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1,2,3-C6H3F3+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 22463.8 gas B-X 445 459 Bondybey, English, et al., 1980
Bondybey, English, et al., 1981
Suh, Lee, et al., 1991
To = 22289 Ne B-X 419 467 Bondybey, English, et al., 1980
Bondybey, English, et al., 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1567 T Ne LF Bondybey, English, et al., 1980
1501 T Ne LF Bondybey, English, et al., 1980
1264 T Ne LF Bondybey, English, et al., 1980
931 Ne LF Bondybey, English, et al., 1980
735 Ne LF Bondybey, English, et al., 1980
664 Ne LF Bondybey, English, et al., 1980
482 Ne LF Bondybey, English, et al., 1980
460 Ne LF Bondybey, English, et al., 1980
302 Ne LF Bondybey, English, et al., 1980

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 191.8 gas B-A 448 463 Suh, Lee, et al., 1991
To = 197 Ne B-A 419 467 Bondybey, English, et al., 1980
Bondybey, English, et al., 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

677.6 gas EM Suh, Lee, et al., 1991
680 Ne LF Bondybey, English, et al., 1980
603.7 gas EM Suh, Lee, et al., 1991
608 Ne LF Bondybey, English, et al., 1980
470.3 gas EM Suh, Lee, et al., 1991
213.5 gas EM Suh, Lee, et al., 1991
218 Ne LF Bondybey, English, et al., 1980
145.4 gas EM Suh, Lee, et al., 1991
119.9 gas EM Suh, Lee, et al., 1991
120 Ne LF Bondybey, English, et al., 1980

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

695.6 gas EM Suh, Lee, et al., 1991
698 Ne LF Bondybey, English, et al., 1980
595.0 gas EM Suh, Lee, et al., 1991
601 Ne LF Bondybey, English, et al., 1980
518.5 gas EM Suh, Lee, et al., 1991
526 Ne LF Bondybey, English, et al., 1980
458.2 gas EM Suh, Lee, et al., 1991
466 Ne LF Bondybey, English, et al., 1980
389 T Ne LF Bondybey, English, et al., 1980
289.3 gas EM Suh, Lee, et al., 1991
294 Ne LF Bondybey, English, et al., 1980

Additional references: Jacox, 1994, page 432; Maier and Thommen, 1981

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bondybey, English, et al., 1980
Bondybey, V.E.; English, J.H.; Miller, T.A.; Shiley, R.H., The laser-induced fluorescence spectrum of the 1,2,3-trifluorobenzene radical cation, J. Mol. Spectrosc., 1980, 84, 1, 124, https://doi.org/10.1016/0022-2852(80)90245-3 . [all data]

Bondybey, English, et al., 1981
Bondybey, V.E.; English, J.H.; Miller, T.A., Ground-state splitting and structure of the 1, 2, 3 trifluorobenzene radical cation from low-temperature gas phase and matrix spectra, J. Mol. Spectrosc., 1981, 90, 2, 592, https://doi.org/10.1016/0022-2852(81)90149-1 . [all data]

Suh, Lee, et al., 1991
Suh, M.H.; Lee, S.K.; Rehfuss, B.D.; Miller, T.A.; Bondybey, V.E., High-resolution Fourier transform studies of molecular ion emission: ground state degeneracy splitting in the 1,2,3-trifluorobenzene radical cation, J. Phys. Chem., 1991, 95, 7, 2727, https://doi.org/10.1021/j100160a021 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Maier and Thommen, 1981
Maier, J.P.; Thommen, F., Fluorescence quantum yields and lifetimes of fluorobenzene cations in selected levels of their B and C states determined by photoelectron-photoion coincidence spectroscopy, Chem. Phys., 1981, 57, 319. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References