Silane, chlorotrimethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid275.1J/mol*KN/ASamorukov, Kostryukov, et al., 1971 

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
187.5298.15Samorukov, Kostryukov, et al., 1971T = 12.38 to 303.05 K. Cp(liq) = 18.19046 + 0.077664T + 309052T-2 cal/mol*K. Value is calculated from equation. Deposited in VINITI, No 2501-71, 18 January 1971.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Δr59.8 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Samorukov, Kostryukov, et al., 1971
Samorukov, O.P.; Kostryukov, V.N.; Samorukova, N.Kh., Thermodynamics of chlorosilanes with organic substituents. Low-temperature heat capacity, temperatures, and heats of phase transformation and thermodynamics functions of the condensed phase of chlorotrimethylsilane, Russ. J. Phys. Chem., 1971, 45, 562-563. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]


Notes

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