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CF2=NH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NH stretch 3402.3 m gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
1 NH stretch 3388.4 m Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
2 C=N stretch 1785.2 vs gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
2 C=N stretch 1777.2 vs Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
3 CF2 a-stretch 1307 vs gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
3 CF2 a-stretch 1294.9 vs Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
4 CNH deform. 1031.2 s gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
4 CNH deform. 1027.0 m s Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
5 CF2 s-stretch 947.2 s gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
5 CF2 s-stretch 941.9 s Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
6 CF2 scissors 572.7 w Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
7 CF2 rock 542.0 m gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
7 CF2 rock 541.4 m Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
a 8 Torsion 831.65 gas IR Burger and Pawelke, 1988
Burger, Kuna, et al., 1992
Pawelke, Dammel, et al., 1992
8 Torsion 827.8 s Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992
9 F2CN OPLA 695.2 w gas IR Burger and Pawelke, 1988
Pawelke, Dammel, et al., 1992
9 F2CN OPLA 694.3 w Ar IR Pawelke, Dammel, et al., 1992
Jacobs, Willner, et al., 1992

Additional references: Jacox, 1994, page 270; Jacox, 1998, page 289; Moller, Winnewisser, et al., 1988; Groner, Nanaie, et al., 1988; Groner, Durig, et al., 1996

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burger and Pawelke, 1988
Burger, H.; Pawelke, G., J. Chem. Soc., 1988, Chem. Commun. 105. [all data]

Pawelke, Dammel, et al., 1992
Pawelke, G.; Dammel, R.; Poll, W., Z. Naturforsch., 1992, 47b, 351. [all data]

Jacobs, Willner, et al., 1992
Jacobs, J.; Willner, H.; Pawelke, G., Fourier transform infrared spectra of the complexes XCN.cntdot..cntdot..cntdot.HF (X = F, CF3, SF5) isolated in an argon matrix, J. Phys. Chem., 1992, 96, 14, 5793, https://doi.org/10.1021/j100193a026 . [all data]

Burger, Kuna, et al., 1992
Burger, H.; Kuna, R.; Pawelke, G.; Sommer, S.; Thiel, W., Z. Naturforsch., 1992, 47a, 475. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Moller, Winnewisser, et al., 1988
Moller, K.; Winnewisser, M.; Pawelke, G.; Burger, H., The microwave and millimeter wave spectrum of difluoromethanimine, F2C«58875»NH: rotational and nuclear hyperfine structure analysis, J. Mol. Struct., 1988, 190, 343, https://doi.org/10.1016/0022-2860(88)80295-3 . [all data]

Groner, Nanaie, et al., 1988
Groner, P.; Nanaie, H.; Durig, J.R.; DesMarteau, D.D., The microwave spectrum of difluoromethanimine, CF2=NH, J. Chem. Phys., 1988, 89, 7, 3983, https://doi.org/10.1063/1.454831 . [all data]

Groner, Durig, et al., 1996
Groner, P.; Durig, J.R.; DesMarteau, D.D., r0 structure of difluoromethanimine, CF2[Double Bond]NH, from microwave spectra of isotopic species, J. Chem. Phys., 1996, 105, 17, 7263, https://doi.org/10.1063/1.472600 . [all data]


Notes

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