Ethyl Chloride
- Formula: C2H5Cl
- Molecular weight: 64.514
- IUPAC Standard InChIKey: HRYZWHHZPQKTII-UHFFFAOYSA-N
- CAS Registry Number: 75-00-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethane, chloro-; Aethylis; Aethylis chloridum; Anodynon; Chelen; Chlorene; Chlorethyl; Chloridum; Chloroethane; Chloryl; Chloryl anesthetic; Cloretilo; Dublofix; Ether chloratus; Ether hydrochloric; Ether muriatic; Hydrochloric ether; Kelene; Monochlorethane; Monochloroethane; Muriatic ether; Narcotile; C2H5Cl; Aethylchlorid; Chloorethaan; Chloroaethan; Chlorure D'ethyle; Cloroetano; Cloruro di etile; Etylu chlorek; NCI-C06224; UN 1037; Chloryle anesthetic
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 289. ± 10. | K | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 136.75 | K | N/A | Timmermans, 1952 | Uncertainty assigned by TRC = 0.4 K; TRC |
Tfus | 133. | K | N/A | Awbery, 1941 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 137. | K | N/A | Timmermans and Hennaut-Roland, 1937 | Uncertainty assigned by TRC = 0.5 K; TRC |
Tfus | 132.3 | K | N/A | Timmermans, 1911 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 134.82 | K | N/A | Gordon and Giauque, 1948 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 460.35 | K | N/A | Berthoud, 1917 | Uncertainty assigned by TRC = 0.4 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 52.4053 | bar | N/A | Berthoud, 1917 | Uncertainty assigned by TRC = 0.4053 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 24.6 ± 0.3 | kJ/mol | Review | Manion, 2002 | weighted average of several measurements plus a correction for non-ideality; DRB |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
24.652 | 285.42 | N/A | Gordon and Giauque, 1948, 2 | P = 101.325 kPa; DH |
25.1 | 300. | A | Stephenson and Malanowski, 1987 | Based on data from 285. to 344. K.; AC |
24.4 | 349. | A | Stephenson and Malanowski, 1987 | Based on data from 334. to 413. K.; AC |
24.4 | 418. | A | Stephenson and Malanowski, 1987 | Based on data from 403. to 460. K.; AC |
27.8 | 222. | A,E | Stephenson and Malanowski, 1987 | Based on data from 207. to 305. K. See also Li and Rossini, 1961 and Dykyj, 1970.; AC |
25.9 | 270. | N/A | Gordon and Giauque, 1948, 2 | Based on data from 218. to 285. K.; AC |
24.83 | 294. | C | Yates, 1926 | ALS |
Entropy of vaporization
ΔvapS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
86.37 | 285.42 | Gordon and Giauque, 1948, 2 | P; DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
217.21 to 285.66 | 4.16181 | 1052.821 | -32.078 | Gordon and Giauque, 1948, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
4.452 | 134.82 | Gordon and Giauque, 1948, 2 | DH |
4.45 | 134.8 | Acree, 1991 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
33.02 | 134.82 | Gordon and Giauque, 1948, 2 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Timmermans, 1952
Timmermans, J.,
Freezing points of organic compounds. VVI New determinations.,
Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]
Awbery, 1941
Awbery, J.H.,
Philos. Mag., 1941, 31, 247. [all data]
Timmermans and Hennaut-Roland, 1937
Timmermans, J.; Hennaut-Roland, M.,
Works from International Bureau at Physical-Chemical Standards. VIII. Physical constants of 20 organic compounds,
J. Chim. Phys. Phys.-Chim. Biol., 1937, 34, 693. [all data]
Timmermans, 1911
Timmermans, J.,
Researches on the freezing point of organic liquid compounds,
Bull. Soc. Chim. Belg., 1911, 25, 300. [all data]
Gordon and Giauque, 1948
Gordon, J.; Giauque, W.F.,
The Entropy of Ethyl Chloride. Heat Capacity from 13 to 287 K. Vapor Pressure. Heats of Fusion and Vaporization,
J. Am. Chem. Soc., 1948, 70, 1506. [all data]
Berthoud, 1917
Berthoud, A.,
Determination of Critical Temperatures and Pressures of Amines and Alkyl Chlorides,
J. Chim. Phys. Phys.-Chim. Biol., 1917, 15, 3. [all data]
Manion, 2002
Manion, J.A.,
Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons,
J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703
. [all data]
Gordon and Giauque, 1948, 2
Gordon, J.; Giauque, W.F.,
The entropy of ethyl chloride. Heat capacity from 18 to 287K. Vapor pressure. Heats of fusion and vaporization,
J. Am. Chem. Soc., 1948, 70, 1506-1510. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Li and Rossini, 1961
Li, J.C.M.; Rossini, F.D.,
Vapor Pressures and Boiling Points of the l-Fluoroalkanes, l-Chloroalkanes, l-Bromoalkanes, and l-Iodoalkanes, C 1 to C 20 .,
J. Chem. Eng. Data, 1961, 6, 2, 268-270, https://doi.org/10.1021/je60010a025
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Yates, 1926
Yates, G.W.C.,
LXXIV. Latent heats of vaporization of ethyl and methyl chlorides,
Philos. Mag., 1926, 2, 817-826. [all data]
Acree, 1991
Acree, William E.,
Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation,
Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Pc Critical pressure Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ΔvapS Entropy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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