t-O4+
- Formula: O4+
- Molecular weight: 63.9971
- CAS Registry Number: 12596-85-9
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td | gas | A-X | 450 | 680L | Beyer and Vanderhoff, 1976 | ||
Vestal and Mauclaire, 1977 | |||||||
Smith, Cosby, et al., 1977 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
ag | 1 | O=O a-stretch | 1644.1 | T | Ne | IR | Thompson and Jacox, 1989 Zhou, Hacaloglu, et al., 1999 |
bu | 5 | O=O a-stretch | 1164.4 | vs | Ne | IR | Thompson and Jacox, 1989 Zhou, Hacaloglu, et al., 1999 |
5 | O=O a-stretch | 1118.6 | Ar | IR | Zhou, Hacaloglu, et al., 1999 | ||
Additional references: Jacox, 1994, page 209; Jacox, 1998, page 258; Jacox, 2003, page 238
Notes
vs | Very strong |
T | Tentative assignment or approximate value |
d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Beyer and Vanderhoff, 1976
Beyer, R.A.; Vanderhoff, J.A.,
Cross Section Measurements for Photodetachment or Photodissociation of Ions Produced in Gaseous Mixtures of O2, CO2 and H2O,
J. Chem. Phys., 1976, 65, 6, 2313, https://doi.org/10.1063/1.433342
. [all data]
Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H.,
Photodissociation of positive and negative ions formed in O2,
J. Chem. Phys., 1977, 67, 8, 3767, https://doi.org/10.1063/1.435317
. [all data]
Smith, Cosby, et al., 1977
Smith, G.P.; Cosby, P.C.; Moseley, J.T.,
Photodissociation of positive and negative ions formed in O2,
J. Chem. Phys., 1977, 67, 8, 3767, https://doi.org/10.1063/1.435317
. [all data]
Thompson and Jacox, 1989
Thompson, W.E.; Jacox, M.E.,
The vibrational spectra of molecular ions isolated in solid neon. II. O+4 and O-4,
J. Chem. Phys., 1989, 91, 7, 3826, https://doi.org/10.1063/1.456868
. [all data]
Zhou, Hacaloglu, et al., 1999
Zhou, M.; Hacaloglu, J.; Andrews, L.,
Infrared spectra of cyclic-O[sub 6][sup +] and trans-O[sub 6][sup +] in solid neon and argon,
J. Chem. Phys., 1999, 110, 19, 9450, https://doi.org/10.1063/1.478910
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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