C6F5OH+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 22406 ± 6 gas B-X 425 500 Maier, Marthaler, et al., 1980
Maier, Misev, et al., 1980
To = 22403 Ne B-X 410 500 Bondybey, English, et al., 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1548 Ne LF Bondybey, English, et al., 1981
1186 Ne LF Bondybey, English, et al., 1981
700 ± 10 gas LF Maier, Misev, et al., 1980
540 ± 10 gas LF Maier, Misev, et al., 1980
543 Ne LF Bondybey, English, et al., 1981
435 ± 10 gas LF Maier, Misev, et al., 1980
430 Ne LF Bondybey, English, et al., 1981
270 ± 10 gas LF Maier, Misev, et al., 1980
268 Ne LF Bondybey, English, et al., 1981

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 1680 ± 10 gas LF Maier, Misev, et al., 1980
2 1688 Ne LF Bondybey, English, et al., 1981
3 1656 Ne LF Bondybey, English, et al., 1981
5 1489 Ne LF Bondybey, English, et al., 1981
6 1472 Ne LF Bondybey, English, et al., 1981
7 1350 Ne LF Bondybey, English, et al., 1981
10 1182 Ne LF Bondybey, English, et al., 1981
11 1147 Ne LF Bondybey, English, et al., 1981
16 560 ± 10 gas LF Maier, Misev, et al., 1980
16 558 Ne LF Bondybey, English, et al., 1981
17 420 ± 10 gas LF Maier, Misev, et al., 1980
17 431 Ne LF Bondybey, English, et al., 1981
19 383 Ne LF Bondybey, English, et al., 1981
21 260 ± 10 gas LF Maier, Misev, et al., 1980
21 266 Ne LF Bondybey, English, et al., 1981

Additional references: Jacox, 1994, page 445

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Marthaler, et al., 1980
Maier, J.P.; Marthaler, O.; Mohraz, M., Emission spectra of the cations of some fluorosubstituted phenols in the gaseous phase, J. Electron Spectrosc. Relat. Phenom., 1980, 19, 11. [all data]

Maier, Misev, et al., 1980
Maier, J.P.; Misev, L.; Shiley, R.H., Laser Induced Excitation Spectra of the Cations of Some Fluoro-substituted Phenols (??2 A? ? ??2 A?) in the Gaseous Phase, Helv. Chim. Acta, 1980, 63, 7, 1920, https://doi.org/10.1002/hlca.19800630719 . [all data]

Bondybey, English, et al., 1981
Bondybey, V.E.; English, J.H.; Miller, T.A.; Vaughn, C.B., Low-temperature fluorescence of the pentafluorophenol radical cation, J. Phys. Chem., 1981, 85, 12, 1667, https://doi.org/10.1021/j150612a013 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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