Dichlorine hexaoxide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
52.3295.Lopez and Sicre, 1990Based on data from 273. to 318. K.

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 46500 T gas Lopez and Sicre, 1990, 2

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 37300 gas Jansen, Schatte, et al., 1988

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 25000 U Ar Jansen, Schatte, et al., 1988

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 ClO3 a-stretch 1249.5 Ne IR Jansen, Schatte, et al., 1988
1 ClO3 a-stretch 1245.9 Ar IR Jansen, Schatte, et al., 1988
2 ClO2 s-stretch 1080 gas IR Jansen, Tobias, et al., 1986
2 ClO2 s-stretch 1082.3 Ne IR Jansen, Schatte, et al., 1988
2 ClO2 s-stretch 1081.5 Ar IR Jansen, Schatte, et al., 1988
3 ClO3 s-stretch 1024 gas IR Jansen, Tobias, et al., 1986
3 ClO3 s-stretch 1026.3 Ne IR Jansen, Schatte, et al., 1988
3 ClO3 s-stretch 1026.0 Ar IR Jansen, Schatte, et al., 1988
4 O3Cl-O stretch 691 gas IR Jansen, Tobias, et al., 1986
4 O3Cl-O stretch 693.0 Ne IR Jansen, Schatte, et al., 1988
4 O3Cl-O stretch 695.7 Ar IR Jansen, Schatte, et al., 1988
5 O2Cl-O stretch 629 gas IR Jansen, Tobias, et al., 1986
5 O2Cl-O stretch 625.2 Ne IR Jansen, Schatte, et al., 1988
5 O2Cl-O stretch 624.0 Ar IR Jansen, Schatte, et al., 1988
6 ClO3 a-deform. 578.2 Ne IR Jansen, Schatte, et al., 1988
6 ClO3 a-deform. 580.0 Ar IR Jansen, Schatte, et al., 1988
7 ClO2 deform. 544 gas IR Jansen, Tobias, et al., 1986
7 ClO2 deform. 543.6 Ne IR Jansen, Schatte, et al., 1988
7 ClO2 deform. 542.5 Ar IR Jansen, Schatte, et al., 1988
8 ClO3 s-deform. 486.6 Ne IR Jansen, Schatte, et al., 1988
8 ClO3 s-deform. 486.0 Ar IR Jansen, Schatte, et al., 1988
9 ClO2 rock 374.6 Ar IR Jansen, Schatte, et al., 1988
10 ClO3 rock 371.2 Ar IR Jansen, Schatte, et al., 1988
11 ClOCl deform. 238.0 Ar IR Jansen, Schatte, et al., 1988
a 12 ClO3 a-stretch 1284.1 Ne IR Jansen, Schatte, et al., 1988
12 ClO3 a-stretch 1278.1 Ar IR Jansen, Schatte, et al., 1988
13 ClO2 a-stretch 1265 gas IR Jansen, Tobias, et al., 1986
13 ClO2 a-stretch 1263.1 Ne IR Jansen, Schatte, et al., 1988
14 ClO2 a-deform. 579 gas IR Jansen, Tobias, et al., 1986
14 ClO2 a-deform. 585.5 Ne IR Jansen, Schatte, et al., 1988
14 ClO2 a-deform. 585.9 Ar IR Jansen, Schatte, et al., 1988
15 ClO2 rock 374.6 Ar IR Jansen, Schatte, et al., 1988
16 ClO3 rock 371.2 Ar IR Jansen, Schatte, et al., 1988

Additional references: Jacox, 1994, page 382

Notes

UUpper bound
TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lopez and Sicre, 1990
Lopez, Maria I.; Sicre, Juan E., Physicochemical properties of chlorine oxides. 1. Composition, ultraviolet spectrum, and kinetics of the thermolysis of gaseous dichlorine hexoxide, J. Phys. Chem., 1990, 94, 9, 3860-3863, https://doi.org/10.1021/j100372a094 . [all data]

Lopez and Sicre, 1990, 2
Lopez, M.I.; Sicre, J.E., Physicochemical properties of chlorine oxides. 1. Composition, ultraviolet spectrum, and kinetics of the thermolysis of gaseous dichlorine hexoxide, J. Phys. Chem., 1990, 94, 9, 3860, https://doi.org/10.1021/j100372a094 . [all data]

Jansen, Schatte, et al., 1988
Jansen, M.; Schatte, G.; Tobias, K.M.; Willner, H., Properties of dichlorine hexaoxide in the gas phase and in low-temperature matrixes, Inorg. Chem., 1988, 27, 10, 1703, https://doi.org/10.1021/ic00283a009 . [all data]

Jansen, Tobias, et al., 1986
Jansen, M.; Tobias, K.M.; Willner, H., Chlor(VI)-oxid, Molek«65533»lstruktur und Verhalten in der Gasphase, Naturwiss., 1986, 73, 12, 734, https://doi.org/10.1007/BF00399244 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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