HKrCl
- Formula: ClHKr
- Molecular weight: 120.259
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 35700 | Kr | Khriachtchev, Pettersson, et al., 2001 | |||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | HKr stretch | 1476 | vs | Kr | IR | Pettersson, Lundell, et al., 1995 |
| 1 | HKr stretch | 1589.0 | Kr | IR | Lignell, Khriachtchev, et al., 2002 Lignell, Khriachtchev, et al., 2003 | ||
| 1 | HKr stretch | 1508.5 | Kr | IR | Lignell, Khriachtchev, et al., 2002 Lignell, Khriachtchev, et al., 2003 | ||
| Π | 2 | Bend | 544 | w | Kr | IR | Pettersson, Lundell, et al., 1995 |
| 2 | Bend | 541.5 | Kr | IR | Lignell, Khriachtchev, et al., 2002 Lignell, Khriachtchev, et al., 2003 | ||
| Σ+ | 3 | KrCl stretch | 253.1 | Kr | IR | Lignell, Lundell, et al., 2003 | |
Additional references: Jacox, 1998, page 158; Jacox, 2003, page 47
Notes
| w | Weak |
| vs | Very strong |
| x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Khriachtchev, Pettersson, et al., 2001
Khriachtchev, L.; Pettersson, M.; Lundell, J.; Rasanen, M.,
Intermediate reactions in solid-state photolysis,
J. Chem. Phys., 2001, 114, 18, 7727, https://doi.org/10.1063/1.1370938
. [all data]
Pettersson, Lundell, et al., 1995
Pettersson, M.; Lundell, J.; Rasanen, M.,
Neutral rare-gas containing charge-transfer molecules in solid matrices. I. HXeCl, HXeBr, HXeI, and HKrCl in Kr and Xe,
J. Chem. Phys., 1995, 102, 16, 6423, https://doi.org/10.1063/1.469357
. [all data]
Lignell, Khriachtchev, et al., 2002
Lignell, A.; Khriachtchev, L.; Pettersson, M.; Rasanen, M.,
Large blueshift of the H--Kr stretching frequency of HKrCl upon complexation with N[sub 2],
J. Chem. Phys., 2002, 117, 3, 961, https://doi.org/10.1063/1.1491403
. [all data]
Lignell, Khriachtchev, et al., 2003
Lignell, A.; Khriachtchev, L.; Pettersson, M.; Rasanen, M.,
Interaction of rare-gas-containing molecules with nitrogen: Matrix-isolation and ab initio study of HArF...N[sub 2], HKrF...N[sub 2], and HKrCl...N[sub 2] complexes,
J. Chem. Phys., 2003, 118, 24, 11120, https://doi.org/10.1063/1.1575198
. [all data]
Lignell, Lundell, et al., 2003
Lignell, A.; Lundell, J.; Pettersson, M.; Khriachtchev, L.; Rasanen, M.,
Kr--Cl stretching vibration of HKrCl: Matrix-isolation and anharmonic ab initio study,
Low Temp. Phys., 2003, 29, 9, 844, https://doi.org/10.1063/1.1619355
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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