Trifluoromethyl peroxynitrate
- Formula: CF3NO4
- Molecular weight: 147.0102
- IUPAC Standard InChIKey: IRCOOTKZKSUTLW-UHFFFAOYSA-N
- CAS Registry Number: 50311-48-3
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
24.8 | 232. | A | Stephenson and Malanowski, 1987 | Based on data from 193. to 247. K. |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | F.A. HOHORST, ALLIED CHEMICAL, IDAHO FALLS, IDAHO, U |
NIST MS number | 72070 |
Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 29400 | gas | 190U | 340 | Kopitzky, Willner, et al., 1998 | |||
State: X
Additional references: Jacox, 1998, page 368; Jacox, 2003, page 395
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
d | Photodissociation threshold |
References
Go To: Top, Phase change data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kopitzky, Willner, et al., 1998
Kopitzky, R.; Willner, H.; Mack, H.-G.; Pfeiffer, A.; Oberhammer, H.,
IR and UV Absorption Cross Sections, Vibrational Analysis, and the Molecular Structure of Trifluoromethyl Peroxynitrate, CF,
Inorg. Chem., 1998, 37, 24, 6208, https://doi.org/10.1021/ic980776p
. [all data]
Hohorst and DesMarteau, 1974
Hohorst, F.A.; DesMarteau, D.D.,
Reactions of trifluromethyl peroxy derivatives with inorganic nitrogen compounds. Synthesis and vibrational spectrum of trifluoromethyl peroxynitrate,
Inorg. Chem., 1974, 13, 3, 715, https://doi.org/10.1021/ic50133a040
. [all data]
Chen, Young, et al., 1993
Chen, J.; Young, V.; Zhu, T.; Niki, H.,
Long-path Fourier-transform infrared spectroscopic study of the reactions of trifluoromethylperoxy and trifluoromethoxy radicals with nitrogen dioxide,
J. Phys. Chem., 1993, 97, 45, 11696, https://doi.org/10.1021/j100147a024
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
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- Symbols used in this document:
ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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