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Trichlorosilyl


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-390.37kJ/molReviewChase, 1998Data last reviewed in December, 1977
Quantity Value Units Method Reference Comment
gas,1 bar318.13J/mol*KReviewChase, 1998Data last reviewed in December, 1977

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 6000.
A 81.59679
B 1.315438
C -0.355645
D 0.030306
E -1.020295
F -418.1720
G 410.7634
H -390.3676
ReferenceChase, 1998
Comment Data last reviewed in December, 1977

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 43700 T gas Irikura, Johnson, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 Umbrella 282 ± 30 gas MPI Irikura, Johnson, et al., 1992

State:   G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 43700 T gas Irikura, Johnson, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 Umbrella 261 ± 15 gas MPI Irikura, Johnson, et al., 1992

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 43700 T gas Irikura, Johnson, et al., 1992


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 Umbrella 262 ± 16 gas MPI Irikura, Johnson, et al., 1992

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SiCl stretch 470 m Ar IR Jacox and Milligan, 1968
Miller and Andrews, 1981
e 3 SiCl stretch 582 vs Ar IR Jacox and Milligan, 1968
Miller and Andrews, 1981

Additional references: Jacox, 1994, page 218; Leray and Roncin, 1965

Notes

mMedium
vsVery strong
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Irikura, Johnson, et al., 1992
Irikura, K.K.; Johnson, R.D., III; Hudgens, J.W., Electronic spectrum of the trichlorosilyl radical, J. Phys. Chem., 1992, 96, 11, 4306, https://doi.org/10.1021/j100190a038 . [all data]

Jacox and Milligan, 1968
Jacox, M.E.; Milligan, D.E., Matrix-Isolation Study of the Vacuum-Ultraviolet Photolysis of Trichlorosilane. The Infrared Spectrum of the Free Radical SiCl3, J. Chem. Phys., 1968, 49, 7, 3130, https://doi.org/10.1063/1.1670560 . [all data]

Miller and Andrews, 1981
Miller, J.H.; Andrews, L., Matrix spectroscopy of the argon resonance photolysis products of group IV chlorides, J. Mol. Struct., 1981, 77, 1-2, 65, https://doi.org/10.1016/0022-2860(81)85267-2 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Leray and Roncin, 1965
Leray, N.; Roncin, J., Hyperfine Interaction of the Chlorine Nucleus in a Solid Matrix, J. Chem. Phys., 1965, 42, 2, 800, https://doi.org/10.1063/1.1696018 . [all data]


Notes

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