NFCl

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 23500 gas A-X 380 500 Exton, Williams, et al., 1993
Tx = 27800 Ar A-X 300 525 Gilbert, Zarubaiko, et al., 1994
Tx = 21200 Ar A-X 300 525 Gilbert and Okin, 1995
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 340 ± 20 Ar AB Gilbert, Zarubaiko, et al., 1994

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NF stretch 917 Ar IR Zarubaiko and Gilbert, 1993
2 Bend 390 ± 40 gas EM Exton, Williams, et al., 1993
2 Bend 390 T Ar EM Gilbert and Okin, 1995
3 NCl stretch 720 Ar IR Zarubaiko and Gilbert, 1993

Additional references: Jacox, 1994, page 108; Jacox, 1998, page 201

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Exton, Williams, et al., 1993
Exton, D.B.; Williams, S.A.; Gilbert, J.V., Photolysis of gas-phase dichlorofluoroamine: ultraviolet emission from chlorine and chlorine fluoride, J. Phys. Chem., 1993, 97, 17, 4326, https://doi.org/10.1021/j100119a013 . [all data]

Gilbert, Zarubaiko, et al., 1994
Gilbert, J.V.; Zarubaiko, A.M.; Lantz, S., UV absorption spectrum of low-temperature matrix-isolated NFCl radicals, Chem. Phys. Lett., 1994, 220, 1-2, 19, https://doi.org/10.1016/0009-2614(94)00150-2 . [all data]

Gilbert and Okin, 1995
Gilbert, J.V.; Okin, G.S., Laser-induced emission from NFCl radicals isolated in low-temperature argon matrixes, J. Phys. Chem., 1995, 99, 29, 11365, https://doi.org/10.1021/j100029a011 . [all data]

Zarubaiko and Gilbert, 1993
Zarubaiko, A.M.; Gilbert, J.V., Infrared spectroscopy of low-temperature matrix-isolated chlorofluoroamine radicals, J. Phys. Chem., 1993, 97, 17, 4331, https://doi.org/10.1021/j100119a014 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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