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t-HN=CHCN


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NH stretch 3288 w gas IR Evans, Lorencak, et al., 1991
3 CðN stretch 2239.5 w gas IR Evans, Lorencak, et al., 1991
3 CðN stretch 2227 w Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
4 C=N stretch 1609 m gas IR Hamada, Tsuboi, et al., 1986
Evans, Lorencak, et al., 1991
4 C=N stretch 1600 s Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
5 CH,NH a-def. 1387 m gas IR Hamada, Tsuboi, et al., 1986
Evans, Lorencak, et al., 1991
5 CH,NH a-def. 1388 m Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
6 NH,CH s-def. 1217 s gas IR Hamada, Tsuboi, et al., 1986
Evans, Lorencak, et al., 1991
6 NH,CH s-def. 1221 s Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
6 NH,CH s-def. 1216 vs Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
7 Mixed 908 m gas IR Hamada, Tsuboi, et al., 1986
Evans, Lorencak, et al., 1991
7 Mixed 902 s Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
a 10 NH,CH s-wag 1095 s gas IR Hamada, Tsuboi, et al., 1986
Evans, Lorencak, et al., 1991
10 NH,CH s-wag 1096 s Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
10 NH,CH s-wag 1093 vs Ar IR Lorencak, Raabe, et al., 1986
Evans, Lorencak, et al., 1991
11 Torsion 815 m gas IR Evans, Lorencak, et al., 1991
11 Torsion 816 m Ar IR Evans, Lorencak, et al., 1991

Additional references: Jacox, 1994, page 328; Takeo, Sugie, et al., 1986; Takano, Sugie, et al., 1990

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Evans, Lorencak, et al., 1991
Evans, R.A.; Lorencak, P.; Ha, T.-K.; Wentrup, C., HCN dimers: iminoacetonitrile and N-cyanomethanimine, J. Am. Chem. Soc., 1991, 113, 19, 7261, https://doi.org/10.1021/ja00019a026 . [all data]

Lorencak, Raabe, et al., 1986
Lorencak, P.; Raabe, G.; Radziszewski, J.J.; Wentrup, C., J. Chem. Soc., 1986, Chem. Commun. 916. [all data]

Hamada, Tsuboi, et al., 1986
Hamada, Y.; Tsuboi, M.; Nakanaga, T.; Takeo, H.; Matsumura, C., Pyrolysis of amines: Infrared spectrum of C-cyanomethanimine, J. Mol. Spectrosc., 1986, 117, 2, 308, https://doi.org/10.1016/0022-2852(86)90156-6 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Takeo, Sugie, et al., 1986
Takeo, H.; Sugie, M.; Matsumura, C.; Hamada, Y.; Tsuboi, M., Microwave spectrum of C-cyanomethanimine: HCN dimer, Chem. Phys. Lett., 1986, 123, 3, 229, https://doi.org/10.1016/0009-2614(86)80019-7 . [all data]

Takano, Sugie, et al., 1990
Takano, S.; Sugie, M.; Sugawara, K.; Takeo, H.; Matsumura, C.; Masuda, A.; Kuchitsu, K., Microwave spectra, dipole moments, and energy difference of E and Z C-cyanomethanimine (HCN dimer), J. Mol. Spectrosc., 1990, 141, 1, 13, https://doi.org/10.1016/0022-2852(90)90273-S . [all data]


Notes

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