yttrium
- Formula: Y
- Molecular weight: 88.90585
- IUPAC Standard InChIKey: VWQVUPCCIRVNHF-UHFFFAOYSA-N
- CAS Registry Number: 7440-65-5
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, NIST Free Links, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(CAS Reg. No. 64883-69-8 • 4294967295) + = CAS Reg. No. 64883-69-8
By formula: (CAS Reg. No. 64883-69-8 • 4294967295Y) + Y = CAS Reg. No. 64883-69-8
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 167.01 ± 0.84 | kcal/mol | N/A | Wu and Wang, 1998 | gas phase |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to Y+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 6.217 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 231. | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 226.1 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.308 ± 0.012 | LPES | Feigerle, Herman, et al., 1981 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.217 | EVAL | Lide, 1992 | LL |
7.0 ± 0.5 | EI | Gupta, Nappi, et al., 1981 | LLK |
6.35 ± 0.10 | EI | Rauh and Ackermann, 1979 | LLK |
6.4 ± 0.5 | EI | Haque and Gingerich, 1979 | LLK |
6.6 ± 0.6 | EI | Fries and Cater, 1978 | LLK |
6.5 ± 0.5 | EI | Steiger and Cater, 1975 | LLK |
6.45 ± 0.15 | EI | Rauh and Ackermann, 1974 | LLK |
6.9 ± 0.1 | EI | Liu and Wahlbeck, 1974 | LLK |
6.217 | S | Garton, Reeves, et al., 1973 | LLK |
6.378 | S | Moore, 1970 | RDSH |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wu and Wang, 1998
Wu, H.B.; Wang, L.S.,
Photoelectron spectroscopy and electronic structure of ScOn- (n = 1-4) and YOn- (n = 1-5): Strong electron correlation effects in ScO- and YO-,
J. Phys. Chem. A, 1998, 102, 46, 9129-9135, https://doi.org/10.1021/jp982588q
. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Feigerle, Herman, et al., 1981
Feigerle, C.S.; Herman, Z.; Lineberger, W.C.,
Laser Photoelectron Spectroscopy of Sc- and Y-: A Determination of the Order of Electron Filling in Transition Metal Anions,
J. Electron Spectros. Rel. Phenom., 1981, 23, 3, 441, https://doi.org/10.1016/0368-2048(81)85050-5
. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Gupta, Nappi, et al., 1981
Gupta, S.K.; Nappi, B.M.; Gingerich, K.A.,
Mass spectrometric study of the stabilities of the gaseous molecules Pt2 and PtY,
Inorg. Chem., 1981, 20, 966. [all data]
Rauh and Ackermann, 1979
Rauh, E.G.; Ackermann, R.J.,
The first ionization potentials of the transition metals,
J. Chem. Phys., 1979, 70, 1004. [all data]
Haque and Gingerich, 1979
Haque, R.; Gingerich, K.A.,
Investigation of the thermodynamic stabilities of the gaseous molecules RhScC, RhScC2 RhYC2 by Knudsen effusion mass spectrometry,
J. Chem. Soc. Faraday Trans. 2, 1979, 985. [all data]
Fries and Cater, 1978
Fries, J.A.; Cater, E.D.,
Vaporization, thermodynamics, and dissociation energy of gadolinium monosulfide: Systematics of vaporization of the rare earth monosulfides,
J. Chem. Phys., 1978, 68, 3978. [all data]
Steiger and Cater, 1975
Steiger, R.A.; Cater, E.D.,
Vaporization, thermodynamics, and dissociation energy of yttrium monosulfide,
High Temp. Sci., 1975, 7, 204. [all data]
Rauh and Ackermann, 1974
Rauh, E.G.; Ackermann, R.J.,
First ionization potentials of some refractory oxide vapors,
J. Chem. Phys., 1974, 60, 1396. [all data]
Liu and Wahlbeck, 1974
Liu, M.B.; Wahlbeck, P.G.,
Knudsen effusion and mass spectrometric studies of the vaporization of Y2O3(s). Dissociation energy of YO(g),
High Temp. Sci., 1974, 6, 179. [all data]
Garton, Reeves, et al., 1973
Garton, W.R.S.; Reeves, E.M.; Tomkins, F.S.; Ercoli, B.,
Rydberg Series and Autoionization Resonances in the Y I Absorption Spectrum,
Proc. R. Soc. London A:, 1973, 333, 17. [all data]
Moore, 1970
Moore, C.E.,
Ionization potentials and ionization limits derived from the analyses of optical spectra,
Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, NIST Free Links, References
- Symbols used in this document:
EA Electron affinity IE (evaluated) Recommended ionization energy ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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