HPCl

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21891.32 gas A-X 420 590 Bramwell, Rogers, et al., 2000
Tackett, He, et al., 2003
Tackett, Clouthier, et al., 2004
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PH stretch 2214.9 gas LF Tackett, He, et al., 2003
2 Bend 631.4 gas EM LF Bramwell, Rogers, et al., 2000
Tackett, He, et al., 2003
3 PCl stretch 555.0 gas EM LF Bramwell, Rogers, et al., 2000
Tackett, He, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PH stretch 2277.3 gas LF Tackett, He, et al., 2003
2 Bend 879.2 gas EM LF Bramwell, Rogers, et al., 2000
Tackett, He, et al., 2003
3 PCl stretch 529.9 gas LF Tackett, He, et al., 2003

Additional references: Jacox, 2003, page 43

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bramwell, Rogers, et al., 2000
Bramwell, M.J.; Rogers, D.M.; McDouall, J.J.W.; Whitehead, J.C., A theoretical and experimental study of the HPCl radical: the visible emission spectrum, Chem. Phys. Lett., 2000, 331, 5-6, 483, https://doi.org/10.1016/S0009-2614(00)01219-7 . [all data]

Tackett, He, et al., 2003
Tackett, B.S.; He, S.-G.; Evans, C.J.; Clouthier, D.J.; Judge, R.H., The electronic spectroscopy and molecular structure of the HPCl free radical: A potential III--V semiconductor growth intermediate, J. Chem. Phys., 2003, 119, 4, 2037, https://doi.org/10.1063/1.1584032 . [all data]

Tackett, Clouthier, et al., 2004
Tackett, B.S.; Clouthier, D.J.; Adam, A.G.; Shepherd, S.A., Phosphorus hyperfine structure in the electronic spectrum of the HPCl free radical, J. Chem. Phys., 2004, 121, 3, 1405, https://doi.org/10.1063/1.1758698 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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