + CHN = (H4N+
3CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.3 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.0 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 3CHN) + CHN = (H4N+
4CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.4 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 4CHN) + CHN = (H4N+
5CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.1 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 5CHN) + CHN = (H4N+
6CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ CHN) + H3N = (H4N+
H3N
CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 78.7 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
39. | 429. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ CHN
H3N) + CHN = (H4N+
2CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.2 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ CHN
2H3N) + CHN = (H4N+
2CHN
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
21. | 315. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ 2CHN
H3N) + CHN = (H4N+
3CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 3CHN
H3N) + CHN = (H4N+
4CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated, T = 392 in paper is error |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated, T = 392 in paper is error |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
11. | 292. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated, T = 392 in paper is error |
By formula: H4N+ + CH4 = (H4N+ CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. | kJ/mol | HPMS | Bennet and Field, 1972 | gas phase; Entropy change is questionable |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.9 | J/mol*K | HPMS | Bennet and Field, 1972 | gas phase; Entropy change is questionable |
By formula: H4N+ + CO2 = (H4N+ CO2)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
9.6 | 296. | FA | Spears and Fehsenfeld, 1972 | gas phase |
By formula: H4N+ + C2H3N = (H4N+ C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. | kJ/mol | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
By formula: (H4N+ C2H3N) + C2H3N = (H4N+
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 88.7 | kJ/mol | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 106. | J/mol*K | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
By formula: (H4N+ 2C2H3N) + C2H3N = (H4N+
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 | kJ/mol | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.6 | J/mol*K | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
By formula: (H4N+ 3C2H3N) + C2H3N = (H4N+
4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 | kJ/mol | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.9 | J/mol*K | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
By formula: H4N+ + C2H4 = (H4N+ C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 294. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
By formula: H4N+ + C2N2 = (H4N+ C2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 315. | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
By formula: H4N+ + C3HN = (H4N+ C3HN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 95.8 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.6 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: H4N+ + C3H6O = (H4N+ C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 118. | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: (H4N+ C3H6O) + C3H6O = (H4N+
2C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: (H4N+ 2C3H6O) + C3H6O = (H4N+
3C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 109. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: (H4N+ 3C3H6O) + C3H6O = (H4N+
4C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: (H4N+ 4C3H6O) + C3H6O = (H4N+
5C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 215. | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; Entropy change calculated or estimated |
By formula: H4N+ + C3H8O2 = (H4N+ C3H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 122. | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: H4N+ + C4H7N = (H4N+ C4H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 119. | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: H4N+ + C4H8 = (H4N+ C4H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 146. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1991 | gas phase; condensation |
![]() | 146. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1990 | gas phase; forms t-C4H9NH3+ |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 155. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1991 | gas phase; condensation |
![]() | 164. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1990 | gas phase; forms t-C4H9NH3+ |
By formula: H4N+ + C4H10O2 = (H4N+ C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 160. ± 10. | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; possible ether decomposition |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 150. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase; possible ether decomposition |
By formula: (H4N+ C4H10O2) + C4H10O2 = (H4N+
2C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 140. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: (H4N+ 2C4H10O2) + C4H10O2 = (H4N+
3C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60. ± 10. | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 114. | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: (H4N+ C4H10O2) + H3N = (H4N+
H3N
C4H10O2)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), Sieck, et al., 1996 | gas phase |
By formula: H4N+ + C6H4F2 = (H4N+ C6H4F2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
21. | 395. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
By formula: H4N+ + C6H5F = (H4N+ C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.2 | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.3 | J/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
