Glycerin

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

Glycerin + Nitric acid = 1,2,3-Propanetriol, 1-nitrate + Water

By formula: C3H8O3 + HNO3 = C3H7NO5 + H2O

Quantity Value Units Method Reference Comment
Δr-4.5 ± 0.5kcal/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of Nitration; ALS
Δr-2.39kcal/molCmTsvetkov, Sopin, et al., 1986liquid phase; ALS

C3H9O3+ + Glycerin = (C3H9O3+ • Glycerin)

By formula: C3H9O3+ + C3H8O3 = (C3H9O3+ • C3H8O3)

Bond type: Hydrogen bonds of the type OH-O between organics

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
13.7500.PHPMSSunner, Kulatunga, et al., 1986gas phase; M

Glycerin + Nitric acid = Glycerol-2-nitrate + Water

By formula: C3H8O3 + HNO3 = C3H7NO5 + H2O

Quantity Value Units Method Reference Comment
Δr-2.5 ± 0.6kcal/molEqkKazakov, Kirpichev, et al., 1990liquid phase; Heat of nitration; ALS

Glycerin + 3Nitric acid = Nitroglycerin + 3Water

By formula: C3H8O3 + 3HNO3 = C3H5N3O9 + 3H2O

Quantity Value Units Method Reference Comment
Δr-8.7 ± 0.4kcal/molCmKazakov, Lagodzinskaya, et al., 1989liquid phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kazakov, Kirpichev, et al., 1990
Kazakov, A.I.; Kirpichev, E.P.; Lagodzinskaya, G.V.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Rubstov, Yu.I.; Manelis, G.B.; Eremenko, L.T., Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in ΔH and ΔS in the nitration reaction, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 1565-1570. [all data]

Tsvetkov, Sopin, et al., 1986
Tsvetkov, V.G.; Sopin, V.P.; Tsvetkova, L.Ya.; Marchenko, G.N., Enthalpy of reaction of nitric acid with some organic compounds, J. Gen. Chem. USSR, 1986, 56, 471-474. [all data]

Sunner, Kulatunga, et al., 1986
Sunner, J.A.; Kulatunga, R.; Kebarle, P., Fast Atom Bombardment Mass Spectrometry and Gas Phase Basicities, Anal. Chem., 1986, 58, 7, 1312, https://doi.org/10.1021/ac00298a010 . [all data]

Kazakov, Lagodzinskaya, et al., 1989
Kazakov, A.I.; Lagodzinskaya, E.P.; Kirpichev, E.P.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Robtsov, Yu.I.; Manelis, G.V.; Eremenko, L.T., Thermodynamics of nitration of glycerol, Dokl. Phys. Chem. (Engl. Transl.), 1989, 305, 287-291. [all data]


Notes

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