Cl2O3
- Formula: Cl2O3
- Molecular weight: 118.904
- CAS Registry Number: 17496-59-2
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- Data at other public NIST sites:
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 37450 | gas | 220 | 320 | Hayman and Cox, 1989 | |||
Burkholder, Orlando, et al., 1990 | |||||||
Burkholder, Mauldin, et al., 1993 | |||||||
Harwood, Rowley, et al., 1995 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
1225 | vs | gas | IR | Schell-Sorokin, Bethune, et al., 1982 Burkholder, Orlando, et al., 1990 | |||
1216.0 | Ne | IR | Muller and Willner, 1993 | ||||
1226.1 | Ar | IR | Cheng and Lee, 1989 | ||||
1213.5 | Ar | IR | Muller and Willner, 1993 | ||||
1203.1 | Ne | IR | Muller and Willner, 1993 | ||||
1200.7 | Ar | IR | Muller and Willner, 1993 | ||||
1057 | s | gas | IR | Burkholder, Orlando, et al., 1990 | |||
1060 | Ne | IR | Muller and Willner, 1993 | ||||
1058.4 | Ar | IR | Cheng and Lee, 1989 Muller and Willner, 1993 | ||||
740 | w | gas | IR | Burkholder, Orlando, et al., 1990 | |||
560 | w m | gas | IR | Burkholder, Orlando, et al., 1990 | |||
Additional references: Jacox, 1994, page 302; Jacox, 1998, page 307; Friedl, Birk, et al., 1995
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hayman and Cox, 1989
Hayman, G.D.; Cox, R.A.,
UV absorption spectrum and thermochemistry of Cl2O3 formed in the photolysis of OClO-containing mixtures at low temperatures,
Chem. Phys. Lett., 1989, 155, 1, 1, https://doi.org/10.1016/S0009-2614(89)87350-6
. [all data]
Burkholder, Orlando, et al., 1990
Burkholder, J.B.; Orlando, J.J.; Howard, C.J.,
Ultraviolet absorption cross sections of chlorine oxide (Cl2O2) between 210 and 410 nm,
J. Phys. Chem., 1990, 94, 2, 687, https://doi.org/10.1021/j100365a033
. [all data]
Burkholder, Mauldin, et al., 1993
Burkholder, J.B.; Mauldin, R.L., III; Yokelson, R.J.; Solomon, S.; Ravishankara, A.R.,
Kinetic, thermochemical, and spectroscopic study of chlorine oxide (Cl2O3),
J. Phys. Chem., 1993, 97, 29, 7597, https://doi.org/10.1021/j100131a032
. [all data]
Harwood, Rowley, et al., 1995
Harwood, M.H.; Rowley, D.M.; Freshwater, R.A.; Cox, R.A.; Jones, R.L.,
J. Chem. Soc., 1995, Faraday Trans. 91, 3027. [all data]
Schell-Sorokin, Bethune, et al., 1982
Schell-Sorokin, A.J.; Bethune, D.S.; Lankard, J.R.; Loy, M.M.T.; Sorokin, P.P.,
Chlorine perchlorate a major photolysis product of chlorine dioxide,
J. Phys. Chem., 1982, 86, 24, 4653, https://doi.org/10.1021/j100221a001
. [all data]
Muller and Willner, 1993
Muller, H.S.P.; Willner, H.,
Vibrational and electronic spectra of chlorine dioxide, OClO, and chlorine superoxide ClOO, isolated in cryogenic matrixes,
J. Phys. Chem., 1993, 97, 41, 10589, https://doi.org/10.1021/j100143a013
. [all data]
Cheng and Lee, 1989
Cheng, B.-M.; Lee, Y.-P.,
Production and trapping of gaseous dimeric ClO: The infrared spectrum of chlorine peroxide (ClOOCl) in solid argon,
J. Chem. Phys., 1989, 90, 11, 5930, https://doi.org/10.1063/1.456359
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Friedl, Birk, et al., 1995
Friedl, R.R.; Birk, M.; Oh, J.J.; Cohen, E.A.,
The Rotational Spectrum and Molecular Structure of Chlorine Chlorate,
J. Mol. Spectrosc., 1995, 170, 2, 383, https://doi.org/10.1006/jmsp.1995.1079
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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