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xenon difluoride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to F2Xe+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.33 ± 0.03eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
12.35 ± 0.01PIBerkowitz, Chupka, et al., 1971LLK
12.35 ± 0.01PEBrundle, Robin, et al., 1970RDSH
12.33 ± 0.02PEBrehm, Menzinger, et al., 1970RDSH
12.28PIMorrison, Nicholson, et al., 1968RDSH
12.4SNielsen and Schwarz, 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
XeF+12.90FPIBerkowitz, Chupka, et al., 1971, 2LLK
XeF+12.86FPIMorrison, Nicholson, et al., 1968RDSH
Xe+11.481F+F-?PIBerkowitz, Chupka, et al., 1971, 2LLK
Xe+~15.32FPIBerkowitz, Chupka, et al., 1971, 2LLK
Xe+12.0 ± 0.1F+F-?EISvec and Flesch, 1963RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.; Spohr, R., Photo-ionization studies of F2, HF, DF, and the xenon fluorides, Advan. Mass Spectrom., 1971, 5, 112. [all data]

Brundle, Robin, et al., 1970
Brundle, C.R.; Robin, M.B.; Jones, G.R., High resolution He I and He II photoelectron spectra of xenon difluoride, J. Chem. Phys., 1970, 52, 3383. [all data]

Brehm, Menzinger, et al., 1970
Brehm, B.; Menzinger, M.; Zorn, C., The photoelectron spectrum of XeF2, Can. J. Chem., 1970, 48, 3193. [all data]

Morrison, Nicholson, et al., 1968
Morrison, J.D.; Nicholson, A.J.C.; O'Donnell, T.A., Ionization and dissociation of xenon difluoride induced by photon impact, J. Chem. Phys., 1968, 49, 959. [all data]

Nielsen and Schwarz, 1976
Nielsen, U.; Schwarz, W.H.E., VUV spectra of the xenon fluorides, Chem. Phys., 1976, 13, 195. [all data]

Berkowitz, Chupka, et al., 1971, 2
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.H.; Spohr, R., Photoionization mass spectrometric study of XeF2, XeF4, and XeF6, J. Phys. Chem., 1971, 75, 1461. [all data]

Svec and Flesch, 1963
Svec, H.J.; Flesch, G.D., Thermochemical properties of xenon difluoride and xenon tetrafluoride from massspectra, Science, 1963, 142, 954. [all data]


Go To: Top, Gas phase ion energetics data, References