Magnesium monofluoride

• Formula: FMg
• Molecular weight: 43.3034
• IUPAC Standard InChI: InChI=1S/FH.Mg/h1H;/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: WSXHQDSJUJYQDO-UHFFFAOYSA-M Copy
• CAS Registry Number: 14953-28-7
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • Constants of diatomic molecules
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to FMg⁺ (ion structure unspecified)

Ionization energy determinations

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through March, 1977

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hildenbrand, 1968
Hildenbrand, D.L., Mass-spectrometric studies of bonding in the group IIA fluorides, J. Chem. Phys., 1968, 48, 3657. [all data]

Barrow and Beale, 1967
Barrow, R.F.; Beale, J.R., Rotational analysis of electronic bands of gaseous MgF, Proc. Phys. Soc. (London), 1967, 91, 483. [all data]

Murad, Hildenbrand, et al., 1966
Murad, E.; Hildenbrand, D.L.; Main, R.P., Dissociation energies of group IIIA monofluorides-the possibility of potential maxima in their excited H states,, J. Chem. Phys., 1966, 45, 263. [all data]

Ehlert, Blue, et al., 1964
Ehlert, T.C.; Blue, G.D.; Green, J.W.; Margrave, J.L., Mass spectrometric studies at high temperatures. IV. Dissociation energies of the alkaline earth monofluorides, J. Chem. Phys., 1964, 41, 2250. [all data]

Novikov and Gurvich, 1971
Novikov, M.M.; Gurvich, L.V., The electronic spectra of MgF and MgF⁺, J. Appl. Spectrosc. Engl. Transl., 1971, 14, 820, In original 1113. [all data]

Jevons, 1929
Jevons, W., Observations in connection with the band systems of the fluorides of beryllium and magnesium, Proc. R. Soc. London A, 1929, 122, 211. [all data]

Knight, Easley, et al., 1971
Knight, L.B., Jr.; Easley, W.C.; Weltner, W., Jr., Hyperfine interaction and chemical bonding in MgF, CaF, SrF, and BaF molecules, J. Chem. Phys., 1971, 54, 322. [all data]

Maheshwari, Singh, et al., 1968
Maheshwari, R.C.; Singh, I.D.; Shukla, M.M., Franck-Condon factors and r centroids for the B-X and C-X systems of the MgF molecule, J. Phys. B:, 1968, 1, 993. [all data]

Rao and Lakshman, 1970
Rao, T.V.R.; Lakshman, S.V.J., r-Centroids and Franck-Condon factors for the bands of the C²Σ⁺-X²Σ⁺ system of MgF, J. Quant. Spectrosc. Radiat. Transfer, 1970, 10, 945. [all data]

Rao and Lakshman, 1970, 2
Rao, T.V.R.; Lakshman, S.V.J., The true potential energy curves, γ-centroids and Franck-Condon factors of the bands of the B²Σ⁺-X²Σ⁺ system of MgF, Physica (Amsterdam), 1970, 46, 609. [all data]

Walker and Richards, 1970
Walker, T.E.H.; Richards, W.G., The assignment of molecular orbital configurations on the basis of λ-type doubling, J. Phys., 1970, 3, 271. [all data]

Walker and Richards, 1968
Walker, T.E.H.; Richards, W.G., The nature of the first excited electronic state in MgF, J. Phys. B:, 1968, 1, 1061. [all data]

Singh, Shukla, et al., 1969
Singh, I.D.; Shukla, M.M.; Maheshwari, R.C., Vibrational transition probabilities and r-centroids for the A-X system of the magnesium fluoride molecule, J. Quant. Spectrosc. Radiat. Transfer, 1969, 9, 533. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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