Di-n-propyl ether

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-328.8 ± 0.88kJ/molCcbColomina, Pell, et al., 1965ALS
Δfliquid-333.1 ± 2.1kJ/molCcbMurrin and Goldhagen, 1957ALS
Quantity Value Units Method Reference Comment
Δcliquid-4033.1 ± 0.79kJ/molCcbColomina, Pell, et al., 1965Corresponding Δfliquid = -328.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-4028.9 ± 2.1kJ/molCcbMurrin and Goldhagen, 1957Corresponding Δfliquid = -333.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid323.9J/mol*KN/AAndon, Counsell, et al., 1975DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
221.45298.15Kimura, Treszczanowicz, et al., 1983DH
221.6298.15Andon, Counsell, et al., 1975T = 10 to 330 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil363. ± 1.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus149.95KN/ATimmermans, 1952Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Ttriple149.4KN/AAndon, Counsell, et al., 1975, 2Metastable crystal phase; Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple158.36KN/AAndon, Counsell, et al., 1975, 2Uncertainty assigned by TRC = 0.06 K; TRC
Quantity Value Units Method Reference Comment
Tc530.6KN/AMajer and Svoboda, 1985 
Tc530.60KN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Pc30.28barN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.06 bar; TRC
Quantity Value Units Method Reference Comment
Δvap35.79kJ/molN/AMajer and Svoboda, 1985 
Δvap35.68kJ/molCMajer, Wagner, et al., 1980ALS
Δvap35.7 ± 0.1kJ/molCMajer, Wagner, et al., 1980AC
Δvap36.5 ± 1.3kJ/molVColomina, Pell, et al., 1965Heat of formation derived by Cox and Pilcher, 1970; ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
31.31363.1N/AMajer and Svoboda, 1985 
31.274363.22N/AAndon, Counsell, et al., 1975P = 101.30 kPa; DH
34.8323.EBAntosik, Fras, et al., 2002Based on data from 308. to 338. K.; AC
32.2400.AStephenson and Malanowski, 1987Based on data from 385. to 467. K.; AC
32.4480.AStephenson and Malanowski, 1987Based on data from 465. to 530. K.; AC
35.6307.AStephenson and Malanowski, 1987Based on data from 292. to 389. K. See also Ambrose, Ellender, et al., 1976.; AC
34.6327.A,EBStephenson and Malanowski, 1987Based on data from 312. to 371. K. See also Meyer and Hotz, 1973.; AC
31.4363.N/AAmbrose, Ellender, et al., 1976AC
35.1315.EBCidlinský and Polák, 1969Based on data from 300. to 362. K.; AC
34.5360.N/ALapidus and Nisel'son, 1968Based on data from 340. to 379. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) β Tc (K) Reference Comment
298. to 363.53.410.2907530.6Majer and Svoboda, 1985 

Entropy of vaporization

ΔvapS (J/mol*K) Temperature (K) Reference Comment
86.10363.22Andon, Counsell, et al., 1975P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference
312.9 to 371.334.01971 ± 0.000461227.47 ± 0.82-57.449 ± 0.095Meyer and Hotz, 1973
299.74 to 361.804.069511254.781-54.33Cidlinský and Polák, 1969

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
10.77158.4Domalski and Hearing, 1996AC

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
9.540149.40crystaline, IliquidAndon, Counsell, et al., 1975DH
10.770158.36crystaline, IIliquidAndon, Counsell, et al., 1975DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
63.86149.40crystaline, IliquidAndon, Counsell, et al., 1975DH
68.01158.36crystaline, IIliquidAndon, Counsell, et al., 1975DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colomina, Pell, et al., 1965
Colomina, M.; Pell, A.S.; Skinner, H.A.; Coleman, D.J., Heats of combustion of four dialkylethers, Trans. Faraday Soc., 1965, 61, 2641. [all data]

Murrin and Goldhagen, 1957
Murrin, J.W.; Goldhagen, S., Determination of the C-O bond energy from the heats of combustion of four aliphatic ethers, NAVORD Report No. 5491, U.S. Naval Powder Factory Res. & Dev. Dept., 1957, 1-14. [all data]

Andon, Counsell, et al., 1975
Andon, R.J.L.; Counsell, J.F.; Lee, D.A.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. 39. Heat capacity of n-propyl ether, J. Chem. Thermodynam., 1975, 7, 587-592. [all data]

Kimura, Treszczanowicz, et al., 1983
Kimura, F.; Treszczanowicz, A.J.; Halpin, C.J.; Benson, G.C., Excess volumes and ultrasonic speeds for (di-n-propylether + n-heptane), J. Chem. Thermodynam., 1983, 15, 503-510. [all data]

Timmermans, 1952
Timmermans, J., Freezing points of organic compounds. VVI New determinations., Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]

Andon, Counsell, et al., 1975, 2
Andon, R.J.L.; Counsell, J.F.; Lees, E.B.; Martin, J.F., Thermodynamic properties of organic oxygen compounds: 39 heat capacity of n-propyl ether, J. Chem. Thermodyn., 1975, 7, 587. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ambrose, Broderick, et al., 1974
Ambrose, D.; Broderick, B.E.; Townsend, R., The Critical Temperatures and Pressures of Thirty Organic Compounds, J. Appl. Chem. Biotechnol., 1974, 24, 359. [all data]

Majer, Wagner, et al., 1980
Majer, V.; Wagner, Z.; Svoboda, V.; Cadek, V., Enthalpies of vaporization and cohesive energies for a group of aliphatic ethers, J. Chem. Thermodyn., 1980, 12, 387-391. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Antosik, Fras, et al., 2002
Antosik, Maria; Fras, Zbigniew; Malanowski, Stanislaw K., Vapor-Liquid Equilibrium in 2-Ethoxyethanol + Valeraldehyde and + Propyl Ether at 313.15 to 333.15 K, J. Chem. Eng. Data, 2002, 47, 4, 757-760, https://doi.org/10.1021/je000275u . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ambrose, Ellender, et al., 1976
Ambrose, D.; Ellender, J.H.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers, The Journal of Chemical Thermodynamics, 1976, 8, 2, 165-178, https://doi.org/10.1016/0021-9614(76)90090-2 . [all data]

Meyer and Hotz, 1973
Meyer, Edwin F.; Hotz, Roger D., High-precision vapor-pressure data for eight organic compounds, J. Chem. Eng. Data, 1973, 18, 4, 359-362, https://doi.org/10.1021/je60059a008 . [all data]

Cidlinský and Polák, 1969
Cidlinský, J.; Polák, J., Saturated vapour pressures of some ethers, Collect. Czech. Chem. Commun., 1969, 34, 4, 1317-1321, https://doi.org/10.1135/cccc19691317 . [all data]

Lapidus and Nisel'son, 1968
Lapidus, I.I.; Nisel'son, L.A., Russ. J. Phys. Chem., 1968, 42, 6, 733. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References