By formula: H4N+ + C6H6 = (H4N+ C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 80.8 | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.5 | J/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
By formula: (H4N+ C6H6) + C6H6 = (H4N+
2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.1 | kJ/mol | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 128. | J/mol*K | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
By formula: (H4N+ 2C6H6) + C6H6 = (H4N+
3C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 | kJ/mol | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 138. | J/mol*K | PHPMS | Liebman, Romm, et al., 1991 | gas phase |
By formula: H4N+ + C6H12 = (H4N+ C6H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
12. | 317. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH< |
By formula: H4N+ + C9H12 = (H4N+ C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 91.2 | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88.7 | J/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
By formula: H4N+ + H2O = (H4N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 83.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 72.4 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 96.7 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 82.4 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H2O) + CO2 = (H4N+
CO2
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.4 | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (H4N+ H2O) + H2O = (H4N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.8 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase; «DELTA»rH?, Entropy change is questionable, appear out of line |
![]() | 57.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; «DELTA»rH of 51.9 kJ/mol from plot is too small |
![]() | 61.5 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase; «DELTA»rH?, Entropy change is questionable, appear out of line |
![]() | 92.0 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; «DELTA»rH of 51.9 kJ/mol from plot is too small |
![]() | 91.6 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 37. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 414. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated; «DELTA»rH of 51.9 kJ/mol from plot is too small |
By formula: (H4N+ 2H2O) + H2O = (H4N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.3 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 56.1 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
![]() | 51.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Speller, 1986 | gas phase |
![]() | 105. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
![]() | 88.7 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (H4N+ 3H2O) + H2O = (H4N+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 51.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 114. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (H4N+ 4H2O) + H2O = (H4N+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 41. | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 93.7 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 5H2O) + H2O = (H4N+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 266. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: (H4N+ 6H2O) + H2O = (H4N+
7H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
12. | 254. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: (H4N+ H2O) + H3N = (H4N+
H3N
H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H2O) + H3N = (H4N+
H3N
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 76.1 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 127. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 3H2O) + H3N = (H4N+
H3N
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.4 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 147. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H2O
H3N) + H2O = (H4N+
2H2O
H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H2O
2H3N) + H2O = (H4N+
2H2O
2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 116. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H2O
H3N) + H2O = (H4N+
3H2O
H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H2O) + O2S = (H4N+
O2S
H2O)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (H4N+ 2H2O) + O2S = (H4N+
O2S
2H2O)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
21. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (H4N+ 3H2O) + O2S = (H4N+
O2S
3H2O)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (H4N+ H2O
O2S) + H2O = (H4N+
2H2O
O2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; From thermochemical cycle,switching reaction, electric fields |
By formula: (H4N+ 2H2O
O2S) + H2O = (H4N+
3H2O
O2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; From thermochemical cycle,switching reaction, electric fields |
By formula: H4N+ + H2S = (H4N+ H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.7 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.9 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
By formula: H4N+ + H3N = (H4N+ H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 107. ± 6. | kJ/mol | AVG | N/A | Average of 4 out of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 111. ± 10. | J/mol*K | AVG | N/A | Average of 4 out of 6 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 400. | HPMS | Wincel, 1972 | gas phase |
By formula: (H4N+ H3N) + CHN = (H4N+
CHN
H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.4 | J/mol*K | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase |
By formula: (H4N+ 2H3N) + CHN = (H4N+
CHN
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 76.6 | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ H3N
2CHN) + H3N = (H4N+
2H3N
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 315. | PHPMS | Deakyne, Knuth, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (H4N+ H3N
