manganese difluoride

• Formula: F₂Mn
• Molecular weight: 92.934851
• CAS Registry Number: 7782-64-1
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Ion clustering data
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to F₂Mn⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kent, Ehlert, et al., 1964
Kent, R.A.; Ehlert, T.C.; Margrave, J.L., Mass Spectrometric Studies at High Temperatures. V. The Sublimation Pressure of Manganese(II) Fluoride and the Dissociation Energy of Manganese(I) Fluoride, J. Am. Chem. Soc., 1964, 86, 23, 5090-5093, https://doi.org/10.1021/ja01077a008 . [all data]

Sidorov and Gubarevich, 1982
Sidorov, L.N.; Gubarevich, G.D., Dissociation of the Gaseous Complex Fluorides. Alkali Metal Trifluoromanganates and Tetrafluoromanganates, Koord. Khim., 1982, 8, 12708c. [all data]

Ehlert and Hsia, 1973
Ehlert, T.C.; Hsia, M., Mass spectrometric and thermochemical studies of the manganese fluorides, J. Fluorine Chem., 1973, 2, 33. [all data]

Zmbov, Uy, et al., 1969
Zmbov, K.F.; Uy, O.M.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXXI. Stabilities of tungsten and molybdenum oxyfluorides, J. Phys. Chem., 1969, 73, 3008. [all data]

Zmbov and Margrave, 1968
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXII. The stabilities of tantalum pentafluoride and tantalum oxytrifluoride, J. Phys. Chem., 1968, 72, 1099. [all data]

Zmbov and Margrave, 1967
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXI. The heat of atomization of galium oxyfluoride, J. Inorg. Nucl. Chem., 1967, 29, 2649. [all data]

Kent, Ehlert, et al., 1964, 2
Kent, R.A.; Ehlert, T.C.; Margrave, J.L., Mass spectrometric studies at high temperatures. V. The sublimation pressure of manganese(II) fluoride and the dissociation energy of manganese(I) fluoride, J. Am. Chem. Soc., 1964, 86, 5090. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  EA	Electron affinity
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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