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H2C=NCN


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CH2 a-stretch 3137 w Ar IR Evans, Lorencak, et al., 1991
3 CðN stretch 2208 vs Ar IR Evans, Lorencak, et al., 1991
4 C=N stretch 1621 s Ar IR Evans, Lorencak, et al., 1991
5 CH2 scissors 1456 m s Ar IR Evans, Lorencak, et al., 1991
6 CH2 rock 1215 m Ar IR Evans, Lorencak, et al., 1991
a 10 CH2 wag 1090 m Ar IR Evans, Lorencak, et al., 1991

Additional references: Jacox, 1994, page 328; Bak, Nielsen, et al., 1978; Bak and Svanholt, 1979; Bak and Svanholt, 1980; Winnewisser, Winnewisser, et al., 1984; Stolze, Sutter, et al., 1989

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Evans, Lorencak, et al., 1991
Evans, R.A.; Lorencak, P.; Ha, T.-K.; Wentrup, C., HCN dimers: iminoacetonitrile and N-cyanomethanimine, J. Am. Chem. Soc., 1991, 113, 19, 7261, https://doi.org/10.1021/ja00019a026 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Bak, Nielsen, et al., 1978
Bak, B.; Nielsen, O.J.; Svanholt, H., HCN and HNC dimers. A new and stable variant, Chem. Phys. Lett., 1978, 59, 2, 330, https://doi.org/10.1016/0009-2614(78)89106-4 . [all data]

Bak and Svanholt, 1979
Bak, B.; Svanholt, H., Microwave transitions of CD2=NCN, Chem. Phys. Lett., 1979, 66, 2, 387, https://doi.org/10.1016/0009-2614(79)85041-1 . [all data]

Bak and Svanholt, 1980
Bak, B.; Svanholt, H., Extended study of rotational spectra of CH2«58875»N-CN and CD2«58875»N-CN at centimeter wavelengths, Chem. Phys. Lett., 1980, 75, 3, 528, https://doi.org/10.1016/0009-2614(80)80570-7 . [all data]

Winnewisser, Winnewisser, et al., 1984
Winnewisser, M.; Winnewisser, B.P.; Wentrup, C., The millimeter wave rotational spectrum of N-cyanomethanimine, CH2NCN, J. Mol. Spectrosc., 1984, 105, 1, 193, https://doi.org/10.1016/0022-2852(84)90111-5 . [all data]

Stolze, Sutter, et al., 1989
Stolze, W.H.; Sutter, D.H.; Wentrup, C., Z. Naturforsch., 1989, 44A, 291. [all data]


Notes

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