C2H3N) + H3N = (H4N+
2H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.9 | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 2H3N
C2H3N) + H3N = (H4N+
3H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.9 | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 3H3N
C2H3N) + H3N = (H4N+
4H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 4H3N
C2H3N) + H3N = (H4N+
5H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 5H3N
C2H3N) + H3N = (H4N+
6H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 6H3N
C2H3N) + H3N = (H4N+
7H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 7H3N
C2H3N) + H3N = (H4N+
8H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ 8H3N
C2H3N) + H3N = (H4N+
9H3N
C2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23. | kJ/mol | MKER | Tzeng, Wei, et al., 1991 | gas phase; from graph |
By formula: (H4N+ H3N) + H2O = (H4N+
H2O
H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.9 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H3N) + H2O = (H4N+
H2O
2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 3H3N) + H2O = (H4N+
H2O
3H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H3N
H2O) + H3N = (H4N+
2H3N
H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.5 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 133. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H3N
2H2O) + H3N = (H4N+
2H3N
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.7 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 142. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ 2H3N
H2O) + H3N = (H4N+
3H3N
H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 | kJ/mol | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 144. | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase |
By formula: (H4N+ H3N) + H3N = (H4N+
2H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70. ± 5. | kJ/mol | AVG | N/A | Average of 5 out of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | HPMS | Tang and Castleman, 1975 | gas phase |
![]() | 99.2 | J/mol*K | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 104. | J/mol*K | DT | Long and Franklin, 1973 | gas phase |
![]() | 112. | J/mol*K | PHPMS | Searles and Kebarle, 1968 | gas phase |
![]() | 95.8 | J/mol*K | PHPMS | Payzant, Cunningham, et al., 1973 | gas phase; typographical error in «DELTA»rH |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 296. | FA | Fehsenfeld and Ferguson, 1973 | gas phase; DG> |
42.3 | 296. | SAMS | Puckett and Teague, 1971 | gas phase |
23. | 400. | HPMS | Wincel, 1972 | gas phase |
By formula: (H4N+ 2H3N) + H3N = (H4N+
3H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50. ± 20. | kJ/mol | AVG | N/A | Average of 6 out of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. ± 5. | J/mol*K | AVG | N/A | Average of 4 out of 7 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. | 296. | FA | Fehsenfeld and Ferguson, 1973 | gas phase |
27. | 296. | SAMS | Puckett and Teague, 1971 | gas phase |
By formula: (H4N+ 3H3N) + H3N = (H4N+
4H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51. ± 4. | kJ/mol | AVG | N/A | Average of 5 out of 10 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. ± 8. | J/mol*K | AVG | N/A | Average of 3 out of 7 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
14. | 296. | FA | Fehsenfeld and Ferguson, 1973 | gas phase |
By formula: (H4N+ 4H3N) + H3N = (H4N+
5H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29. | kJ/mol | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 31. | kJ/mol | PHPMS | Searles and Kebarle, 1968 | gas phase |
![]() | 30. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
![]() | 12. | kJ/mol | TPEPICO | Kamke, Herrmann, et al., 1988 | gas phase |
![]() | 40. | kJ/mol | DT | Long and Franklin, 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.0 | J/mol*K | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 100. | J/mol*K | PHPMS | Searles and Kebarle, 1968 | gas phase |
![]() | 130. | J/mol*K | DT | Long and Franklin, 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2. | kJ/mol | HPMS | Hogg, Haynes, et al., 1966 | gas phase |
By formula: (H4N+ 5H3N) + H3N = (H4N+
6H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27. | kJ/mol | PHPMS | Arshadi and Futrell, 1974 | gas phase |
![]() | 30. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.6 | J/mol*K | PHPMS | Arshadi and Futrell, 1974 | gas phase |
By formula: (H4N+ 6H3N) + H3N = (H4N+
7H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 7H3N) + H3N = (H4N+
8H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 8H3N) + H3N = (H4N+
9H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 9H3N) + H3N = (H4N+
10H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 10H3N) + H3N = (H4N+
11H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 11H3N) + H3N = (H4N+
12H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 12H3N) + H3N = (H4N+
13H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 13H3N) + H3N = (H4N+
14H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 14H3N) + H3N = (H4N+
15H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: (H4N+ 15H3N) + H3N = (H4N+
16H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. | kJ/mol | MKER | Wei, Tzeng, et al., 1990 | gas phase; from graph |
By formula: H4N+ + N2 = (H4N+ N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50. ± 20. | kJ/mol | DT | Gheno and Fitaire, 1987 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 130. | J/mol*K | DT | Gheno and Fitaire, 1987 | gas phase |
Vibrational and/or electronic energy levels
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
f2 | 3 | NH stretch | 3343.14 | gas | LD CC | Crofton and Oka, 1983 Schaeffer, Begemann, et al., 1983 Schafer, Saykally, et al., 1984 Keim, Polak, et al., 1990 | |
