CHN2

• Formula: CHN₂
• Molecular weight: 41.0320
• CAS Registry Number: 12347-01-2
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CN₂^- +  = CHN₂

By formula: CN₂^- + H⁺ = CHN₂

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to CHN₂⁺ (ion structure unspecified)

De-protonation reactions

CN₂^- +  = CHN₂

By formula: CN₂^- + H⁺ = CHN₂

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   B

State:   X

Additional references: Jacox, 1994, page 160; Jacox, 1998, page 235; Jacox, 2003, page 188; Yamamoto and Saito, 1994

Notes

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clifford, Wenthold, et al., 1998
Clifford, E.P.; Wenthold, P.G.; Lineberger, W.C.; Peterssom, G.A.; Broaddus, K.M.; Kass, S.R.; Kato, S., Properties of Diazocarbene [CNN] and the diazomethyl Radical [HCNN] via Ion Chemistry and Spectroscopy, J. Phys. Chem. A, 1998, 102, 36, 7100, https://doi.org/10.1021/jp9802735 . [all data]

Basco and Yee, 1968
Basco, N.; Yee, K.K., Chem. Commun., 1968, 150. [all data]

Kroto, Morgan, et al., 1970
Kroto, H.W.; Morgan, T.F.; Sheena, H.H., Flash photolysis of cyanogen azide, NCN3, Trans. Faraday Soc., 1970, 66, 2237, https://doi.org/10.1039/tf9706602237 . [all data]

Bise, Hoops, et al., 2001
Bise, R.T.; Hoops, A.A.; Neumark, D.M., Photodissociation and photoisomerization pathways of the HNCN free radical, J. Chem. Phys., 2001, 114, 20, 9000, https://doi.org/10.1063/1.1367411 . [all data]

Herzberg and Warsop, 1963
Herzberg, G.; Warsop, P.A., SPECTRUM AND STRUCTURE OF THE FREE HNCN RADICAL, Can. J. Phys., 1963, 41, 2, 286, https://doi.org/10.1139/p63-034 . [all data]

Wu, Hall, et al., 1993
Wu, M.; Hall, G.; Sears, T.J., J. Chem. Soc., 1993, Faraday Trans. 89, 615. [all data]

Maier, Eckwert, et al., 1996
Maier, G.; Eckwert, J.; Bothur, A.; Reisenauer, H.P.; Schmidt, C., Liebigs Ann., 1996, 1041. [all data]

Clifford, Wenthold, et al., 1997
Clifford, E.P.; Wenthold, P.G.; Lineberger, W.C.; Peterssom, G.A.; Ellison, G.B., Photoelectron Spectroscopy of the NCN- and HNCN- Ions, J. Phys. Chem. A, 1997, 101, 24, 4338, https://doi.org/10.1021/jp964067d . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Yamamoto and Saito, 1994
Yamamoto, S.; Saito, S., Microwave spectrum of the HNCN radical in the X 2A' ground electronic state, J. Chem. Phys., 1994, 101, 12, 10350, https://doi.org/10.1063/1.467915 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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