CaOCH3

• Formula: CH₃CaO
• Molecular weight: 71.112
• CAS Registry Number: 87330-90-3
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   B

State:   A

State:   X

Additional references: Jacox, 1994, page 314; Jacox, 2003, page 315

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Elhanine, Lawruszczuk, et al., 1998
Elhanine, M.; Lawruszczuk, R.; Soep, B., Laser spectroscopy of metallic free radicals: the observation of the C--X vibronically allowed electronic transition for Ca--OCH3, Ca--OC2H5 and Ca--CCH, Chem. Phys. Lett., 1998, 288, 5-6, 785, https://doi.org/10.1016/S0009-2614(98)00352-2 . [all data]

Wormsbecher and Suenram, 1982
Wormsbecher, R.F.; Suenram, R.D., Laser spectroscopy and chemiluminescence from the monomethoxides of Ca, Sr, and Ba, J. Mol. Spectrosc., 1982, 95, 2, 391, https://doi.org/10.1016/0022-2852(82)90138-2 . [all data]

Brazier, Ellingboe, et al., 1986
Brazier, C.R.; Ellingboe, L.C.; Kinsey-Nielsen, S.; Bernath, P.F., Laser spectroscopy of alkaline earth monoalkoxide free radicals, J. Am. Chem. Soc., 1986, 108, 9, 2126, https://doi.org/10.1021/ja00269a002 . [all data]

Namiki, Robinson, et al., 1998
Namiki, K.C.; Robinson, J.S.; Steimle, T.C., A spectroscopic study of CaOCH[sub 3] using the pump/probe microwave and the molecular beam/optical Stark techniques, J. Chem. Phys., 1998, 198, 13, 5283, https://doi.org/10.1063/1.477146 . [all data]

Whitham, Beaton, et al., 1998
Whitham, C.J.; Beaton, S.A.; Ito, Y.; Brown, J.M., Laser Excitation Spectroscopy of theB2A1--X2A1Transition of the CaOCH3Radical, J. Mol. Spectrosc., 1998, 191, 2, 286, https://doi.org/10.1006/jmsp.1998.7642 . [all data]

Linton, Ross, et al., 2008
Linton, C.; Ross, A.J.; Adam, A.G.; Crozet, P.; Downie, L.E.; Granger, A.D.; Hopkins, W.S., Isotopic study of the transition of calcium monomethoxide using laser excitation and population depletion spectroscopy, J. Mol. Spectrosc., 2008, 250, 2, 98, https://doi.org/10.1016/j.jms.2008.05.002 . [all data]

Crozet, Martin, et al., 2002
Crozet, P.; Martin, F.; Ross, A.J.; Linton, C.; Dick, M.J.; Adam, A.G., The A2E--X2A1 System of CaOCH3, J. Mol. Spectrosc., 2002, 213, 1, 28, https://doi.org/10.1006/jmsp.2002.8536 . [all data]

Crozet, Ross, et al., 2005
Crozet, P.; Ross, A.J.; Linton, C.; Adam, A.G.; Hopkins, W.S.; Le Roy, R.J., Geometry of the CaOCH3 radical from isotope effects in the transition, J. Mol. Spectrosc., 2005, 229, 2, 224, https://doi.org/10.1016/j.jms.2004.09.006 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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