Lithium fluoride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-81.451kcal/molReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
gas,1 bar47.851cal/mol*KReviewChase, 1998Data last reviewed in December, 1968

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 3000. to 6000.
A 8.386310
B 0.599110
C -0.123634
D 0.010457
E -0.102129
F -84.31831
G 57.25229
H -81.45010
ReferenceChase, 1998
Comment Data last reviewed in December, 1968

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-143.08kcal/molReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
liquid,1 bar10.27cal/mol*KReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
Δfsolid-147.45kcal/molReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
solid8.540cal/mol*KReviewChase, 1998Data last reviewed in December, 1968

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1121.3 to 3000.
A 15.34010
B 1.002730×10-11
C -5.502560×10-12
D 9.379162×10-13
E 2.749131×10-13
F -147.6550
G 28.83210
H -143.0810
ReferenceChase, 1998
Comment Data last reviewed in December, 1968

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 1121.3
A 9.980490
B 4.472061
C 0.165792
D -0.237242
E -0.116409
F -151.0120
G 18.62350
H -147.4500
ReferenceChase, 1998
Comment Data last reviewed in December, 1968

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
64.1 ± 1.01073. to 1121.Scheffee and Margrave, 1959See also Eisenstadt, Rothberg, et al., 1958.
64.0 ± 1.0957. to 1113.Porter and Schoonmaker, 1958 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to FLi+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
>1.34997EIAEEbinghaus, 1964From (LiF)2; G3MP2B3 calculations indicate an EA of ca.0.5 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.3EIBerkowitz, Tasman, et al., 1962RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Li+11.40FEIVeljkovic, Neskovic, et al., 1993LL
Li+11.5FEIBerkowitz, Tasman, et al., 1962RDSH
Li+~12.FEIPorter and Schoonmaker, 1958RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Scheffee and Margrave, 1959
Scheffee, R.S.; Margrave, J.L., Vapor Pressure Equations for Species over Solid and Liquid LiF, J. Chem. Phys., 1959, 31, 6, 1682, https://doi.org/10.1063/1.1730680 . [all data]

Eisenstadt, Rothberg, et al., 1958
Eisenstadt, M.; Rothberg, G.M.; Kusch, P., Molecular Composition of Alkali Fluoride Vapors, J. Chem. Phys., 1958, 29, 4, 797, https://doi.org/10.1063/1.1744593 . [all data]

Porter and Schoonmaker, 1958
Porter, R.F.; Schoonmaker, R.C., Mass spectrometric study of the vaporization of LiF, NaF, and LiF-NaF mixtures, J. Chem. Phys., 1958, 29, 1070. [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Berkowitz, Tasman, et al., 1962
Berkowitz, J.; Tasman, H.A.; Chupka, W.A., Double-oven experiments with lithium halide vapors, J. Chem. Phys., 1962, 36, 2170. [all data]

Veljkovic, Neskovic, et al., 1993
Veljkovic, M.V.; Neskovic, O.M.; Miletic, M.B.; Zmbov, K.F., Mass spectrometric study of ionization and fragmentation of lithium fluoride vapor by electron impact, J. Serb. Chem. Soc., 1993, 58, 101. [all data]


Notes

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