Ethyne, 1-trimethylsilyl-

• Formula: C₂H₄Si
• Molecular weight: 56.1387
• IUPAC Standard InChI: InChI=1S/C5H10Si/c1-5-6(2,3)4/h1H,2-4H3 Copy

  
• IUPAC Standard InChIKey: CWMFRHBXRUITQE-UHFFFAOYSA-N Copy
• CAS Registry Number: 1066-27-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • (Trimethylsilyl)acetylene
• Information on this page:
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Options:
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₃Si^- +  =

By formula: C₂H₃Si^- + H⁺ = C₂H₄Si

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

De-protonation reactions

C₂H₃Si^- +  =

By formula: C₂H₃Si^- + H⁺ = C₂H₄Si

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ebsworth and Frankiss, 1963
Ebsworth, E.A.V.; Frankiss, S.G., 104. The preparation and properties of silylacetylene, and the structures of silyl cyanides, J. Chem. Soc., 1963, 661, https://doi.org/10.1039/jr9630000661 . [all data]

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]

Ensslin, Bock, et al., 1974
Ensslin, W.; Bock, H.; Becker, G., Photoelectron spectra and molecular properties. XXX. π interactions in H₃Si- H₃C-substituted acetylenes, J. Am. Chem. Soc., 1974, 96, 2757. [all data]

Notes

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• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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