3 | NH stretch | 3343.1 | H | gas | PF | Dopfer, Nizkorodov, et al., 1996 Lakin, Olkhov, et al., 2001 | |
3 | NH stretch | 3344.0 | gas | PF | Lakin, Olkhov, et al., 2001 | ||
3 | NH stretch | 3335.8 | A | gas | PF | Bieske, Nizkorodov, et al., 1996 Dopfer, Nizkorodov, et al., 1997 Lakin, Dopfer, et al., 2000 Lakin, Dopfer, et al., 2000, 2 | |
3 | NH stretch | 3357.5 | Ne | IR | Jacox and Thompson, 2005 | ||
4 | Deformation | 1447.22 | gas | DL | Polak, Gruebele, et al., 1989 Park, Xia, et al., 1996 | ||
4 | Deformation | 1442.5 | Ne | IR | Jacox and Thompson, 2005 | ||
Additional references: Jacox, 1994, page 229; Jacox, 1998, page 266; Crofton and Oka, 1987; Signorell, Palm, et al., 1997
Notes
H | (1/2)(2![]() |
A | 0~1 cm-1 uncertainty |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Speller and Meot-Ner (Mautner), 1985
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Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives,
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Complexing of the Ammonium Ion by Polyethers. Comparative Complexing Thermochemistry of Ammonium, Hydronium, and Alkali Cations,
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Meot-Ner (Mautner) and Sieck, 1991
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Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range,
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Meot-Ner (Mautner) and Sieck, 1990
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Ion Thermochemistry at High Temperatures. 1. Thermochemistry of the Ammonium Ion from Variable - Temperature Equilibrium Measurements. Proton Transfer, Association, and Decomposition Reactions in Ammonia, Isobutene, and t-Butylamine,
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Meot-Ner (Mautner) and Sieck, 1985
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The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters,
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Spears and Fehsenfeld, 1972
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Termolecular Association Reactions of Mg, Ca, and Ba Ions,
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Liebman, Romm, et al., 1991
Liebman, J.F.; Romm, M.J.; Meot-Ner (Mautner), M.; Cybulski, S.M.; Scheiner, S.,
Isotropy in ionic interactions. 2. How spherical is the ammonium ion? Comparison of the gas-phase clustering energies and condensed-phase thermochemistry of K+ and NH4+,
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Gheno and Fitaire, 1987
Gheno, F.; Fitaire, M.,
Association of N2 with NH4+ and H3O+(H2O)n, n = 1,2,3,
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Crofton and Oka, 1983
Crofton, M.; Oka, T.,
Infrared studies of molecular ions. I. The «nu»3 band of NH4+,
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Schaeffer, Begemann, et al., 1983
Schaeffer, E.; Begemann, M.H.; Gudeman, C.S.; Saykally, R.J.,
The «nu»3 vibrational spectrum of the free ammonium ion (NH4+),
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Schafer, Saykally, et al., 1984
Schafer, E.; Saykally, R.J.; Robiette, A.G.,
A high resolution study of the «nu»3 band of the ammonium ion (NH+4) by velocity modulation laser absorption spectroscopy,
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Keim, Polak, et al., 1990
Keim, E.R.; Polak, M.L.; Owrutsky, J.C.; Coe, J.V.; Saykally, R.J.,
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Dopfer, Nizkorodov, et al., 1996
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The «nu»3 infrared spectrum of the He«58872»NH4+ complex,
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Lakin, Olkhov, et al., 2001
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Internal rotation in NH4+--Rg dimers (Rg=He, Ne, Ar): Potential energy surfaces and IR spectra of the «nu»3 band,
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Bieske, Nizkorodov, et al., 1996
Bieske, E.J.; Nizkorodov, S.A.; Dopfer, O.; Maier, J.P.; Stickland, R.J.; Cotterell, B.J.; Howard, B.J.,
Observation of the infrared spectrum of the «nu»3 band of the argon-ammonium ionic complex,
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Dopfer, Nizkorodov, et al., 1997
Dopfer, O.; Nizkorodov, S.A.; Meuwly, M.; Bieske, E.J.; Maier, J.P.,
Microsolvation of the ammonium ion in argon: infrared spectra of NH4+«58872»Arn complexes (n = 1--7),
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Lakin, Dopfer, et al., 2000
Lakin, N.M.; Dopfer, O.; Meuwly, M.; Howard, B.J.; Maier, J.P.,
The intermolecular potential of NH,
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Lakin, Dopfer, et al., 2000, 2
Lakin, N.M.; Dopfer, O.; Howard, B.J.; Maier, J.P.,
The inter molecular potential of NH,
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Jacox and Thompson, 2005
Jacox, M.E.; Thompson, W.E.,
Infrared spectrum of the NH4-dn+ cation trapped in solid neon,
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Polak, Gruebele, et al., 1989
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Velocity modulation infrared laser spectroscopy of molecular ions,
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Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
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Crofton and Oka, 1987
Crofton, M.W.; Oka, T.,
Observation of forbidden transitions of ammonium ion (NH+4) «nu»3 band and determination of ground state rotational constants. Observation of «nu»3 band allowed transitions of ND+4,
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Signorell, Palm, et al., 1997
Signorell, R.; Palm, H.; Merkt, F.,
Structure of the ammonium radical from a rotationally resolved photoelectron spectrum,
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Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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