4-Pyridinamine, N,N-dimethyl-
- Formula: C7H10N2
- Molecular weight: 122.1677
- IUPAC Standard InChIKey: VHYFNPMBLIVWCW-UHFFFAOYSA-N
- CAS Registry Number: 1122-58-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Pyridine, 4-(dimethylamino)-; γ-(Dimethylamino)pyridine; N,N-Dimethyl-4-aminopyridine; N,N-Dimethyl-4-pyridinamine; 4-(Dimethylamino)pyridine; 4-Dimethylaminepyridine; p-Dimethylaminopyridine; N,N-dimethylpyridin-4-amine
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
5.170 | 387.1 | AC | Shi, Tan, et al., 2007 | Based on data from 80. to 402. K. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 238.4 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 232.1 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.3 ± 0.1 | EI | Stefanovic and Grutzmacher, 1974 | LLK |
7.82 | PE | Ramsey and Walker, 1974 | Vertical value; LLK |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | A.E.WILLIAMS ICI DYESTUFFS DIVISION. BLACKLEY. |
NIST MS number | 2269 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Subscription Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Shi, Tan, et al., 2007
Shi, Quan; Tan, Zhi-Cheng; Di, You-Ying; Tong, Bo; Li, Yan-Sheng; Wang, Shao-Xu,
Thermal Analysis and Calorimetric Study of 4-Dimethylaminopyridine,
J. Chem. Eng. Data, 2007, 52, 3, 941-947, https://doi.org/10.1021/je6005423
. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Stefanovic and Grutzmacher, 1974
Stefanovic, D.; Grutzmacher, H.F.,
The ionisation potential of some substituted pyridines,
Org. Mass Spectrom., 1974, 9, 1052. [all data]
Ramsey and Walker, 1974
Ramsey, B.G.; Walker, F.A.,
A linear relationship between substituted pyridine lone pair vertical ionization potentials and pKa,
J. Am. Chem. Soc., 1974, 96, 3314. [all data]
Notes
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- Symbols used in this document:
ΔfusH Enthalpy of fusion - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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